{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T01:45:10Z","timestamp":1760233510363,"version":"build-2065373602"},"reference-count":40,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2021,1,21]],"date-time":"2021-01-21T00:00:00Z","timestamp":1611187200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002261","name":"Russian Foundation for Basic Research","doi-asserted-by":"publisher","award":["19-33-50136","18-33-20056"],"award-info":[{"award-number":["19-33-50136","18-33-20056"]}],"id":[{"id":"10.13039\/501100002261","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Reaction of heterometallic cubane-type cluster complexes\u2014[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba\u2014dibenzylideneacetone, dbbpy\u20144,4\u2032-di-tert-butyl-2,2\u2032-bipyridine, tu\u2014thiourea, acac\u2014acetylacetonate, py\u2014pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.<\/jats:p>","DOI":"10.3390\/molecules26030538","type":"journal-article","created":{"date-parts":[[2021,1,21]],"date-time":"2021-01-21T09:49:21Z","timestamp":1611222561000},"page":"538","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}"],"prefix":"10.3390","volume":"26","author":[{"given":"Airat M.","family":"Kuchkaev","sequence":"first","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4845-2674","authenticated-orcid":false,"given":"Nikita Y.","family":"Shmelev","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, Pirogov Str. 2, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aidar M.","family":"Kuchkaev","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aleksandr V.","family":"Sukhov","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3918-7031","authenticated-orcid":false,"given":"Vasily M.","family":"Babaev","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2913-5120","authenticated-orcid":false,"given":"Khasan R.","family":"Khayarov","sequence":"additional","affiliation":[{"name":"Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3214-1433","authenticated-orcid":false,"given":"Artem L.","family":"Gushchin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9361-4594","authenticated-orcid":false,"given":"Maxim N.","family":"Sokolov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, Pirogov Str. 2, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oleg G.","family":"Sinyashin","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3906-8841","authenticated-orcid":false,"given":"Dmitry G.","family":"Yakhvarov","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,1,21]]},"reference":[{"key":"ref_1","unstructured":"Yakhvarov, D.G., Kagirov, R.M., and Sinyashin, O.G. (2011). Method of Producing Phosphorous Acid from White Phosphorus. (2460687), Russian Patent."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1116","DOI":"10.1007\/s11172-010-0213-1","article-title":"Activation and transformation of white phosphorus by palladium(II) complexes","volume":"59","author":"Kagirov","year":"2010","journal-title":"Russ. Chem. Bull."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1016\/j.mencom.2011.07.010","article-title":"Selective synthesis of nanosized palladium phosphides from white phosphorus","volume":"21","author":"Kagirov","year":"2011","journal-title":"Mendeleev Commun."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"935","DOI":"10.1016\/j.crci.2010.07.004","article-title":"d6 metal systems for white phosphorus activation","volume":"13","author":"Peruzzini","year":"2010","journal-title":"Comptes Rendus Chim."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Di Vaira, M., Frediani, P., Costantini, S.S., Peruzzini, M., and Stoppioni, P. (2005). Easy hydrolysis of white phosphorus coordinated to ruthenium. Dalton Trans., 2234\u20132236.","DOI":"10.1039\/b504795a"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"4425","DOI":"10.1002\/anie.200800723","article-title":"Controlling the activation of white phosphorus: Formation of phosphorous acid and ruthenium-coordinated 1-hydroxytriphosphane by hydrolysis of doubly metalated P4","volume":"47","author":"Barbaro","year":"2008","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.jorganchem.2012.03.019","article-title":"The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis","volume":"714","author":"Caporali","year":"2012","journal-title":"J. Organomet. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","unstructured":"Akbayeva, D.N., Di Vaira, M., Seniori Costantini, S., Peruzzini, M., and Stoppioni, P. (2006). Stabilization of the tautomers HP(OH)2 and P(OH)3 of hypophosphorous and phosphorous acids as ligands. Dalton Trans., 389\u2013395.","DOI":"10.1039\/B510479C"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"8287","DOI":"10.1021\/ja00047a048","article-title":"Synthesis of Mixed-Metal Sulfido Clusters with a Cuboidal Mo3PdS4 Core Which Coordinate Alkene to the Unique Palladium Site Surrounded by Sulfido Ligands","volume":"114","author":"Murata","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"3389","DOI":"10.1021\/ja00087a025","article-title":"Syntheses of Mixed-Metal Sulfide Cubane-Type Clusters with the Novel PdMo3S4 Core and Reactivities of the Unique Tetrahedral Pd Site Surrounded by Sulfide Ligands toward Alkenes, CO, tBuNC, and Alkynes","volume":"116","author":"Murata","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"670","DOI":"10.1070\/RCR4800","article-title":"Tri- and tetranuclear molybdenum and tungsten chalcogenide clusters: On the way to new materials and catalysts","volume":"87","author":"Gushchin","year":"2018","journal-title":"Russ. Chem. Rev."},{"key":"ref_12","unstructured":"McCleverty, J.A., and Meyer, T.J. (2004). Comprehensive Coordination Chemistry II, Elsevier Ltd."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"974","DOI":"10.1021\/ic0205379","article-title":"A complete family of isostructural cluster compounds with cubane-like M3S4M\u2032 cores (M = Mo, W; M\u2032 = Ni, Pd, Pt): Comparative crystallography and electrochemistry","volume":"42","author":"Herbst","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1021\/ar960152s","article-title":"Behavioral Patterns of Heterometallic Cuboidal Derivatives of [M3Q4(H2O)9]4+ (M = Mo, W; Q = S, Se)","volume":"34","author":"Sokolov","year":"2001","journal-title":"Acc. Chem. Res."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"847","DOI":"10.1039\/c0sc00545b","article-title":"Catalytic functions of cubane-type M4S4 clusters","volume":"2","author":"Seino","year":"2011","journal-title":"Chem. Sci."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1579","DOI":"10.1039\/b817509h","article-title":"Combined kinetic and DFT studies on the stabilization of the pyramidal form of H3PO2 at the heterometal site of [Mo3M\u2032S4(H2O)10]4+ clusters (M\u2032 = Pd, Ni)","volume":"4","author":"Algarra","year":"2009","journal-title":"Dalton Trans."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Kryuchkova, N.A., Ryzhikov, M.R., and Syrokvashin, M.M. (2020). Interatomic Interactions in Heterometallic Cubane-Type Clusters with {Mo3S4M\u2032} (M\u2032 = Cu, Ni, Pd) Core. J. Clust. Sci.","DOI":"10.1007\/s10876-020-01800-z"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1336","DOI":"10.1021\/ic011108y","article-title":"Molecular metal sulfide cluster model for substrate binding to oil-refinery hydrodesulfurization catalysts","volume":"41","author":"Herbst","year":"2002","journal-title":"Inorg. Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/0010-8545(93)85053-7","article-title":"Syntheses of sulphur-bridged molybdenum and tungsten coordination compounds","volume":"123","author":"Shibahara","year":"1993","journal-title":"Coord. Chem. Rev."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1021\/ar990016y","article-title":"Synthesis and reactivities of cubane-type sulfido clusters containing noble metals","volume":"33","author":"Hidai","year":"2000","journal-title":"Acc. Chem. Res."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Llusar, R., and Vicent, C. (2006). Trinuclear Molybdenum and Tungsten Cluster Chalcogenides: From Solid State to Molecular Materials. Inorg. Chem. Focus III, 105\u2013120.","DOI":"10.1002\/9783527609932.ch7"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"4582","DOI":"10.1002\/chem.200802473","article-title":"Unprecedented Solvent-assisted reactivity of hydrido W3CuS4 cubane clusters: The Non-innocent behaviour of the Cluster-core unit","volume":"15","author":"Algarra","year":"2009","journal-title":"Chem. A Eur. J."},{"key":"ref_23","doi-asserted-by":"crossref","unstructured":"Laricheva, Y.A., Shmelev, N.Y., Gushchin, A.L., and Sokolov, M.N. (2021). The study of the interaction of fullerene C60 with palladium-containing molybdenum clusters {CS4} by spectroscopic and calculation methods. Russ. J. Coord. Chem., in press.","DOI":"10.1134\/S1070328421020032"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2942","DOI":"10.1021\/jo2024812","article-title":"Friedel-crafts-type allylation of nitrogen-containing aromatic compounds with allylic alcohols catalyzed by a [Mo3S4Pd(\u03b7 3-allyl)] cluster","volume":"77","author":"Tao","year":"2012","journal-title":"J. Org. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"2726","DOI":"10.1021\/ol100805c","article-title":"Highly efficient and regioselective allylation with allylic alcohols catalyzed by [Mo3S4Pd(\u03b73-allyl)] clusters","volume":"12","author":"Tao","year":"2010","journal-title":"Org. Lett."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1982","DOI":"10.1016\/j.tetlet.2010.02.017","article-title":"Highly efficient and regioselective allylic amination of allylic alcohols catalyzed by [Mo3PdS4] cluster","volume":"51","author":"Tao","year":"2010","journal-title":"Tetrahedron Lett."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2123","DOI":"10.1002\/anie.199621231","article-title":"A Novel Catalyst with a Cuboidal PdMo3S4 Core for the Cyclization of Alkynoic Acids to Enol Lactones","volume":"35","author":"Wakabayashi","year":"1996","journal-title":"Angew. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"4816","DOI":"10.1021\/ic015520p","article-title":"Phosphorous acid and arsenious acid as ligands","volume":"40","author":"Sokolov","year":"2001","journal-title":"Inorg. Chem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1023\/B:JOCL.0000005060.12513.23","article-title":"Reactivity of Mo3PdS44+ cluster: Evidence for new ligands PhP(OH)2 and Ph2P(OH) and structural characterization of [Mo3(Pd(PPh3))S4(H2O)5Cl4]\u00b70.5CH3OH\u00b73H2O","volume":"14","author":"Sokolov","year":"2003","journal-title":"J. Clust. Sci."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"11","DOI":"10.2116\/xraystruct.30.11","article-title":"X-ray Structure Analysis Online Synthesis and Crystal Structure of a Sulfur-bridged Incomplete Cubane-type Molybdenum Cluster with a Tris(pyrazolyl)methanesulfonate Ligand","volume":"30","author":"Oriwaki","year":"2014","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"5230","DOI":"10.1021\/acs.inorgchem.9b00309","article-title":"Synthesis of [Mo3S4] Clusters from Half-Sandwich Molybdenum(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes","volume":"58","author":"Ohki","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"13205","DOI":"10.1002\/chem.201702783","article-title":"Efficient and Selective N-Methylation of Nitroarenes under Mild Reaction Conditions","volume":"23","author":"Pedrajas","year":"2017","journal-title":"Chem. A Eur. J."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"17138","DOI":"10.1002\/chem.201804083","article-title":"Cubane-Type [Mo3S4M] Clusters with First-Row Groups 4\u201310 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum","volume":"24","author":"Ohki","year":"2018","journal-title":"Chem. A Eur. J."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1134\/S1070328419040079","article-title":"Phosphine-substituted Cubane Clusters with the Mo3S4Ga Core","volume":"45","author":"Petrov","year":"2019","journal-title":"Russ. J. Coord. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"748","DOI":"10.1007\/s10947-008-0105-5","article-title":"Crystal structure of K2[Mo3(PdPPh3)S4(C2O4)3(H2O)3]\u00b70.5H2O","volume":"49","author":"Gushchin","year":"2008","journal-title":"J. Struct. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"202","DOI":"10.1016\/j.poly.2018.07.039","article-title":"Novel mixed-metal cubane-type {Mo3NiS4} and {Mo3PdS4} clusters coordinated with 2,2\u2032-bipyridine type ligands","volume":"154","author":"Laricheva","year":"2018","journal-title":"Polyhedron"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"9912","DOI":"10.1021\/acs.inorgchem.6b01878","article-title":"Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4\u2032-Di-tert-butyl-2,2\u2032-bipyridine","volume":"55","author":"Algarra","year":"2016","journal-title":"Inorg. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/S0022-328X(00)91277-4","article-title":"Chemistry of dibenzylideneacetone-palladium(0) complexes. Novel tris(dibenzylideneacetone)dipalladium(solvent) complexes and their reactions with quinones","volume":"65","author":"Ukai","year":"1974","journal-title":"J. Organomet. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"7872","DOI":"10.1039\/C6NJ01787H","article-title":"Cycloaddition of alkynes to diimino Mo3S4 cubane-type clusters: A combined experimental and theoretical approach","volume":"40","author":"Laricheva","year":"2016","journal-title":"New J. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/S0020-1693(01)00746-0","article-title":"Preparation and characterization of triangular clusters [M3Q4(acac)3(py)3]+ (M = Mo, W; Q = S, Se)","volume":"331","author":"Sokolov","year":"2002","journal-title":"Inorganica Chim. Acta"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/26\/3\/538\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T05:13:23Z","timestamp":1760159603000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/26\/3\/538"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,21]]},"references-count":40,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2021,2]]}},"alternative-id":["molecules26030538"],"URL":"https:\/\/doi.org\/10.3390\/molecules26030538","relation":{},"ISSN":["1420-3049"],"issn-type":[{"type":"electronic","value":"1420-3049"}],"subject":[],"published":{"date-parts":[[2021,1,21]]}}}