{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T16:26:35Z","timestamp":1791390395551,"version":"4.3.3"},"reference-count":58,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2021,8,18]],"date-time":"2021-08-18T00:00:00Z","timestamp":1629244800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100008993","name":"Sveu\u010dili\u0161te u Zagrebu","doi-asserted-by":"publisher","award":["118120281106"],"award-info":[{"award-number":["118120281106"]}],"id":[{"id":"10.13039\/100008993","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003415","name":"Ministarstvo Obrazovanja, Znanosti i Sporta","doi-asserted-by":"publisher","award":["119-1193079-1332"],"award-info":[{"award-number":["119-1193079-1332"]}],"id":[{"id":"10.13039\/501100003415","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Three new mercury(II) coordination compounds, {[HgCl(pic)]}n (1), [HgCl(pic)(picH)] (2), and [HgBr(pic)(picH)] (3) (picH = pyridine-2-carboxylic acid, picolinic acid) were prepared by reactions of the corresponding mercury(II) halides and picolinic acid in an aqueous (1) or alcohol\u2013methanol or ethanol (2 and 3) solutions. Two different types of coordination compounds were obtained depending on the solvent used. The crystal structures were determined by the single-crystal X-ray structural analysis. Compound 1 is a one-dimensional (1-D) coordination polymer with mercury(II) ions bridged by chelating and bridging N,O,O\u2032-picolinate ions. Each mercury(II) ion is four-coordinated with a bidentate picolinate ion, a carboxylate O atom from the symmetry-related picolinate ion and with a chloride ion; the resulting coordination environment can be described as a highly distorted tetrahedron. Compounds 2 and 3 are isostructural mononuclear coordination compounds, each mercury(II) ion being coordinated with the respective halide ion, N,O-bidentate picolinate ion, and N,O-bidentate picolinic acid in a highly distorted square-pyramidal coordination environment. Compounds 1\u20133 were characterized by IR spectroscopy, PXRD, and thermal methods (TGA\/DSC) in the solid state and by 1H and 13C NMR spectroscopy in the DMSO solution.<\/jats:p>","DOI":"10.3390\/molecules26165002","type":"journal-article","created":{"date-parts":[[2021,8,18]],"date-time":"2021-08-18T10:54:35Z","timestamp":1629284075000},"page":"5002","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["The Solvent Effect on Composition and Dimensionality of Mercury(II) Complexes with Picolinic Acid"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4206-8209","authenticated-orcid":false,"given":"\u017deljka","family":"Soldin","sequence":"first","affiliation":[{"name":"Division of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9582-404X","authenticated-orcid":false,"given":"Boris-Marko","family":"Kukovec","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, Faculty of Chemistry and Technology, University of Split, Ru\u0111era Bo\u0161kovi\u0107a 35, HR-21000 Split, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4909-8312","authenticated-orcid":false,"given":"Dubravka","family":"Matkovi\u0107-\u010calogovi\u0107","sequence":"additional","affiliation":[{"name":"Division of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1122-8284","authenticated-orcid":false,"given":"Zora","family":"Popovi\u0107","sequence":"additional","affiliation":[{"name":"Division of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,8,18]]},"reference":[{"key":"ref_1","first-page":"001","article-title":"Emerging Trends in Coordination Polymers and Metal-Organic Frameworks: Perspectives, Synthesis, Properties and Applications","volume":"1","author":"Sunday","year":"2018","journal-title":"Arch. Org. Inorg. Chem. Sci."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1882","DOI":"10.1016\/j.ccr.2009.02.018","article-title":"Structures and properties of mercury(II) coordination polymers","volume":"253","author":"Morsali","year":"2009","journal-title":"Coord. Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2156","DOI":"10.1002\/ejic.200400937","article-title":"Pyridine- and Imidazoledicarboxylates of Zinc: Hydrothermal Synthesis, Structure, and Properties","volume":"2005","author":"Mahata","year":"2005","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1043","DOI":"10.1016\/j.msec.2019.01.058","article-title":"Quinoline-derivative coordination compounds as potential applications to antibacterial and antineoplasic drugs","volume":"98","author":"Fonseca","year":"2019","journal-title":"Mater. Sci. Eng. C"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"7110","DOI":"10.1021\/ja042802q","article-title":"Design, synthesis, structure, and gas (N2, Ar, CO2, CH4, and H2) sorption properties of porous metal-organic tetrahedral and heterocuboidal polyhedra","volume":"127","author":"Sudik","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"ref_6","doi-asserted-by":"crossref","unstructured":"Fang, Q.-R., Zhu, G.-S., Xue, M., Sun, J.-Y., and Qiu, S.-L. (2006). Porous coordination polymers with zeolite topologies constructed from 4-connected building units. Dalton Trans., 2399\u20132402.","DOI":"10.1039\/b517400g"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1594","DOI":"10.1002\/ejic.200500808","article-title":"Fe(Cu)-Containing Coordination Polymers: Syntheses, Crystal Structures, and Applications as Benzyl Alcohol Oxidation Catalysts","volume":"2006","author":"Han","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/j.poly.2007.08.046","article-title":"New N-heterocyclic carbene mercury(II) and silver(I) complexes","volume":"27","author":"Liu","year":"2008","journal-title":"Polyhedron"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"3136","DOI":"10.1016\/j.jssc.2006.05.046","article-title":"Four triazole-bridging coordination polymers containing (m-phenol)-1,2,4-triazole: Syntheses, structures and properties of fluorescence and magnetism","volume":"179","author":"Liu","year":"2006","journal-title":"J. Solid State Chem."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1134\/S0022476614040167","article-title":"Fluorescence and crystal structures of new mercury(II) macrocyclic N-heterocyclic carbene complexes with ether chains","volume":"55","author":"Wang","year":"2014","journal-title":"J. Struct. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"2029","DOI":"10.1039\/c0ce00624f","article-title":"Structure and fluorescent properties of mercury(II) pyridine-2,3-dicarboxylate coordination polymers tuned by ancillary ligands and alkaline-earth metal ions","volume":"13","author":"Chen","year":"2011","journal-title":"CrystEngComm"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1062","DOI":"10.1039\/b707228g","article-title":"Counter-ion influence on the coordination mode of the 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (bpo) ligand in mercury(II) coordination polymers, [Hg(bpo)nX2]: X = I\u2212, Br\u2212, SCN\u2212, N3\u2212 and NO2\u2212; spectroscopic, thermal, fluorescence and structural studies","volume":"9","author":"Mahmoudi","year":"2007","journal-title":"CrystEngComm"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"2743","DOI":"10.1021\/cm0103545","article-title":"Two luminescent coordination polymers with a triple-helix structure: HgX2(C31H24N2)\u00b7CH2Cl2(X = Cl and Br)","volume":"13","author":"Ciurtin","year":"2001","journal-title":"Chem. Mater."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"2735","DOI":"10.1016\/j.poly.2009.05.040","article-title":"Various coordination modes in mercury(II) complexes with quinoline-2-carboxylic acid: Preparation and structural characterization","volume":"28","author":"Soldin","year":"2009","journal-title":"Polyhedron"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1184","DOI":"10.1016\/j.inoche.2004.09.003","article-title":"A novel one-dimensional helical chain polymer involving both tetra- and hexacoordinate mercury(II) ions","volume":"7","author":"Morsali","year":"2004","journal-title":"Inorg. Chem. Commun."},{"key":"ref_16","first-page":"m165","article-title":"Polymeric \u03bc-bromo-\u03bc-pyridine-3-carboxylato-\u03ba3O,O\u2032:N-mercury(II)","volume":"C59","author":"Soldin","year":"2003","journal-title":"Acta Crystallogr."},{"key":"ref_17","first-page":"m272","article-title":"Iodo(picolinato-\u03ba2N,O)(picolinic acid-\u03ba2N,O)mercury(II)","volume":"C62","author":"Soldin","year":"2006","journal-title":"Acta Crystallogr."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2080","DOI":"10.1007\/s10904-018-0852-5","article-title":"A design of mercury(II) coordination polymers with pyridinedicarboxylic acids: Structural, spectroscopic and thermal studies","volume":"28","author":"Soldin","year":"2018","journal-title":"J. Inorg. Organomet. Polym."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1071\/CH18146","article-title":"Hydrogen-bonded frameworks of mercury(II) complexes with pyridinedicarboxylic acids","volume":"71","author":"Soldin","year":"2018","journal-title":"Aust. J. Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1016\/j.arabjc.2016.01.003","article-title":"Dependence of solvents, pH, molar ratio and temperature in tuning metal organic framework architecture","volume":"12","author":"Seetharaj","year":"2019","journal-title":"Arab. J. Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3407","DOI":"10.3390\/ma3053407","article-title":"Of Chains and Rings: Synthetic Strategies and Theoretical Investigations for Tuning the Structure of Silver Coordination Compounds and Their Applications","volume":"3","author":"Slenters","year":"2010","journal-title":"Materials"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1454","DOI":"10.1039\/C8CC09152H","article-title":"Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks","volume":"55","author":"Sanii","year":"2019","journal-title":"Chem. Commun."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"15014","DOI":"10.1039\/C8NJ02110D","article-title":"The effect of solvent on one-dimensional cadmium coordination polymers","volume":"42","author":"Notash","year":"2018","journal-title":"New J. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1271","DOI":"10.1021\/ic001012o","article-title":"The effect of pH on the dimensionality of coordination polymers","volume":"40","author":"Pan","year":"2001","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1039\/b417413e","article-title":"New trends in crystal engineering","volume":"7","author":"Braga","year":"2005","journal-title":"CrystEngComm"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1039\/b313412c","article-title":"Developments in inorganic crystal engineering","volume":"33","author":"Brammer","year":"2004","journal-title":"Chem. Soc. Rev."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"8342","DOI":"10.1002\/anie.200700534","article-title":"Crystal engineering: A holistic view","volume":"46","author":"Desiraju","year":"2007","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2410","DOI":"10.1126\/science.1070967","article-title":"Crystal engineering: From structure to function","volume":"295","author":"Hollingsworth","year":"2002","journal-title":"Science"},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Braga, D. (2003). Crystal engineering, Where from? Where to?. Chem. Commun., 2751\u20132754.","DOI":"10.1039\/b306269b"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"30","DOI":"10.1002\/ejic.201601121","article-title":"Hampered Subcomponent Self-Assembly Leads to an Aminal Ligand: Reactivity with Silver(I) and Copper(II)","volume":"2017","author":"Tessarolo","year":"2016","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1080\/15533174.2013.819913","article-title":"A Tridentate In Situ Generated Ligand Leading the Self-Assembly of a Transition Metal Coordination Polymer: Solvothermal Synthesis and Structural Characterization of 1D Cadmium Pyridine-2-Carboxylate","volume":"45","author":"Cevik","year":"2014","journal-title":"Synth. React. Inorg. Met. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"1947","DOI":"10.1002\/ejic.200400679","article-title":"Extended Structures and Magnetic Properties of Lanthanide-Copper Complexes with Picolinic Acids as Bridging Ligands","volume":"2005","author":"Wu","year":"2005","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"607","DOI":"10.1107\/S0567740874003396","article-title":"Structure cristalline du pyridine-2 carboxylate de cadmium","volume":"30","author":"Deloume","year":"1974","journal-title":"Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"105958","DOI":"10.1016\/j.solidstatesciences.2019.105958","article-title":"One-Pot hydrothermal synthesis of 1D copper (II) coordination polymers involving in-situ decarboxylation","volume":"96","author":"Ay","year":"2019","journal-title":"Solid State Sci."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4148","DOI":"10.1021\/ic0504137","article-title":"A Solvothermally in Situ Generated Mixed-ligand Approach for NLO-Active Metal\u2212Organic Framework Materials","volume":"44","author":"Wang","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1007\/s10904-012-9650-7","article-title":"Preparation of Cadmium(II) Oxide Nanoparticles from a New One-Dimensional Cadmium(II) Coordination Polymer Precursor; Spectroscopic and Thermal Analysis Studies","volume":"22","author":"Payehghadr","year":"2012","journal-title":"J. Inorg. Organomet. Polym. Mater."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"320","DOI":"10.1016\/j.inoche.2014.06.020","article-title":"Exploring the coordination chemistry of 2-picolinic acid to zinc and application of the complexes in catalytic oxidation chemistry","volume":"46","author":"Enthaler","year":"2014","journal-title":"Inorg. Chem. Commun."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1213","DOI":"10.1016\/j.ica.2007.07.020","article-title":"Structure and magnetic properties of polynuclear copper(II) compounds with syn\u2013anti carboxylato- and bromo-bridges","volume":"361","author":"Slepokura","year":"2008","journal-title":"Inorganica Chim. Acta"},{"key":"ref_39","first-page":"171","article-title":"The Cambridge Structural Database","volume":"B72","author":"Groom","year":"2016","journal-title":"Acta Crystallogr."},{"key":"ref_40","first-page":"695","article-title":"Crystal structure of catena{bis[\u03bc-(2-pyridinecarboxilato-\u03bc-O2,O1,N)]mercury(II)}, Hg((C5H4N)(CO2))2","volume":"209","author":"Piniella","year":"1994","journal-title":"Z. Kristallogr."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"1591","DOI":"10.1016\/S0277-5387(97)00298-2","article-title":"Reactions of mercury(II) with 2-pyridinecarboxylic and 6-methyl-2-pyridinecarboxylic acids and corresponding esters. Crystal structures of [Hg(C5H4NCOO)2], [HgX2(C5H4NCOOPri)], X = Br or I and [HgCl2(MeC5H3NCOOEt)]","volume":"17","author":"Leiva","year":"1998","journal-title":"Polyhedron"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/j.ica.2018.04.024","article-title":"The role of non-covalent interactions on supramolecular assembly of coordination compounds of mercury(II) based on substituted pyridine mixed ligands. A survey of different conditions on morphology of new flower and ribbon like submicro structures","volume":"479","author":"Hayati","year":"2018","journal-title":"Inorg. Chim. Acta"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/S0020-1693(97)05537-0","article-title":"Mercury(II) halide adducts of esters of 2-pyridinecarboxylic acid. Crystal structures and structural variations within the series [HgCl2(C5H4NCOOR)], R. = Me, Et, Prn, Pri","volume":"266","author":"Clegg","year":"1997","journal-title":"Inorg. Chim. Acta"},{"key":"ref_44","doi-asserted-by":"crossref","unstructured":"Yang, L., Powell, D.R., and Houser, R.P. (2007). Structural variation in copper(I) complexes with pyridylmethylamide ligands: Structural analysis with a new four-coordinate geometry index, \u03c44. Dalton Trans., 955\u2013964.","DOI":"10.1039\/B617136B"},{"key":"ref_45","doi-asserted-by":"crossref","unstructured":"Addison, A.W., Nageswara Rao, T., Reedijk, J., van Rijn, J., and Verschoor, G.C. (1984). Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen\u2013sulphur donor ligands; the crystal and molecular structure of aqua [1,7-bis(N-methylbenzimidazol-2\u2032-yl)-2,6-dithiaheptane]copper(II) perchlorate. J. Chem. Soc. Dalton Trans., 1349\u20131356.","DOI":"10.1039\/DT9840001349"},{"key":"ref_46","doi-asserted-by":"crossref","unstructured":"Janiak, C. (2000). A critical account on \u03c0\u2013\u03c0 stacking in metal complexes with aromatic nitrogen-containing ligands. J. Chem. Soc. Dalton Trans., 3885\u20133896.","DOI":"10.1039\/b003010o"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/S0022-2860(03)00247-3","article-title":"Experimental and theoretical IR and Raman spectra of picolinic, nicotinic and isonicotinic acids","volume":"655","author":"Dobrowolski","year":"2003","journal-title":"J. Mol. Struct."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1016\/0277-5387(95)00245-N","article-title":"Synthesis, spectral and structural characterization of a monomeric chloro complex of Zinc(II) with picolinic acid, [Zn(C5H4NCO2H)(C5H4NCO2)Cl]","volume":"15","author":"Goher","year":"1996","journal-title":"Polyhedron"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/0277-5387(96)00274-4","article-title":"Polymeric complexes of cadmium(II) bridged simultaneously by tetradentate picolinato and \u03bc(1,1)-azido or \u03bc(N,S)-thiocyanato anions. Synthesis and structural characterization of [Cd(picolinato)(N3)]n and [Cd(picolinato)(NCS)]n","volume":"16","author":"Mautner","year":"1997","journal-title":"Polyhedron"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"2137","DOI":"10.1016\/S0277-5387(00)83687-6","article-title":"Preparation and structural characterization of catena-\u03bc(1,3)-azido-\u03bc(O,N-picolinato)-aquamanganese(II), Mn(NC5H4CO2)(N3)(H2O)","volume":"11","author":"Goher","year":"1992","journal-title":"Polyhedron"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1016\/j.tca.2004.03.016","article-title":"Correlation of thermal and spectral properties of zinc(II) complexes of pyridinecarboxylic acids with their crystal structures","volume":"423","year":"2004","journal-title":"Thermochim. Acta"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1007\/BF02156501","article-title":"A study of solid-state thermal decomposition characteristics of some metallo-organic compounds","volume":"30","author":"Ghosh","year":"1985","journal-title":"J. Therm. Anal. Calorim."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/S0003-2670(00)80929-0","article-title":"The thermal properties of some metal pyridinecarboxylates","volume":"50","author":"Wendlandt","year":"1970","journal-title":"Anal. Chim. Acta"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1016\/S0003-2670(00)88761-9","article-title":"The determination of mercury in organic compounds","volume":"30","author":"Gouverneur","year":"1964","journal-title":"Anal. Chim. Acta"},{"key":"ref_55","unstructured":"Rikagu Oxford Diffraction (2020). CrysAlisPro, Agilent Technologies Inc."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","article-title":"SHELXT\u2013 Integrated space-group and crystal-structure determination","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. A Found. Adv."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal structure refinement withSHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. C Struct. Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","article-title":"Mercury 4.0: From visualization to analysis, design and prediction","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Crystallogr."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/26\/16\/5002\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T06:46:33Z","timestamp":1760165193000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/26\/16\/5002"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,8,18]]},"references-count":58,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2021,8]]}},"alternative-id":["molecules26165002"],"URL":"https:\/\/doi.org\/10.3390\/molecules26165002","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,8,18]]}}}