{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T23:09:07Z","timestamp":1786403347827,"version":"build-2736575974"},"reference-count":128,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2022,4,14]],"date-time":"2022-04-14T00:00:00Z","timestamp":1649894400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004686","name":"King Faisal University","doi-asserted-by":"publisher","award":["AN000610"],"award-info":[{"award-number":["AN000610"]}],"id":[{"id":"10.13039\/501100004686","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Drinking water containing nitrate ions at a higher concentration level of more than 10 mg\/L, according to the World Health Organization (WHO), poses a considerable peril to humans. This danger lies in its reduction of nitrite ions. These ions cause methemoglobinemia during the oxidation of hemoglobin into methemoglobin. Many protocols can be applied to the remediation of nitrate ions from hydra solutions such as Zn metal and amino sulfonic acid. Furthermore, the electrochemical process is a potent protocol that is useful for this purpose. Designing varying parameters, such as the type of cathodic electrode (Sn, Al, Fe, Cu), the type of electrolyte, and its concentration, temperature, pH, and current density, can give the best conditions to eliminate the nitrate as a pollutant. Moreover, the use of accessible, functional, and inexpensive adsorbents such as granular ferric hydroxide, modified zeolite, rice chaff, chitosan, perlite, red mud, and activated carbon are considered a possible approach for nitrate removal. Additionally, biological denitrification is considered one of the most promising methodologies attributable to its outstanding performance. Among these powerful methods and materials exist zero-valent iron (ZVI), which is used effectively in the deletion process of nitrate ions. Non-precious synthesis pathways are utilized to reduce the Fe2+ or Fe3+ ions by borohydride to obtain ZVI. The structural and morphological characteristics of ZVI are elucidated using UV\u2013Vis spectroscopy, zeta potential, XRD, FE-SEM, and TEM. The adsorptive properties are estimated through batch experiments, which are achieved to control the feasibility of ZVI as an adsorbent under the effects of Fe0 dose, concentration of NO3\u2212 ions, and pH. The obtained literature findings recommend that ZVI is an appropriate applicant adsorbent for the remediation of nitrate ions.<\/jats:p>","DOI":"10.3390\/molecules27082552","type":"journal-article","created":{"date-parts":[[2022,4,19]],"date-time":"2022-04-19T01:03:01Z","timestamp":1650330181000},"page":"2552","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Removal of the Harmful Nitrate Anions from Potable Water Using Different Methods and Materials, including Zero-Valent Iron"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6610-393X","authenticated-orcid":false,"given":"Hany M. Abd","family":"El-Lateef","sequence":"first","affiliation":[{"name":"Department of Chemistry, College of Science, King Faisal University, P.O. Box 400, Al-Ahsa 31982, Saudi Arabia"},{"name":"Chemistry Department, Faculty of Science, Sohag University, Sohag 82425, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0599-9928","authenticated-orcid":false,"given":"Mai M.","family":"Khalaf","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science, King Faisal University, P.O. Box 400, Al-Ahsa 31982, Saudi Arabia"},{"name":"Chemistry Department, Faculty of Science, Sohag University, Sohag 82425, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alaa El-dien","family":"Al-Fengary","sequence":"additional","affiliation":[{"name":"Chemistry Department, Faculty of Science, Sohag University, Sohag 82425, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mahmoud","family":"Elrouby","sequence":"additional","affiliation":[{"name":"Chemistry Department, Faculty of Science, Sohag University, Sohag 82425, Egypt"},{"name":"Faculty of Science, King Salman International University, Sinai 46612, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,4,14]]},"reference":[{"key":"ref_1","first-page":"A55","article-title":"Drinking Water Health Advisory: Pesticides (United States Environmental Protection Agency Office of Drinking Water Health Advisories)","volume":"67","author":"Renfrew","year":"1990","journal-title":"J. Chem. Educ."},{"key":"ref_2","unstructured":"(2011). Water quality for drinking: Who guidelines. SpringerReference, Springer."},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Naicker, R., Mutanga, O., Sibanda, M., and Peerbhay, K. (2020). 9-Discriminating tropical grasses grown under different nitrogen fertilizer regimes in KwaZulu-Natal, South Africa. Hyperspectral Remote Sensing, Elsevier.","DOI":"10.1016\/B978-0-08-102894-0.00014-0"},{"key":"ref_4","first-page":"882","article-title":"The Dutch National Atlas of Public Health","volume":"47","author":"Zwakhals","year":"2004","journal-title":"Bundesgesundheitsblatt Gesundh. Gesundh."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1016\/j.jhazmat.2013.09.025","article-title":"Sustainable nitrate-contaminated water treatment using multi cycle ion-exchange\/bioregeneration of nitrate selective resin","volume":"262","author":"Ebrahimi","year":"2013","journal-title":"J. Hazard. Mater."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"83","DOI":"10.12973\/ejac.2017.00146a","article-title":"Spectrophotometric Methods for the Determination of Anti-diabetic Drug Glipizide in Pure and Pharmaceutical Formulations","volume":"12","author":"Ismail","year":"2016","journal-title":"Eurasian J. Anal. Chem."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"3163","DOI":"10.1016\/j.chroma.2009.01.096","article-title":"Selective determination method for measurement of nitrite and nitrate in water samples using high-performance liquid chromatography with post-column photochemical reaction and chemiluminescence detection","volume":"1216","author":"Kodamatani","year":"2009","journal-title":"J. Chromatogr. A"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/0021-9673(90)85064-3","article-title":"Alkanesulphonates as eluents for the determination of nitrate and nitrite by ion chromatography with direct UV detection","volume":"521","author":"Thomsen","year":"1990","journal-title":"J. Chromatogr. A"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"187","DOI":"10.2116\/analsci.27.187","article-title":"Rapid Method for Simultaneous Determination of Nitrite and Nitrate in Water Samples Using Short-Column Ion-Pair Chromatographic Separation, Photochemical Reaction, and Chemiluminescence Detection","volume":"27","author":"Kodamatani","year":"2011","journal-title":"Anal. Sci."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/S0003-2670(01)01068-6","article-title":"Rapid determination of nitrate and nitrite in drinking water samples using ion-interaction liquid chromatography","volume":"441","author":"Connolly","year":"2001","journal-title":"Anal. Chim. Acta"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"66","DOI":"10.1016\/j.talanta.2010.08.042","article-title":"Simultaneous electrochemical determination of nitrate and nitrite in aqueous solution using Ag-doped zeolite-expanded graphite-epoxy electrode","volume":"83","author":"Manea","year":"2010","journal-title":"Talanta"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1171","DOI":"10.1007\/s11581-012-0839-0","article-title":"Voltammetric detection of nitrate in water sample based on in situ copper-modified electrode","volume":"19","author":"Luo","year":"2013","journal-title":"Ionics"},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Wilde, E.W. (2000). Removal of Gadolinium Nitrate from Heavy Water, Office of Scientific and Technical Information (OSTI).","DOI":"10.2172\/758308"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1206","DOI":"10.1016\/j.reactfunctpolym.2006.03.009","article-title":"Removal of nitrate from aqueous solution by nitrate selective ion exchange resins","volume":"66","author":"Samatya","year":"2006","journal-title":"React. Funct. Polym."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1007\/BF00572386","article-title":"Removal of nitrates from potable water by ion exchange","volume":"2","author":"Korngold","year":"1973","journal-title":"Water. Air. Soil Pollut."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Obotey Ezugbe, E., and Rathilal, S. (2020). Membrane Technologies in Wastewater Treatment: A Review. Membranes, 10.","DOI":"10.3390\/membranes10050089"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"8806","DOI":"10.1021\/ie070195k","article-title":"Adsorptive removal of phosphate and nitrate anions from aqueous solutions using ammonium-functionalized mesoporous silica","volume":"46","author":"Hamoudi","year":"2007","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1016\/S0010-8545(99)00143-5","article-title":"The chemical reduction of nitrate in aqueous solution","volume":"199","author":"Fanning","year":"2000","journal-title":"Coord. Chem. Rev."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1016\/j.envres.2018.01.030","article-title":"Remediation of contaminated soils by enhanced nanoscale zero valent iron","volume":"163","author":"Jiang","year":"2018","journal-title":"Environ. Res."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"437","DOI":"10.2478\/s11696-011-0029-y","article-title":"Denitrification of simulated nitrate-rich wastewater using sulfamic acid and zinc scrap","volume":"65","author":"Jang","year":"2011","journal-title":"Chem. Pap."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"975","DOI":"10.1016\/j.watres.2006.01.018","article-title":"Development of physicochemical nitrogen removal process for high strength industrial wastewater","volume":"40","author":"Lee","year":"2006","journal-title":"Water Res."},{"key":"ref_22","doi-asserted-by":"crossref","unstructured":"Kistiakowsky, G.B. (1980). Reminiscences of Wartime Los Alamos. Reminiscences Los Alamos 1943\u20131945, Springer.","DOI":"10.1007\/978-94-009-9022-7_5"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1080\/09593330.2012.706646","article-title":"A review of nitrate reduction using inorganic materials","volume":"1","author":"Zhu","year":"2012","journal-title":"Environ. Technol. Rev."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"4573","DOI":"10.1149\/1.1394103","article-title":"Electroreduction of Nitrate and Nitrite Ion on a Platinum-Group-Metal Catalyst-Modified Carbon Fiber Electrode Chronoamperometry and Mechanism Studies","volume":"147","author":"De","year":"2000","journal-title":"J. Electrochem. Soc."},{"key":"ref_25","first-page":"1107","article-title":"Efficiency of electrochemical denitrification using electrolysis cell containing BDD electrode","volume":"53","author":"Ghazouani","year":"2015","journal-title":"Desalin. Water Treat."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"478","DOI":"10.1016\/j.jhazmat.2012.02.034","article-title":"Effect of the cathode material on the removal of nitrates by electrolysis in non-chloride media","volume":"214","author":"Lacasa","year":"2012","journal-title":"J. Hazard. Mater."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"4600","DOI":"10.1016\/j.electacta.2009.03.064","article-title":"Efficient electrochemical reduction of nitrate to nitrogen using Ti\/IrO2\u2013Pt anode and different cathodes","volume":"54","author":"Li","year":"2009","journal-title":"Electrochim. Acta."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"66","DOI":"10.1016\/j.cej.2011.12.090","article-title":"Electrochemical denitrificacion with chlorides using DSA and BDD anodes","volume":"184","author":"Lacasa","year":"2012","journal-title":"Chem. Eng. J."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.electacta.2018.08.154","article-title":"Electrochemical reduction of nitrate via Cu\/Ni composite cathode paired with Ir-Ru\/Ti anode: High efficiency and N2 selectivity","volume":"291","author":"Zhang","year":"2018","journal-title":"Electrochim. Acta"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"6553","DOI":"10.1016\/j.biortech.2010.03.076","article-title":"Treatment of nitrate contaminated water using an electrochemical method","volume":"101","author":"Li","year":"2010","journal-title":"Bioresour. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"4065","DOI":"10.1016\/j.watres.2005.07.032","article-title":"Electrochemical denitrificaton of simulated ground water","volume":"39","author":"Dash","year":"2005","journal-title":"Water Res."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"1185","DOI":"10.1023\/A:1012755222981","article-title":"Electrochemical reduction of nitrate in weakly alkaline solutions","volume":"31","author":"Bouzek","year":"2001","journal-title":"J. Appl. Electrochem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/BF00248182","article-title":"Electrochemical reduction of nitrates and nitrites in alkaline nuclear waste solutions","volume":"26","author":"Genders","year":"1996","journal-title":"J. Appl. Electrochem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1007\/s10800-004-8349-z","article-title":"Electrochemical reduction of nitrate ion on various cathodes? reaction kinetics on bronze cathode","volume":"35","author":"Polatides","year":"2005","journal-title":"J. Appl. Electrochem."},{"key":"ref_35","first-page":"103","article-title":"Internet Banking: The Second Wave (A Banker\u2019s Guide to Internet Strategy in the Post Dotcom Era), Sanjiv Singhal, New Delhi: Tata Mcgraw-Hill Publishing Company Limited, 2003: 200p","volume":"2","author":"Jayadev","year":"2003","journal-title":"Metamorph. A J. Manag. Res."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"114885","DOI":"10.1016\/j.watres.2019.114885","article-title":"Selective adsorption of nitrate over chloride in microporous carbons","volume":"164","author":"Mubita","year":"2019","journal-title":"Water Res."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"2585","DOI":"10.1007\/s10562-016-1894-3","article-title":"Electrochemical Reduction of High-Concentrated Nitrate Using Ti\/TiO2 Nanotube Array Anode and Fe Cathode in Dual-Chamber Cell","volume":"146","author":"Li","year":"2016","journal-title":"Catal. Letters."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1266","DOI":"10.33793\/acperpro.02.03.141","article-title":"Removal of Fluoride from Groundwater by Batch Electrocoagulation Process Using Al Plate Electrodes","volume":"2","author":"Karabulut","year":"2019","journal-title":"Acad. Perspect. Procedia."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"691","DOI":"10.4152\/pea.200906691","article-title":"A Study of Stripping Voltammetric Behaviour of Cefadroxil Antibiotic in the Presence of Cu (II) and its Determination in Pharmaceutical Formulation","volume":"27","author":"Loura","year":"2009","journal-title":"Port. Electrochim. Acta."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"996","DOI":"10.1016\/j.electacta.2008.08.003","article-title":"Electrocatalytic reduction of nitrate on copper electrode in alkaline solution","volume":"54","author":"Badea","year":"2009","journal-title":"Electrochim. Acta."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.jelechem.2014.10.024","article-title":"The electrochemical reduction of nitrate ion on polypyrrole coated copper electrode","volume":"736","year":"2015","journal-title":"J. Electroanal. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.electacta.2016.12.147","article-title":"Electrocatalytic reduction of Nitrate on Copper single crystals in acidic and alkaline solutions","volume":"227","author":"Figueiredo","year":"2017","journal-title":"Electrochim. Acta."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1329","DOI":"10.1016\/j.electacta.2006.07.034","article-title":"Efficient electrochemical reduction of nitrate to nitrogen on tin cathode at very high cathodic potentials","volume":"52","author":"Katsounaros","year":"2006","journal-title":"Electrochim. Acta."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"228","DOI":"10.1139\/cjc-2013-0406","article-title":"Electrochemical reduction of aqueous nitrate ion at tin cathodes","volume":"92","author":"Ambrosioni","year":"2014","journal-title":"Can. J. Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"5477","DOI":"10.1016\/j.electacta.2008.03.018","article-title":"Influence of nitrate concentration on its electrochemical reduction on tin cathode: Identification of reaction intermediates","volume":"53","author":"Katsounaros","year":"2008","journal-title":"Electrochim. Acta."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"6412","DOI":"10.1016\/j.electacta.2007.04.050","article-title":"Influence of the concentration and the nature of the supporting electrolyte on the electrochemical reduction of nitrate on tin cathode","volume":"52","author":"Katsounaros","year":"2007","journal-title":"Electrochim. Acta."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1016\/j.jhazmat.2004.05.001","article-title":"Nitrate removal from aqueous solution by adsorption onto various materials","volume":"112","year":"2004","journal-title":"J. Hazard. Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1016\/S0956-053X(01)00041-1","article-title":"Arsenic adsorption from aqueous solutions by activated red mud","volume":"22","author":"Bildik","year":"2002","journal-title":"Waste Manag."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"2","DOI":"10.4172\/2161-0525.1000346","article-title":"Removal of Nitrate and Nitrite Anions from Wastewater Using Activated Carbon Derived from Rice Straw","volume":"6","author":"Hanafi","year":"2016","journal-title":"J. Environ. Anal. Toxicol."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1016\/j.jhazmat.2005.11.055","article-title":"Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricot","volume":"135","year":"2006","journal-title":"J. Hazard. Mater."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1016\/j.molliq.2017.03.004","article-title":"Removal of nitrate from aqueous solution using modified granular activated carbon","volume":"233","author":"Mazarji","year":"2017","journal-title":"J. Mol. Liq."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"51470","DOI":"10.1039\/C5RA03920G","article-title":"Parameter optimization for nitrate removal from water using activated carbon and composite of activated carbon and Fe2O3 nanoparticles","volume":"5","author":"Mehrabi","year":"2015","journal-title":"RSC Adv."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1675","DOI":"10.1016\/j.biortech.2009.09.087","article-title":"Removal of nitrate from aqueous solutions by activated carbon prepared from sugar beet bagasse","volume":"101","author":"Demiral","year":"2010","journal-title":"Bioresour. Technol."},{"key":"ref_54","first-page":"1","article-title":"Color Removal from Tannery Wastewater Using Activated Carbon Generated from Rice Husk","volume":"2018","author":"Ahmed","year":"2018","journal-title":"World Environ. Water Resour. Congr."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"1045","DOI":"10.13005\/bbra\/2131","article-title":"Evaluation of Nitrate Removal from Water Using Activated Carbon and Clinoptilolite by Adsorption Method","volume":"13","author":"Asl","year":"2016","journal-title":"Biosci. Biotechnol. Res. Asia."},{"key":"ref_56","unstructured":"Balasundaram, G., Ananthasingh, T., and Kandy, A. (2017, January 22\u201324). Removal of Nitrate from Ground Water Using Neem Leaves as Adsorbent. Proceedings of the ICLTET-2017, ACBES-2017, Kuala Lumpur, Malaysia."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"14739","DOI":"10.1080\/19443994.2015.1073179","article-title":"Removal of orthophosphate ions from aqueous solution using chitin as natural adsorbent","volume":"57","author":"Abidar","year":"2015","journal-title":"Desalin. Water Treat."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"1972","DOI":"10.1016\/j.jhazmat.2010.12.090","article-title":"Removal of nitrate from aqueous solution using cetylpyridinium bromide (CPB) modified zeolite as adsorbent","volume":"186","author":"Zhan","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"655","DOI":"10.4314\/wsa.v36i5.61999","article-title":"Functionalised natural zeolite and its potential for treating drinking water containing excess amount of nitrate","volume":"36","author":"Onyango","year":"2010","journal-title":"Water SA."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1002\/apj.1965","article-title":"Removal of nitrate from aqueous solutions in batch systems using activated perlite: An application of response surface methodology","volume":"11","author":"Baei","year":"2016","journal-title":"Asia-Pacific J. Chem. Eng."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"178","DOI":"10.4236\/jeas.2015.54015","article-title":"Effective Removal of Nitrates Ions from Aqueous Solution Using New Clay as Potential Low-Cost Adsorbent","volume":"05","author":"Qourzal","year":"2015","journal-title":"J. Encapsulation Adsorpt. Sci."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1016\/S0269-7491(00)00147-0","article-title":"New methods of nitrate removal from water","volume":"112","author":"Shrimali","year":"2001","journal-title":"Environ. Pollut."},{"key":"ref_63","first-page":"21","article-title":"Removal of Nitrate From Aqueous Solution Using Rice Chaff","volume":"6","author":"Dehghani","year":"2015","journal-title":"Jentashapir J. Heal. Res."},{"key":"ref_64","first-page":"629","article-title":"Adsorption of nitrate from aqueous solution onto modified cassava (Manihot esculenta) straw\/Adsorpcja azotan\u00f3w z roztworu wodnego na zmodyfikowanej s\u0142omie manioku Manihot esculenta","volume":"19","author":"Li","year":"2012","journal-title":"Ecol. Chem. Eng. S."},{"key":"ref_65","first-page":"e26419","article-title":"Removal of Nitrate in the Aqueous Phase Using Granular Ferric Hydroxide","volume":"7","author":"Dehghani","year":"2015","journal-title":"Jundishapur J. Heal. Sci."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.ecoleng.2016.06.035","article-title":"Removal of nitrate from aqueous solution by modified sugarcane bagasse biochar","volume":"95","author":"Hafshejani","year":"2016","journal-title":"Ecol. Eng."},{"key":"ref_67","doi-asserted-by":"crossref","unstructured":"Stjepanovi\u0107, M., Veli\u0107, N., and Habuda-Stani\u0107, M. (2022). Modified Hazelnut Shells as a Novel Adsorbent for the Removal of Nitrate from Wastewater. Water, 14.","DOI":"10.3390\/w14050816"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1706","DOI":"10.1016\/j.scitotenv.2016.11.194","article-title":"Comparison of heterotrophic and autotrophic denitrification processes for treating nitrate-contaminated surface water","volume":"579","author":"Wang","year":"2017","journal-title":"Sci. Total Environ."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"3965","DOI":"10.1016\/j.biortech.2007.05.026","article-title":"Bio-electrochemical removal of nitrate from water and wastewater\u2014A review","volume":"99","author":"Ghafari","year":"2008","journal-title":"Bioresour. Technol."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.ibiod.2016.04.020","article-title":"Effect of C\/N ratio and support material on heterotrophic denitrification of potable water in bio-filters using sugar as carbon source","volume":"111","author":"Karanasios","year":"2016","journal-title":"Int. Biodeterior. Biodegrad."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"723","DOI":"10.1016\/j.chemosphere.2008.06.065","article-title":"A long-term performance test on an autotrophic denitrification column for application as a permeable reactive barrier","volume":"73","author":"Moon","year":"2008","journal-title":"Chemosphere"},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1016\/S1389-1723(03)80024-5","article-title":"Influence of ethanol concentration on biofilm bacterial composition from a denitrifying submerged filter used for contaminated groundwater","volume":"95","author":"Gomez","year":"2003","journal-title":"J. Biosci. Bioeng."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"1212","DOI":"10.1061\/(ASCE)0733-9372(2005)131:8(1212)","article-title":"Zero-Valent Iron-Assisted Autotrophic Denitrification","volume":"131","author":"Biswas","year":"2005","journal-title":"J. Environ. Eng."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1016\/j.aquaeng.2005.04.004","article-title":"Denitrification in recirculating systems: Theory and applications","volume":"34","author":"Tal","year":"2006","journal-title":"Aquac. Eng."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"591","DOI":"10.1016\/j.cej.2016.12.106","article-title":"High-rate autotrophic denitrification in a fluidized-bed reactor at psychrophilic temperatures","volume":"313","author":"Milone","year":"2017","journal-title":"Chem. Eng. J."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"677","DOI":"10.1016\/j.biortech.2016.08.014","article-title":"Biological denitrification process based on the Fe(0)\u2013carbon micro-electrolysis for simultaneous ammonia and nitrate removal from low organic carbon water under a microaerobic condition","volume":"219","author":"Deng","year":"2016","journal-title":"Bioresour. Technol."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"1539","DOI":"10.1016\/j.procbio.2006.02.015","article-title":"Biological denitrification in drinking water using Glycyrrhiza glabra and Arunda donax as the carbon source","volume":"41","author":"Ovez","year":"2006","journal-title":"Process Biochem."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1016\/j.biortech.2017.01.049","article-title":"Aerobic-heterotrophic nitrogen removal through nitrate reduction and ammonium assimilation by marine bacterium Vibrio sp. Y1\u20135","volume":"230","author":"Li","year":"2017","journal-title":"Bioresour. Technol."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"2397","DOI":"10.1007\/s11274-008-9753-z","article-title":"Biological denitrification by Pseudomonas stutzeri immobilized on microbial cellulose","volume":"24","author":"Rezaee","year":"2008","journal-title":"World J. Microbiol. Biotechnol."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/j.jhazmat.2007.02.012","article-title":"Biological denitrification of drinking water in a slow sand filter","volume":"148","author":"Aslan","year":"2007","journal-title":"J. Hazard. Mater."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"101786","DOI":"10.1016\/j.jwpe.2020.101786","article-title":"Biological nitrate removal from groundwater by an aerobic granular technology to supply drinking water at pilot-scale","volume":"40","year":"2021","journal-title":"J. Water Process Eng."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.ibiod.2016.10.057","article-title":"Denitrification of high strength nitrate bearing acidic waters in granular sludge sequencing batch reactors","volume":"119","author":"Nancharaiah","year":"2017","journal-title":"Int. Biodeterior. Biodegrad."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"21","DOI":"10.5109\/1808449","article-title":"Treatment and Regeneration of Nano-scale Zero-valent Iron Spent in Water Remediation","volume":"4","author":"Khalil","year":"2017","journal-title":"Evergreen"},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1080\/10408430601057611","article-title":"Zero-Valent Iron Nanoparticles for Abatement of Environmental Pollutants: Materials and Engineering Aspects","volume":"31","author":"Li","year":"2006","journal-title":"Crit. Rev. Solid State Mater. Sci."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1080\/10643380600620387","article-title":"Synthesis, Properties, and Environmental Applications of Nanoscale Iron-Based Materials: A Review","volume":"36","author":"Li","year":"2006","journal-title":"Crit. Rev. Environ. Sci. Technol."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"595","DOI":"10.1007\/s11270-010-0502-1","article-title":"A Comparison Between Field Applications of Nano-, Micro-, and Millimetric Zero-Valent Iron for the Remediation of Contaminated Aquifers Water","volume":"215","author":"Comba","year":"2010","journal-title":"Air. Soil Pollut."},{"key":"ref_87","doi-asserted-by":"crossref","unstructured":"Ibrahim, H.M., Awad, M., Al-Farraj, A.S., and Al-Turki, A.M. (2020). Stability and Dynamic Aggregation of Bare and Stabilized Zero-Valent Iron Nanoparticles under Variable Solution Chemistry. Nanomater, 10.","DOI":"10.3390\/nano10020192"},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"2022","DOI":"10.1021\/es0616534","article-title":"Adsorption of Humic Acid onto Nanoscale Zerovalent Iron and Its Effect on Arsenic Removal","volume":"41","author":"Giasuddin","year":"2007","journal-title":"Environ. Sci. Technol."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1142\/9781860948572_0002","article-title":"Nanoscale Zero-Valent Iron (nZVI) for Site Remediation","volume":"10","author":"Elliott","year":"2007","journal-title":"Environ. Appl. Nanomater."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"618","DOI":"10.1016\/j.cej.2015.11.046","article-title":"Review on nano zerovalent iron (nZVI): From synthesis to environmental applications","volume":"287","author":"Stefaniuk","year":"2016","journal-title":"Chem. Eng. J."},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"62","DOI":"10.4028\/www.scientific.net\/AMR.1112.62","article-title":"Ridwan, Marsi, Faizal, Synthesis and Characterization of Zero-Valent Iron Nanoparticles","volume":"1112","author":"Yusmartini","year":"2015","journal-title":"Adv. Mater. Res."},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"3777","DOI":"10.1021\/acs.nanolett.9b00905","article-title":"Room-temperature magnetic order in air-stable ultrathin iron oxide","volume":"19","author":"Yuan","year":"2019","journal-title":"Nano Lett."},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"107457","DOI":"10.1016\/j.jece.2022.107457","article-title":"Recent trends in application of nanoscale zero-valent metals and metal single atoms in membrane processes","volume":"10","author":"Amiri","year":"2022","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"497","DOI":"10.1016\/j.molliq.2018.07.093","article-title":"Adsorption and removal of cationic and anionic surfactants using zero-valent iron nanoparticles","volume":"268","author":"Ali","year":"2018","journal-title":"J. Mol. Liq."},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.jconhyd.2015.03.004","article-title":"Methods for characterizing the fate and effects of nano zerovalent iron during groundwater remediation","volume":"181","author":"Shi","year":"2015","journal-title":"J. Contam. Hydrol."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"178","DOI":"10.1016\/j.jmrt.2016.11.004","article-title":"Synthesis and characterization of zero-valent iron nanoparticles supported on SBA-15","volume":"6","author":"Santos","year":"2017","journal-title":"J. Mater. Res. Technol."},{"key":"ref_97","doi-asserted-by":"crossref","unstructured":"Greenlee, L.F., and Hooker, S. (2011). Characterization of Stabilized Zero Valent Iron Nanoparticles. Materials Challenges and Testing for Supply of Energy and Resources, Springer.","DOI":"10.1007\/978-3-642-23348-7_16"},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"4063","DOI":"10.1007\/s11051-011-0350-y","article-title":"Synthesis, characterization and role of zero-valent iron nanoparticle in removal of hexavalent chromium from chromium-spiked soil","volume":"13","author":"Singh","year":"2011","journal-title":"J. Nanoparticle Res."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/j.cis.2006.03.001","article-title":"Characterization of zero-valent iron nanoparticles","volume":"120","author":"Sun","year":"2006","journal-title":"Adv. Colloid Interface Sci."},{"key":"ref_100","first-page":"23","article-title":"Preface","volume":"v\u2013vi","author":"Dukhin","year":"2002","journal-title":"Stud. Interface Sci"},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"1936","DOI":"10.1021\/acs.jced.9b01110","article-title":"Mechanochemically Activated Microsized Zero-Valent Iron\/Pyrite Composite for Effective Hexavalent Chromium Sequestration in Aqueous Solution","volume":"65","author":"He","year":"2020","journal-title":"J. Chem. Eng. Data"},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/j.colsurfa.2007.05.029","article-title":"A method for the preparation of stable dispersion of zero-valent iron nanoparticles.Colloids Surfaces A Physicochem","volume":"308","author":"Sun","year":"2007","journal-title":"Eng. Asp."},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"224","DOI":"10.17221\/11\/2014-SWR","article-title":"Nitrate removal from aqueous solution using natural zeolite-supported zero-valent iron nanoparticles","volume":"9","author":"Sepehri","year":"2014","journal-title":"Soil Water Res."},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"71","DOI":"10.4028\/www.scientific.net\/AMR.777.71","article-title":"Chemical Reduction of Nitrate in Aqueous Solution by Iron Powder","volume":"777","author":"Zhou","year":"2013","journal-title":"Adv. Mater. Res."},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"310","DOI":"10.1016\/j.chemosphere.2006.12.073","article-title":"Pressurized CO2\/zero valent iron system for nitrate removal","volume":"68","author":"Li","year":"2007","journal-title":"Chemosphere"},{"key":"ref_106","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/S0920-5861(02)00042-1","article-title":"Catalytic denitrification of water with palladium-based catalysts supported on activated carbons","volume":"75","author":"Lemaignen","year":"2002","journal-title":"Catal. Today"},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"282","DOI":"10.5004\/dwt.2020.25347","article-title":"Phosphorous removal by nanoscale zero-valent iron (nZVI) and chitosan-coated nZVI (CS-nZVI)","volume":"184","author":"Shanableh","year":"2020","journal-title":"Desalin. Water Treat."},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1016\/j.apgeochem.2003.08.001","article-title":"Nitrate reduction by zero-valent iron under different pH regimes","volume":"19","author":"Choe","year":"2004","journal-title":"Appl. Geochem."},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"1507","DOI":"10.3390\/met5031507","article-title":"Use of Nanoscale Zero-Valent Iron (NZVI) Particles for Chemical Denitrification under Different Operating Conditions","volume":"5","author":"Siciliano","year":"2015","journal-title":"Metals"},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"41","DOI":"10.2166\/ws.2005.0037","article-title":"Innovative process using Fe0\/CO2 for the removal of nitrate from groundwater","volume":"5","author":"Ruangchainikom","year":"2005","journal-title":"Water Supply"},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1016\/j.cej.2016.02.040","article-title":"Enhancing oil removal from water using ferric oxide nanoparticles doped carbon nanotubes adsorbents","volume":"293","author":"Fard","year":"2016","journal-title":"Chem. Eng. J."},{"key":"ref_112","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1016\/j.envint.2019.01.030","article-title":"Guangming Zeng, Integration of nanoscale zero-valent iron and functional anaerobic bacteria for groundwater remediation: A review","volume":"124","author":"Dong","year":"2019","journal-title":"Environ. Int."},{"key":"ref_113","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1007\/s10230-020-00668-9","article-title":"Nitrate Reduction of the Siilinj\u00e4rvi\/Finland Mine Water with Zero-valent Iron and Iron Waste as Alternative Iron Sources","volume":"39","author":"Lopes","year":"2020","journal-title":"Mine Water Environ."},{"key":"ref_114","doi-asserted-by":"crossref","first-page":"352","DOI":"10.1016\/j.chemosphere.2015.09.025","article-title":"Impact of nanoscale zero valent iron on bacteria is growth phase dependent","volume":"144","author":"Chaithawiwat","year":"2016","journal-title":"Chemosphere"},{"key":"ref_115","doi-asserted-by":"crossref","first-page":"427","DOI":"10.1016\/j.jhazmat.2006.10.062","article-title":"The effect of acid treatment of carbon cloth on the adsorption of nitrite and nitrate ions","volume":"144","author":"Afkhami","year":"2007","journal-title":"J. Hazard. Mater."},{"key":"ref_116","doi-asserted-by":"crossref","first-page":"901","DOI":"10.1080\/01496395.2014.978462","article-title":"Magnetic Pb(II) Ion-Imprinted Polymer Prepared by Surface Imprinting Technique and its Adsorption Properties","volume":"50","author":"Zhang","year":"2015","journal-title":"Sep. Sci. Technol."},{"key":"ref_117","doi-asserted-by":"crossref","first-page":"886","DOI":"10.1080\/01496390701787461","article-title":"Removal of Nitrate from Water by Adsorption onto Zinc Chloride Treated Activated Carbon","volume":"43","author":"Bhatnagar","year":"2008","journal-title":"Sep. Sci. Technol."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1016\/j.cej.2009.09.033","article-title":"Removal of perchlorate from aqueous solution using protonated cross-linked chitosan","volume":"156","author":"Xie","year":"2010","journal-title":"Chem. Eng. J."},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"255","DOI":"10.1016\/j.biortech.2004.02.015","article-title":"Removal of nitrate-nitrogen from drinking water using bamboo powder charcoal","volume":"95","author":"Mizuta","year":"2004","journal-title":"Bioresour. Technol."},{"key":"ref_120","doi-asserted-by":"crossref","first-page":"92","DOI":"10.1016\/j.clay.2009.11.047","article-title":"Preparation, characterization of surfactants modified clay minerals and nitrate adsorption","volume":"48","author":"Xi","year":"2010","journal-title":"Appl. Clay Sci."},{"key":"ref_121","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1007\/s10924-010-0275-z","article-title":"Heterotrophic Biological Denitrification Using Microbial Cellulose as Carbon Source","volume":"19","author":"Godini","year":"2010","journal-title":"J. Polym. Environ."},{"key":"ref_122","doi-asserted-by":"crossref","first-page":"742","DOI":"10.1134\/S0020168508070121","article-title":"Nitrate adsorption from aqueous solution by MII-Al-CO3 layered double hydroxide","volume":"44","author":"Hosni","year":"2008","journal-title":"Inorg. Mater."},{"key":"ref_123","doi-asserted-by":"crossref","first-page":"524","DOI":"10.1016\/j.jhazmat.2009.03.128","article-title":"Nitrate sorption by thermally activated Mg\/Al chloride hydrotalcite-like compound","volume":"169","author":"Islam","year":"2009","journal-title":"J. Hazard. Mater."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1016\/j.desal.2010.02.003","article-title":"Synthesis and physicochemical characterization of Zn\/Al chloride layered double hydroxide and evaluation of its nitrate removal efficiency","volume":"256","author":"Islam","year":"2010","journal-title":"Desalination"},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"1012","DOI":"10.1016\/j.jhazmat.2008.09.001","article-title":"The removal of nitrate from aqueous solutions by chitosan hydrogel beads","volume":"164","author":"Chatterjee","year":"2009","journal-title":"J. Hazard. Mater."},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1016\/j.cis.2009.09.003","article-title":"Applications of chitin- and chitosan-derivatives for the detoxification of water and wastewater\u2014A short review","volume":"152","author":"Bhatnagar","year":"2009","journal-title":"Adv. Colloid Interface Sci."},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"374","DOI":"10.1016\/j.seppur.2006.02.020","article-title":"Removal of nitrate from aqueous solution by using red mud","volume":"51","author":"Cengeloglu","year":"2006","journal-title":"Sep. Purif. Technol."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"711","DOI":"10.1016\/j.ultsonch.2009.12.002","article-title":"Sorption studies of nitrate ion by a modified beet residue in the presence and absence of ultrasound","volume":"17","author":"Karimi","year":"2010","journal-title":"Ultrason. Sonochem."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/8\/2552\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T22:54:27Z","timestamp":1760136867000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/8\/2552"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,4,14]]},"references-count":128,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2022,4]]}},"alternative-id":["molecules27082552"],"URL":"https:\/\/doi.org\/10.3390\/molecules27082552","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,4,14]]}}}