{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,18]],"date-time":"2026-04-18T06:51:57Z","timestamp":1776495117428,"version":"3.51.2"},"reference-count":40,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2021,9,13]],"date-time":"2021-09-13T00:00:00Z","timestamp":1631491200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21572126"],"award-info":[{"award-number":["21572126"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21801214"],"award-info":[{"award-number":["21801214"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Natural Science Foundation of Henan","award":["202300410016"],"award-info":[{"award-number":["202300410016"]}]},{"name":"the Higher Educa- 180 tion Institution Key Research Project Plan of Henan Province of China","award":["20B150019"],"award-info":[{"award-number":["20B150019"]}]},{"name":"the Science and Technology Research Plan Project of Henan Province","award":["202102210224"],"award-info":[{"award-number":["202102210224"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A simple and rapid method for efficient synthesis of sulfonyl chlorides\/bromides from sulfonyl hydrazide with NXS (X = Cl or Br) and late-stage conversion to several other functional groups was described. A variety of nucleophiles could be engaged in this transformation, thus permitting the synthesis of complex sulfonamides and sulfonates. In most cases, these reactions are highly selective, simple, and clean, affording products at excellent yields.<\/jats:p>","DOI":"10.3390\/molecules26185551","type":"journal-article","created":{"date-parts":[[2021,9,13]],"date-time":"2021-09-13T23:32:23Z","timestamp":1631575943000},"page":"5551","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Facile Synthesis of Sulfonyl Chlorides\/Bromides from Sulfonyl Hydrazides"],"prefix":"10.3390","volume":"26","author":[{"given":"Rongxiang","family":"Chen","sequence":"first","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shaohong","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fumin","family":"Shen","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Canran","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6107-1019","authenticated-orcid":false,"given":"Kaikai","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhanyong","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Xinxiang University, Xinxiang 453000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lantao","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,9,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"892","DOI":"10.1002\/anie.200352634","article-title":"ortho-Anisylsulfonyl as a Protecting Group for Secondary Amines: Mild Ni0-Catalyzed Hydrodesulfonylation","volume":"43","author":"Milburn","year":"2004","journal-title":"Angew. 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