{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T03:40:28Z","timestamp":1791862828772,"version":"4.3.4"},"reference-count":62,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2021,11,4]],"date-time":"2021-11-04T00:00:00Z","timestamp":1635984000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100014440","name":"Ministerio de Ciencia, Innovaci\u00f3n y Universidades","doi-asserted-by":"publisher","award":["PGC2018-094644-B-C21 and PID2019-110091GB-I00"],"award-info":[{"award-number":["PGC2018-094644-B-C21 and PID2019-110091GB-I00"]}],"id":[{"id":"10.13039\/100014440","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The Lewis basicity of selected organic bases, modeled by the enthalpies of adduct formation between gaseous BF3 and bases in dichloromethane (DCM) solution, is critically examined. Although experimental enthalpies for a large number of molecules have been reported in the literature, it may be desirable to estimate missing or uncertain data for important Lewis bases. We decided to use high-level ab initio procedures, combined with a polarized continuum solvation model, in which the solvated species were the clusters formed by specific hydrogen bonding of DCM with the Lewis base and the Lewis base\/BF3 adduct. This mode of interaction with DCM corresponds to a specific solvation model (SSM). The results essentially showed that the enthalpy of BF3 adduct formation in DCM solution was clearly influenced by specific interactions, with DCM acting as hydrogen-bonding donor (HBD) molecule in two ways: base\/DCM and adduct\/DCM, confirming that specific solvation is an important contribution to experimentally determined Lewis basicity scales. This analysis allowed us to conclude that there are reasons to suspect some gas-phase values to be in error by more than the stated experimental uncertainty. Some experimental values in DCM solution that were uncertain for identified reasons could be complemented by the computed values.<\/jats:p>","DOI":"10.3390\/molecules26216659","type":"journal-article","created":{"date-parts":[[2021,11,4]],"date-time":"2021-11-04T09:11:32Z","timestamp":1636017092000},"page":"6659","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Enthalpies of Adduct Formation between Boron Trifluoride and Selected Organic Bases in Solution: Toward an Accurate Theoretical Entry to Lewis Basicity"],"prefix":"10.3390","volume":"26","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5500-5461","authenticated-orcid":false,"given":"Jean-Fran\u00e7ois","family":"Gal","sequence":"first","affiliation":[{"name":"Institut de Chimie de Nice, UMR 7272, Universit\u00e9 C\u00f4te d\u2019Azur, Parc Valrose, 06108 Nice, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6089-5860","authenticated-orcid":false,"given":"Pierre-Charles","family":"Maria","sequence":"additional","affiliation":[{"name":"Institut de Chimie de Nice, UMR 7272, Universit\u00e9 C\u00f4te d\u2019Azur, Parc Valrose, 06108 Nice, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manuel","family":"Y\u00e1\u00f1ez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica (M\u00f3dulo 13, Facultad de Ciencias) and Institute of Advanced Chemical Sciences (IadChem), Campus de Excelencia UAM-CSIC, Cantoblanco, Universidad Aut\u00f3noma de Madrid, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2596-5987","authenticated-orcid":false,"given":"Otilia","family":"M\u00f3","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica (M\u00f3dulo 13, Facultad de Ciencias) and Institute of Advanced Chemical Sciences (IadChem), Campus de Excelencia UAM-CSIC, Cantoblanco, Universidad Aut\u00f3noma de Madrid, 28049 Madrid, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2021,11,4]]},"reference":[{"key":"ref_1","unstructured":"Gur\u2019yanova, E.N., Gol\u2019dshtein, I.P., and Romm, I.P. 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