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As confirmed by spectroscopic studies, UV-Vis and 1H-NMR in classical or competitive titration mode, the attachment to a carrier allocates the active moieties to mutual positions predetermining the function of the whole receptor molecule. Bivalent receptors form self-aggregates. Dendritic receptors with low dihydrogen phosphate loadings offer a cooperative complexation mode associated with a positive dendritic effect. In higher dihydrogen phosphate concentrations, the dendritic branches act independently and the binding mode changes to 1:1 anion: complexation site. Despite the anchoring, the dendritic receptors retain the superior efficiency and selectivity of a monomer, paving the way to recyclable receptors, desirable for economic and ecological reasons.<\/jats:p>","DOI":"10.3390\/molecules26185670","type":"journal-article","created":{"date-parts":[[2021,9,21]],"date-time":"2021-09-21T22:34:01Z","timestamp":1632263641000},"page":"5670","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Controlled Anchoring of (Phenylureido)sulfonamide-Based Receptor Moieties: An Impact of Binding Site Multiplication on Complexation Properties"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7595-8569","authenticated-orcid":false,"given":"Karol\u00edna","family":"Salvadori","sequence":"first","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"},{"name":"Department of Solid State Chemistry, University of Chemistry and Technology Prague, Technick\u00e1 5, 16828 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alena","family":"Krupkov\u00e1","sequence":"additional","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lucie \u010cervenkov\u00e1","family":"\u0160\u0165astn\u00e1","sequence":"additional","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Monika","family":"M\u00fcllerov\u00e1","sequence":"additional","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"V\u00e1clav","family":"Eigner","sequence":"additional","affiliation":[{"name":"Department of Solid State Chemistry, University of Chemistry and Technology Prague, Technick\u00e1 5, 16828 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tom\u00e1\u0161","family":"Stra\u0161\u00e1k","sequence":"additional","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8264-7032","authenticated-orcid":false,"given":"Petra","family":"Cu\u0159\u00ednov\u00e1","sequence":"additional","affiliation":[{"name":"Institute of Chemical Process Fundamentals of CAS, v.v.i., Rozvojov\u00e1 135, 16502 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,9,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Fr\u00e9chet, J.M.J., and Tomalia, D.A. 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