{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T00:53:50Z","timestamp":1777337630363,"version":"3.51.4"},"reference-count":140,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2022,3,21]],"date-time":"2022-03-21T00:00:00Z","timestamp":1647820800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["19-75-30008"],"award-info":[{"award-number":["19-75-30008"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The reactivity of cyclic \u03b1-diazo monocarbonyl compounds differs from that of their acyclic counterparts. In this review, we summarize the current literature available on the synthesis and synthetic applications of three major classes of cyclic \u03b1-diazo monocarbonyl compounds: \u03b1-diazo ketones, \u03b1-diazo lactones and \u03b1-diazo lactams.<\/jats:p>","DOI":"10.3390\/molecules27062030","type":"journal-article","created":{"date-parts":[[2022,3,21]],"date-time":"2022-03-21T21:48:42Z","timestamp":1647899322000},"page":"2030","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Preparation and Synthetic Applications of Five-to-Seven-Membered Cyclic \u03b1-Diazo Monocarbonyl Compounds"],"prefix":"10.3390","volume":"27","author":[{"given":"Daniil","family":"Zhukovsky","sequence":"first","affiliation":[{"name":"Research & Development Department, BratskChemSyntez LLC, PharmaSyntez Company, 5A\/1 Kommunalnaya St., 665717 Bratsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0413-7413","authenticated-orcid":false,"given":"Dmitry","family":"Dar\u2019in","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint Petersburg State University, 199034 Saint Petersburg, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olga","family":"Bakulina","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint Petersburg State University, 199034 Saint Petersburg, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0200-4772","authenticated-orcid":false,"given":"Mikhail","family":"Krasavin","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint Petersburg State University, 199034 Saint Petersburg, Russia"},{"name":"Immanuel Kant Baltic Federal University, 236041 Kaliningrad, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,3,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1091","DOI":"10.1021\/cr00028a010","article-title":"Organic Synthesis with a-Diazo Carbonyl Compounds","volume":"94","author":"Ye","year":"1994","journal-title":"Chem. 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