{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T22:26:25Z","timestamp":1764368785295,"version":"build-2065373602"},"reference-count":40,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2022,5,14]],"date-time":"2022-05-14T00:00:00Z","timestamp":1652486400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Xunta de Galicia","award":["GRC2019\/14"],"award-info":[{"award-number":["GRC2019\/14"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Treatment of the imines a\u2013c with palladium(II) acetate in acetic acid yielded the \u03bc-acetate dinuclear complexes 1a\u2013c, which readily reacted with sodium chloride or bromide to provide \u03bc-halide analogues. The reaction of the latter with nitrogen, phosphorus and oxygen donor nucleophiles yielded new imine palladacycles following the cleavage of the Pd2X2 unit. The complexes were fully characterized by microanalysis, 1H, 13C and 31P NMR spectroscopies, as appropriate. The compounds were applied as catalysts in the Suzuki\u2013Miyaura coupling reaction in aqueous and semi-aqueous media.<\/jats:p>","DOI":"10.3390\/molecules27103146","type":"journal-article","created":{"date-parts":[[2022,5,14]],"date-time":"2022-05-14T09:27:56Z","timestamp":1652520476000},"page":"3146","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Imine Palladacycles: Synthesis, Structural Analysis and Application in Suzuki\u2013Miyaura Cross Coupling in Semi-Aqueous Media"],"prefix":"10.3390","volume":"27","author":[{"given":"Brais","family":"Berm\u00fadez-Puente","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Luis A.","family":"Adrio","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4505-2360","authenticated-orcid":false,"given":"F\u00e1tima","family":"Lucio-Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8536-3382","authenticated-orcid":false,"given":"Francisco","family":"Reigosa","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9930-5717","authenticated-orcid":false,"given":"Juan M.","family":"Ortigueira","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9 M.","family":"Vila","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,5,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3272","DOI":"10.1021\/ja01092a063","article-title":"Formation of Covalent Bonds from Platinum or Palladium to Carbon by Direct Substitution","volume":"87","author":"Cope","year":"1965","journal-title":"J. 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