{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T04:19:57Z","timestamp":1787977197841,"version":"build-2784847793"},"reference-count":96,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2021,1,18]],"date-time":"2021-01-18T00:00:00Z","timestamp":1610928000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001634","name":"NUI Galway","doi-asserted-by":"publisher","award":["College of Science scholarship"],"award-info":[{"award-number":["College of Science scholarship"]}],"id":[{"id":"10.13039\/501100001634","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The simultaneous use of 2-pyridyl oximes (pyridine-2 amidoxime, H2pyaox; 2-methyl pyridyl ketoxime, Hmpko) and 1,3,5-benzenetricarboxylic acid (H3btc) provided access to five new compounds, namely [Zn(H2btc)2(H2pyaox)2]\u20222H2O (1\u20222H2O), [Zn(Hbtc)(H2pyaox)2]n (2), [Cu(Hbtc)(H2pyaox)]n (3), [Cu(Hbtc)(HmpKo)]n (4) and [Cu2(Hbtc)2(Hmpko)2(H2O)2]\u20224H2O (5\u20224H2O). Among them, 3 is the first example of a metal-organic framework (MOF) containing H2pyaox. Its framework can be described as a 3-c uninodal net of hcb topology with the layers being parallel to the (1,0,1) plane. Furthermore, 3 is the third reported MOF based on a 2-pyridyl oxime in general. 2 and 4 are new members of a small family of coordination polymers containing an oximic ligand. 1\u20135 form 3D networks through strong intermolecular interactions. Dc magnetic susceptibility studies were carried out in a crystalline sample of 3 and revealed the presence of weak exchange interactions between the metal centres; the experimental data were fitted to a theoretical model with the fitting parameters being J = \u22120.16(1) cm\u22121 and g = 2.085(1). The isotropic g value was also confirmed by electronic paramagnetic resonance (EPR) spectroscopy. Reactivity studies were performed for 3 in the presence of metal ions; the reaction progress was studied and discussed for Fe(NO3)3 by the use of several characterization techniques, including single crystal X-ray crystallography and IR spectroscopy.<\/jats:p>","DOI":"10.3390\/molecules26020491","type":"journal-article","created":{"date-parts":[[2021,1,19]],"date-time":"2021-01-19T11:39:55Z","timestamp":1611056395000},"page":"491","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["ZnII and CuII-Based Coordination Polymers and Metal Organic Frameworks by the of Use of 2-Pyridyl Oximes and 1,3,5-Benzenetricarboxylic Acid"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6676-4749","authenticated-orcid":false,"given":"Ioannis","family":"Mylonas-Margaritis","sequence":"first","affiliation":[{"name":"School of Chemistry, College of Science and Engineering, National University of Ireland Galway, University Road, H91 TK33 Galway, Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8875-8075","authenticated-orcid":false,"given":"Julia","family":"Mayans","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedr\u00e1tico Jos\u00e9 Beltran 2, 46980 Paterna Valencia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick","family":"McArdle","sequence":"additional","affiliation":[{"name":"School of Chemistry, College of Science and Engineering, National University of Ireland Galway, University Road, H91 TK33 Galway, Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Constantina","family":"Papatriantafyllopoulou","sequence":"additional","affiliation":[{"name":"School of Chemistry, College of Science and Engineering, National University of Ireland Galway, University Road, H91 TK33 Galway, Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,1,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"7169","DOI":"10.1021\/jacs.5b02688","article-title":"Ultrastable Polymolybdate-Based Metal\u2013Organic Frameworks as Highly Active Electrocatalysts for Hydrogen Generation from Water","volume":"137","author":"Qin","year":"2015","journal-title":"J. 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