{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T22:57:50Z","timestamp":1773874670395,"version":"3.50.1"},"reference-count":60,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2021,9,7]],"date-time":"2021-09-07T00:00:00Z","timestamp":1630972800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Although there exists a variety of different catalysts for hydroboration of organic substrates such as aldehydes, ketones, imines, nitriles etc., recent evidence suggests that tetra-coordinate borohydride species, formed by activation, redistribution, or decomposition of boron reagents, are the true hydride donors. We then proposed that Me2S-BH3 could also act as a hydride donor for the reduction of various imines, as similar compounds have been observed to reduce carbonyl substrates. This boron reagent was shown to be an effective and chemoselective hydroboration reagent for a wide variety of imines.<\/jats:p>","DOI":"10.3390\/molecules26185443","type":"journal-article","created":{"date-parts":[[2021,9,7]],"date-time":"2021-09-07T10:24:25Z","timestamp":1631010265000},"page":"5443","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Imine Reduction with Me2S-BH3"],"prefix":"10.3390","volume":"26","author":[{"given":"Mohammad M.","family":"Kamal","sequence":"first","affiliation":[{"name":"School of Chemistry, Faculty of Sciences, Monash University, Clayton 3800, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhizhou","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry, Faculty of Sciences, Monash University, Clayton 3800, Australia"},{"name":"Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Siyuan","family":"Zhai","sequence":"additional","affiliation":[{"name":"School of Chemistry, Faculty of Sciences, Monash University, Clayton 3800, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4269-3995","authenticated-orcid":false,"given":"Dragoslav","family":"Vidovi\u0107","sequence":"additional","affiliation":[{"name":"School of Chemistry, Faculty of Sciences, Monash University, Clayton 3800, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,9,7]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3238","DOI":"10.1021\/acscatal.5b00428","article-title":"Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide","volume":"5","author":"Chong","year":"2015","journal-title":"ACS Catal."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1021\/bk-2016-1236.ch006","article-title":"Current developments in the catalyzed hydroboration reaction","volume":"1236","author":"Geier","year":"2016","journal-title":"ACS Symp. 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