{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T13:44:52Z","timestamp":1790775892726,"version":"4.1.0"},"reference-count":70,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2020,12,8]],"date-time":"2020-12-08T00:00:00Z","timestamp":1607385600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002261","name":"Russian Foundation for Basic Research","doi-asserted-by":"publisher","award":["18-29-04007"],"award-info":[{"award-number":["18-29-04007"]}],"id":[{"id":"10.13039\/501100002261","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["19-73-20196"],"award-info":[{"award-number":["19-73-20196"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Compounds based on new cyanide cluster anions [{Mo6I8}(CN)6]2\u2013, trans-[{Mo6I8}(CN)4(MeO)2]2\u2013 and trans-[{W6I8}(CN)2(MeO)4]2\u2212 were synthesized using mechanochemical or solvothermal synthesis. The crystal and electronic structures as well as spectroscopic properties of the anions were investigated. It was found that the new compounds exhibit red luminescence upon excitation by UV light in the solid state and solutions, as other cluster complexes based on {Mo6I8}4+ and {W6I8}4+ cores do. The compounds can be recrystallized from aqueous methanol solutions; besides this, it was shown using NMR and UV-Vis spectroscopy that anions did not undergo hydrolysis in the solutions for a long time. These facts indicate that hydrolytic stabilization of {Mo6I8} and {W6I8} cluster cores can be achieved by coordination of cyanide ligands.<\/jats:p>","DOI":"10.3390\/molecules25245796","type":"journal-article","created":{"date-parts":[[2020,12,10]],"date-time":"2020-12-10T22:15:36Z","timestamp":1607638536000},"page":"5796","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Cyanide Complexes Based on {Mo6I8}4+ and {W6I8}4+ Cluster Cores"],"prefix":"10.3390","volume":"25","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4663-3714","authenticated-orcid":false,"given":"Aleksei S.","family":"Pronin","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Spartak S.","family":"Yarovoy","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6378-0409","authenticated-orcid":false,"given":"Yakov M.","family":"Gayfulin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aleksey A.","family":"Ryadun","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin A.","family":"Brylev","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2688-4521","authenticated-orcid":false,"given":"Denis G.","family":"Samsonenko","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. 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Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2331","DOI":"10.1002\/ejic.201402076","article-title":"Hexamolybdenum Cluster Complexes with Pyrene and Anthracene Carboxylates: Ultrabright Red Emitters with the Antenna Effect","volume":"2014","author":"Kirakci","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1351","DOI":"10.1021\/ic00229a011","article-title":"Photophysics and Electrochemistry of Hexanuclear Tungsten Halide Clusters","volume":"25","author":"Zietlow","year":"1986","journal-title":"Inorg. Chem."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1878","DOI":"10.1021\/ja00345a034","article-title":"Spectroscopic, Electrochemical, and Photochemical Properties of Molybdenum(II) and Tungsten(II) Halide Clusters","volume":"105","author":"Maverick","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1131","DOI":"10.1039\/C7DT04485B","article-title":"A study on the redox, spectroscopic, and photophysical characteristics of a series of octahedral hexamolybdenum(ii) clusters: [{Mo6X8}Y6]2\u2212 (X, Y = Cl, Br, or I)","volume":"47","author":"Akagi","year":"2018","journal-title":"Dalton Trans."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"4181","DOI":"10.1002\/ejic.201900630","article-title":"Molybdenum Iodides \u2013 from Obscurity to Bright Luminescence","volume":"2019","author":"Mikhaylov","year":"2019","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"10259","DOI":"10.1021\/acs.inorgchem.6b01525","article-title":"Quasi-One-Step Six-Electron Electrochemical Reduction of an Octahedral Hexanuclear Molybdenum(II) Cluster","volume":"55","author":"Fujii","year":"2016","journal-title":"Inorg. Chem."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"2324","DOI":"10.1021\/acs.jpcc.5b12481","article-title":"Elaboration, Characterizations, and Energetics of Robust Mo6 Cluster-Terminated Silicon-Bound Molecular Junctions","volume":"120","author":"Cordier","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"270","DOI":"10.1016\/j.apcatb.2012.11.017","article-title":"One-pot synthesis of gold nanoparticle\/molybdenum cluster\/graphene oxide nanocomposite and its photocatalytic activity","volume":"130-131","author":"Barras","year":"2013","journal-title":"Appl. Catal. B Environ."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1963","DOI":"10.1002\/cssc.201600381","article-title":"In\u2005Situ Generation of Active Molybdenum Octahedral Clusters for Photocatalytic Hydrogen Production from Water","volume":"9","author":"Feliz","year":"2016","journal-title":"ChemSusChem"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.carbon.2015.06.029","article-title":"Hexamolybdenum clusters supported on graphene oxide: Visible-light induced photocatalytic reduction of carbon dioxide into methanol","volume":"94","author":"Kumar","year":"2015","journal-title":"Carbon"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"15443","DOI":"10.1021\/acs.inorgchem.9b02529","article-title":"Supramolecular Anchoring of Octahedral Molybdenum Clusters onto Graphene and Their Synergies in Photocatalytic Water Reduction","volume":"58","author":"Feliz","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"10921","DOI":"10.1002\/anie.201503205","article-title":"From Mesomorphic Phosphine Oxide to Clustomesogens Containing Molybdenum and Tungsten Octahedral Cluster Cores","volume":"54","author":"Molard","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"6021","DOI":"10.1039\/C3DT53126K","article-title":"A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials","volume":"43","author":"Efremova","year":"2014","journal-title":"Dalton Trans."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"7224","DOI":"10.1039\/c3dt32863e","article-title":"A comparative study of the redox and excited state properties of (nBu4N)2[Mo6X14] and (nBu4N)2[Mo6X8(CF3COO)6] (X. = Cl, Br, or I)","volume":"42","author":"Kirakci","year":"2013","journal-title":"Dalton Trans."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"4500","DOI":"10.1021\/j100374a029","article-title":"Oxygen quenching of electronically excited hexanuclear molybdenum and tungsten halide clusters","volume":"94","author":"Jackson","year":"1990","journal-title":"J. Phys. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"4839","DOI":"10.1039\/C6TB00723F","article-title":"Cellular internalisation, bioimaging and dark and photodynamic cytotoxicity of silica nanoparticles doped by {Mo6I8}4+ metal clusters","volume":"4","author":"Solovieva","year":"2016","journal-title":"J. Mater. Chem. B"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1670","DOI":"10.1039\/C6NJ03469A","article-title":"Water-soluble hybrid materials based on {Mo6X8}4+ (X = Cl, Br, I) cluster complexes and sodium polystyrene sulfonate","volume":"41","author":"Svezhentseva","year":"2017","journal-title":"New J. Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/j.ejpb.2018.01.007","article-title":"Molybdenum cluster loaded PLGA nanoparticles: An innovative theranostic approach for the treatment of ovarian cancer","volume":"125","author":"Brandhonneur","year":"2018","journal-title":"Eur. J. Pharm. Biopharm."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1016\/j.jinorgbio.2016.11.014","article-title":"Nanosized mesoporous metal\u2013organic framework MIL-101 as a nanocarrier for photoactive hexamolybdenum cluster compounds","volume":"166","author":"Cheplakova","year":"2017","journal-title":"J. Inorg. Biochem."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"387","DOI":"10.1016\/j.jcis.2018.12.013","article-title":"Interfacial uploading ofluminescent hexamolybdenum cluster units onto amino-decorated silica nanoparticles as new design of nanomaterial for cellular imaging and photodynamic therapy","volume":"538","author":"Elistratova","year":"2019","journal-title":"J. Colloid Interf. Sci."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"5975","DOI":"10.1039\/C6TB01966H","article-title":"A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus","volume":"4","author":"Mikhailov","year":"2016","journal-title":"J. Mater. Chem. B"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"6058","DOI":"10.1039\/C7TB01478C","article-title":"Superior performance of macroporous over gel type polystyrene as a support for the development of photo-bactericidal materials","volume":"5","author":"Miravet","year":"2017","journal-title":"J. Mater. Chem. B"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Rojas-Mancilla, E., Oyarce, A., Verdugo, V., Morales-Verdejo, C., Echeverria, C., Vel\u00e1squez, F., Chnaiderman, J., Valiente-Echeverr\u00eda, F., and Ramirez-Tagle, R. (2017). The [Mo6Cl14]2\u2212 Cluster is Biologically Secure and Has Anti-Rotavirus Activity In Vitro. Molecules, 22.","DOI":"10.3390\/molecules22071108"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"30166","DOI":"10.1039\/C6CP05290H","article-title":"Time-gated luminescence bioimaging with new luminescent nanocolloids based on [Mo6I8(C2F5COO)6]2\u2212 metal atom clusters","volume":"18","author":"Neaime","year":"2016","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1906","DOI":"10.1002\/pi.5473","article-title":"One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction","volume":"66","author":"Vorotnikova","year":"2017","journal-title":"Polym. Int."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1023\/A:1022060806724","article-title":"Inorganic Coordination Polymers Based on Chalcocyanide Cluster Complexes","volume":"43","author":"Fedorov","year":"2002","journal-title":"J. Struct. Chem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"12286","DOI":"10.1021\/acs.chemrev.5b00320","article-title":"Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks","volume":"115","author":"Alexandrov","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"2533","DOI":"10.1002\/ejic.200600178","article-title":"Design of Cyano-Bridged Coordination Polymers Based on Tetrahedral Rhenium Cluster Cyanide Complexes and 3d Transition Metals","volume":"2006","author":"Efremova","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"9813","DOI":"10.1039\/C4TC02098G","article-title":"Hexacyano octahedral metallic clusters as versatile building blocks in the design of extended polymeric framework and clustomesogens","volume":"2","author":"Cordier","year":"2014","journal-title":"J. Mater. Chem. C"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"3396","DOI":"10.1039\/C8CE00113H","article-title":"Low dimensional solids based on Mo6 cluster cyanides and Mn2+, Mn3+ or Cd2+ metal ions: Crystal chemistry, magnetic and optical properties","volume":"20","author":"Daigre","year":"2018","journal-title":"CrystEngComm"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"1311","DOI":"10.1016\/S0277-5387(00)81263-2","article-title":"Mechanochemical synthesis of soluble complexes containing M3S74+ and M3Se74+ fragments from polymeric M3Y7Br4 (M. = Mo, W; Y = S, Se). The crystal structure of (PPN)2W3S7Cl6","volume":"10","author":"Fedin","year":"1991","journal-title":"Polyhedron"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"7271","DOI":"10.1021\/ic800613d","article-title":"Synthesis and Study of Hexanuclear Molybdenum Clusters Containing Thiolate Ligands","volume":"47","author":"Szczepura","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1016\/j.ica.2015.10.043","article-title":"Water-soluble octahedral molybdenum cluster compounds Na2[Mo6I8(N3)6] and Na2[Mo6I8(NCS)6]: Syntheses, luminescence, and in vitro studies","volume":"441","author":"Kirakci","year":"2016","journal-title":"Inorg. Chim. Acta"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1016\/j.molstruc.2016.12.052","article-title":"Hexaazide octahedral molybdenum cluster complexes: Synthesis, properties and the evidence of hydrolysis","volume":"1134","author":"Vorotnikov","year":"2017","journal-title":"J. Mol. Struct."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"16546","DOI":"10.1021\/acs.inorgchem.9b02569","article-title":"Phosphinate Apical Ligands: A Route to a Water-Stable Octahedral Molybdenum Cluster Complex","volume":"58","author":"Kirakci","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"17915","DOI":"10.1002\/chem.201804663","article-title":"From Photoinduced to Dark Cytotoxicity through an Octahedral Cluster Hydrolysis","volume":"24","author":"Svezhentseva","year":"2018","journal-title":"Chem. Eur. J."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/j.jhazmat.2012.03.058","article-title":"Root uptake and phytotoxicity of nanosized molybdenum octahedral clusters","volume":"219\u2013220","author":"Aubert","year":"2012","journal-title":"J. Hazard. Mater."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"15427","DOI":"10.1039\/C6DT02863B","article-title":"Octahedral molybdenum cluster complexes with aromatic sulfonate ligands","volume":"45","author":"Efremova","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1002\/zaac.19976230103","article-title":"Darstellung, Kristallstrukturen, NMR-, Schwingungsspektren und Normalkoordinatenanalyse der Clusteranionen [(Mo6I)Y]2\u2212, Ya = F, Cl, Br, I.Z","volume":"623","author":"Preetz","year":"1997","journal-title":"Anorg. Allg. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"8437","DOI":"10.1021\/acs.inorgchem.6b01042","article-title":"Synthetic Tuning of Redox, Spectroscopic, and Photophysical Properties of {Mo6I8}4+ Core Cluster Complexes by Terminal Carboxylate Ligands","volume":"55","author":"Mikhailov","year":"2016","journal-title":"Inorg. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1885","DOI":"10.1002\/zaac.19976231211","article-title":"Darstellung, Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalyse von [(Mo6Br)Y]2\u2212; Ya = CN, NCS","volume":"623","author":"Simsek","year":"1997","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1021\/ic034443q","article-title":"Synthesis and Characterization of Mo6 Chalcobromides and Cyano-Substituted Compounds Built from a Novel [(Mo6Bri6Yi2)La6]n- Discrete Cluster Unit (Yi = S or Se and La = Br or CN)","volume":"43","author":"Cordier","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"2177","DOI":"10.1002\/ejic.202000204","article-title":"Hexasubstituted Iodide Tungsten Cluster Complexes with Azide and Isothiocyanate Ligands","volume":"2020","author":"Petunin","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"15500","DOI":"10.1039\/C6DT02471H","article-title":"A ligand substituted tungsten iodide cluster: Luminescence vs. singlet oxygen production","volume":"45","author":"Riehl","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1134\/S1070328419010081","article-title":"Methyl Propiolate Cluster Complex (Ph4P)2[W6I8(C\u2261C\u2013C(O)OCH3)6]","volume":"45","author":"Mikhailov","year":"2019","journal-title":"Russ. J. Coord. Chem."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"28574","DOI":"10.1039\/C5CP03960F","article-title":"Combined theoretical and time-resolved photoluminescence investigations of [Mo6Bri8Bra6]2\u2212 metal cluster units: Evidence of dual emission","volume":"17","author":"Costuas","year":"2015","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"2581","DOI":"10.1002\/chem.200800152","article-title":"Divergent Electronic Structures of Isoelectronic Metalloclusters: Tungsten(II) Halides and Rhenium(III) Chalcogenide Halides","volume":"15","author":"Gray","year":"2009","journal-title":"Chem. Eur. J."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"438","DOI":"10.1016\/j.cplett.2008.06.035","article-title":"Electronic structure and molecular properties of the [Mo6X8L6]2\u2212; X=Cl, Br, I.; L=F, Cl, Br, I clusters","volume":"460","year":"2008","journal-title":"Chem. Phys. Lett."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"5588","DOI":"10.1021\/ic00126a032","article-title":"Effect of Coordination Environment on the Electronic Structure and Properties of Mo6-Based Systems: A Density Functional Treatment","volume":"34","author":"Robinson","year":"1995","journal-title":"Inorg. Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"6375","DOI":"10.1039\/c1dt10376h","article-title":"Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2\u2013 (X = Br, I)","volume":"40","author":"Sokolov","year":"2011","journal-title":"Dalton Trans."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"12477","DOI":"10.1021\/ic401377g","article-title":"Alkynyl complexes of high-valence clusters. Synthesis and luminescence properties of [Mo6I8(C\u2261CC(O)OMe)6]2\u2013, the first complex with exclusively organometallic outer ligands in the family of octahedral {M6X8} clusters","volume":"52","author":"Sokolov","year":"2013","journal-title":"Inorg. Chem."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"11738","DOI":"10.1039\/C7DT01919J","article-title":"A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes","volume":"46","author":"Evtushok","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1002\/zaac.200400281","article-title":"Synthesis and Characterization of Cs2Mo6X14 (X = Br or I) Hexamolybdenum Cluster Halides: Efficient Mo6 Cluster Precursors for Solution Chemistry Syntheses","volume":"631","author":"Kirakci","year":"2005","journal-title":"Z. Anorg. Allg. Chem."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2591","DOI":"10.1007\/s11172-015-1194-x","article-title":"Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(\u00b53-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)","volume":"64","author":"Vorotnikov","year":"2015","journal-title":"Russ. Chem. Bull."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"1354","DOI":"10.1021\/ic50088a012","article-title":"Chemistry of polynuclear metal halides. V. Reactions and characterization of compounds containing tungsten halide cluster species","volume":"9","author":"Hogue","year":"1970","journal-title":"Inorg. Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"2449","DOI":"10.1016\/j.ccr.2010.04.006","article-title":"Recent advances in instrumentation for absolute emission quantum yield measurements","volume":"254","author":"Ishida","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"ref_59","unstructured":"(2018). CrysAlisPro 1.171.39.46, Rigaku Oxford Diffraction."},{"key":"ref_60","unstructured":"APEX3, SAINT, and SADABS (2016). Bruker Advanced X-ray Solutions, Bruker AXS Inc."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT-Integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal structure refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"931","DOI":"10.1002\/jcc.1056","article-title":"Chemistry with ADF","volume":"22","author":"Bickelhaupt","year":"2001","journal-title":"J. Comput. Chem."},{"key":"ref_64","first-page":"391","article-title":"Towards an order-N DFT method","volume":"99","author":"Snijders","year":"1998","journal-title":"Theor. Chem. Acc."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"1200","DOI":"10.1139\/p80-159","article-title":"Accurate spin-dependent electron liquid correlation energies for local spin density calculations: A critical analysis","volume":"58","author":"Vosko","year":"1980","journal-title":"Can. J. Phys."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"13244","DOI":"10.1103\/PhysRevB.45.13244","article-title":"Accurate and simple analytic representation of the electron-gas correlation energy","volume":"45","author":"Perdew","year":"1992","journal-title":"Phys. Rev. B"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.cplett.2013.06.045","article-title":"A new family of hybrid density functionals","volume":"580","author":"Swart","year":"2013","journal-title":"Chem. Phys. Lett."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1142","DOI":"10.1002\/jcc.10255","article-title":"Optimized Slater-type basis sets for the elements 1\u2013118","volume":"24","author":"Baerends","year":"2003","journal-title":"J. Comput. Chem."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"8943","DOI":"10.1063\/1.478813","article-title":"Geometry optimizations in the zero order regular approximation for relativistic effects","volume":"110","author":"Ehlers","year":"1999","journal-title":"J. Chem. Phys."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"396","DOI":"10.1007\/s002140050457","article-title":"An implementation of the conductor-like screening model of solvation within the Amsterdam density functional package","volume":"101","author":"Pye","year":"1999","journal-title":"Theor. Chem. 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