{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T15:12:50Z","timestamp":1775315570575,"version":"3.50.1"},"reference-count":40,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2020,12,5]],"date-time":"2020-12-05T00:00:00Z","timestamp":1607126400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["16-13-10331"],"award-info":[{"award-number":["16-13-10331"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Complexation of the 8,8\u2032-bis(methylsulfanyl) derivatives of cobalt and iron bis(dicarbollides) [8,8\u2032-(MeS)2-3,3\u2032-M(1,2-C2B9H10)2]\u2212 (M = Co, Fe) with copper, silver, palladium and rhodium leads to the formation of the corresponding chelate complexes, which is accompanied by a transition from the transoid to the cisoid conformation of the bis(dicarbollide) complex. This transition is reversible and can be used in design of coordination-driven molecular switches based on transition metal bis(dicarbollide) complexes. The solid-state structures of {(Ph3P)ClPd[8,8\u2032- (MeS)2-3,3\u2032-Co(1,2-C2B9H10)2-\u03ba2-S,S\u2032]} and {(COD)Rh[8,8\u2032-(MeS)2-3,3\u2032-Co(1,2-C2B9H10)2-\u03ba2-S,S\u2032]} were determined by single crystal X-ray diffraction.<\/jats:p>","DOI":"10.3390\/molecules25235745","type":"journal-article","created":{"date-parts":[[2020,12,10]],"date-time":"2020-12-10T22:15:36Z","timestamp":1607638536000},"page":"5745","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Bis(dicarbollide) Complexes of Transition Metals as a Platform for Molecular Switches. Study of Complexation of 8,8\u2032-Bis(methylsulfanyl) Derivatives of Cobalt and Iron Bis(dicarbollides)"],"prefix":"10.3390","volume":"25","author":[{"given":"Sergey A.","family":"Anufriev","sequence":"first","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey V.","family":"Timofeev","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5097-5584","authenticated-orcid":false,"given":"Alexei A.","family":"Anisimov","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991 Moscow, Russia"},{"name":"Higher Chemical College at the Russian Academy of Sciences, D.I. Mendeleev Russian Chemical Technological University, 9 Miusskaya Sq., 125047 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kyrill Yu.","family":"Suponitsky","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991 Moscow, Russia"},{"name":"Basic Department of Chemistry of Innovative Materials and Technologies, G.V. Plekhanov Russian University of Economics, 36 Stremyannyi Line, 117997 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5442-367X","authenticated-orcid":false,"given":"Igor B.","family":"Sivaev","sequence":"additional","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,12,5]]},"reference":[{"key":"ref_1","unstructured":"Sauvage, J.-P. (2001). Molecular Machines and Motors (Structure and Bonding, Volume 99), Springer."},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Credi, A., Silvi, S., and Venturi, M. (2014). Molecular Machines and Motors: Recent Advances and Perspectives (Topics in Current Chemistry, Volume 354), Springer.","DOI":"10.1007\/978-3-319-08678-1"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"10081","DOI":"10.1021\/acs.chemrev.5b00146","article-title":"Artificial molecular machines","volume":"115","author":"Leigh","year":"2015","journal-title":"Chem. 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