{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,18]],"date-time":"2026-04-18T01:16:18Z","timestamp":1776474978015,"version":"3.51.2"},"reference-count":47,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2020,11,29]],"date-time":"2020-11-29T00:00:00Z","timestamp":1606608000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"ANCD","award":["20.80009.5007.15"],"award-info":[{"award-number":["20.80009.5007.15"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Eight mixed-ligand coordination networks, [Cd(2-aba)(NO3)(4-bphz)3\/2]n\u00b7n(dmf) (1), [Cd(2-aba)2(4-bphz)]n\u00b70.75n(dmf) (2), [Cd(seb)(4-bphz)]n\u00b7n(H2O) (3), [Cd(seb)(4-bpmhz)]n\u00b7n(H2O) (4), [Cd(hpa)(3-bphz)]n (5), [Zn(1,3-bdc)(3-bpmhz)]n\u00b7n(MeOH) (6), [Cd(1,3-bdc)(3-bpmhz)]n \u00b70.5n(H2O)\u00b70.5n(EtOH) (7), and [Cd(NO3)2(3-bphz)(bpe)]n\u00b7n(3-bphz) (8) were obtained by interplay of cadmium nitrate tetrahydrate or zinc nitrate hexahydrate with 2-aminobenzenecarboxylic acid (H(2-aba)), three dicarboxylic acids, sebacic (decanedioic acid, H2seb), homophthalic (2-(carboxymethyl)benzoic acid, H2hpa), isophthalic (1,3-benzenedicarboxylic acid, H2(1,3-bdc)) acids, bis(4-pyridyl)ethane (bpe) and with four azine ligands, 1,2-bis(pyridin-4-ylmethylene)hydrazine (4-bphz), 1,2-bis(1-(pyridin-4-yl)ethylidene) hydrazine (4-bpmhz), 1,2-bis(pyridin-3-ylmethylene)hydrazine (3-bphz), and 1,2-bis(1-(pyridin-3-yl) ethylidene)hydrazine (3-bpmhz). Compounds 1 and 2 are 1D coordination polymers, while compounds 3\u20138 are 2D coordination polymers. All compounds were characterized by spectroscopic and X-ray diffraction methods of analysis. The solvent uptakes and stabilities to the guest evacuation were studied and compared for 1D and 2D coordination networks. The de-solvated forms revealed a significant increase of emission in comparison with the as-synthesized crystals.<\/jats:p>","DOI":"10.3390\/molecules25235616","type":"journal-article","created":{"date-parts":[[2020,11,29]],"date-time":"2020-11-29T21:55:31Z","timestamp":1606686931000},"page":"5616","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis, Crystal Structures, Inclusion, and Emission Properties"],"prefix":"10.3390","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1955-8480","authenticated-orcid":false,"given":"Victor Ch.","family":"Kravtsov","sequence":"first","affiliation":[{"name":"Institute of Applied Physics, Academiei 5, MD2028 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vasile","family":"Lozovan","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Academiei 3, MD2028 Chisinau, Moldova"},{"name":"Chemistry Department, Tiraspol State University, Iablocikin 5, MD2069 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nikita","family":"Siminel","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics, Academiei 5, MD2028 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eduard B.","family":"Coropceanu","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Academiei 3, MD2028 Chisinau, Moldova"},{"name":"Chemistry Department, Tiraspol State University, Iablocikin 5, MD2069 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olga V.","family":"Kulikova","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics, Academiei 5, MD2028 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Natalia V.","family":"Costriucova","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics, Academiei 5, MD2028 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2508-5368","authenticated-orcid":false,"given":"Marina S.","family":"Fonari","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics, Academiei 5, MD2028 Chisinau, Moldova"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,11,29]]},"reference":[{"key":"ref_1","first-page":"703","article-title":"Selective binding and removal of guests in a microporous metal-organic framework","volume":"378","author":"Yaghi","year":"1995","journal-title":"Nat. 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