{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T20:34:26Z","timestamp":1792787666924,"version":"4.5.0"},"reference-count":61,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2021,6,30]],"date-time":"2021-06-30T00:00:00Z","timestamp":1625011200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR SLOW-2"],"award-info":[{"award-number":["ANR SLOW-2"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>AB5 compounds issued from the reactivity of hexachlorocyclotriphosphazene are relatively easy to obtain using two ways: either first the reaction of one chloride with one reagent, followed by the reaction of the five remaining Cl with another reagent, or first the reaction of five chlorides with one reagent, followed by the reaction of the single remaining Cl with another reagent. This particular property led to the use of such compounds as core for the synthesis of dendrons (dendritic wedges), using the five functions for growing the dendritic branches. The single function can be used for the synthesis of diverse types of dendrimers (onion peel, dumbbell-shape, Janus), for covalent or non-covalent grafting to solid surfaces, providing nanomaterials, for grafting a fluorophore, especially for studying biological mechanisms, or for self-associations to get micelles. All these properties are reviewed in this paper.<\/jats:p>","DOI":"10.3390\/molecules26134017","type":"journal-article","created":{"date-parts":[[2021,6,30]],"date-time":"2021-06-30T10:03:19Z","timestamp":1625047399000},"page":"4017","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["AB5 Derivatives of Cyclotriphosphazene for the Synthesis of Dendrons and Their Applications"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2837-3728","authenticated-orcid":false,"given":"Artem","family":"Zibarov","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, 31077 Toulouse, CEDEX 4, France"},{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 31077 Toulouse, CEDEX 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdelouahd","family":"Oukhrib","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, 31077 Toulouse, CEDEX 4, France"},{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 31077 Toulouse, CEDEX 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julien","family":"Aujard Catot","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, 31077 Toulouse, CEDEX 4, France"},{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 31077 Toulouse, CEDEX 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C\u00e9dric-Olivier","family":"Turrin","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, 31077 Toulouse, CEDEX 4, France"},{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 31077 Toulouse, CEDEX 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8487-3578","authenticated-orcid":false,"given":"Anne-Marie","family":"Caminade","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie de Coordination du CNRS, 205 Route de Narbonne, 31077 Toulouse, CEDEX 4, France"},{"name":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 31077 Toulouse, CEDEX 4, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,6,30]]},"reference":[{"key":"ref_1","first-page":"139","article-title":"Nachtrag der redaction","volume":"11\u201312","author":"Liebig","year":"1834","journal-title":"Ann. 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