{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T06:22:31Z","timestamp":1788330151271,"version":"build-2803163510"},"reference-count":187,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2022,6,8]],"date-time":"2022-06-08T00:00:00Z","timestamp":1654646400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"German Research Foundation","award":["393148499"],"award-info":[{"award-number":["393148499"]}]},{"name":"University of Greifswald","award":["393148499"],"award-info":[{"award-number":["393148499"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Throughout the previous ten years many scientists took inspiration from natural molybdenum and tungsten-dependent oxidoreductases to build functional active site analogues. These studies not only led to an ever more detailed mechanistic understanding of the biological template, but also paved the way to atypical selectivity and activity, such as catalytic hydrogen evolution. This review is aimed at representing the last decade\u2019s progress in the research of and with molybdenum and tungsten functional model compounds. The portrayed systems, organized according to their ability to facilitate typical and artificial enzyme reactions, comprise complexes with non-innocent dithiolene ligands, resembling molybdopterin, as well as entirely non-natural nitrogen, oxygen, and\/or sulfur bearing chelating donor ligands. All model compounds receive individual attention, highlighting the specific novelty that each provides for our understanding of the enzymatic mechanisms, such as oxygen atom transfer and proton-coupled electron transfer, or that each presents for exploiting new and useful catalytic capability. Overall, a shift in the application of these model compounds towards uncommon reactions is noted, the latter are comprehensively discussed.<\/jats:p>","DOI":"10.3390\/molecules27123695","type":"journal-article","created":{"date-parts":[[2022,6,12]],"date-time":"2022-06-12T22:37:20Z","timestamp":1655073440000},"page":"3695","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Inspired by Nature\u2014Functional Analogues of Molybdenum and Tungsten-Dependent Oxidoreductases"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2832-6948","authenticated-orcid":false,"given":"Sebastian","family":"P\u00e4tsch","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Biochemie, Universit\u00e4t Greifswald, Felix-Hausdorff-Str. 4, 17489 Greifswald, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jevy V.","family":"Correia","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Biochemie, Universit\u00e4t Greifswald, Felix-Hausdorff-Str. 4, 17489 Greifswald, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4627-6905","authenticated-orcid":false,"given":"Benedict J.","family":"Elvers","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Biochemie, Universit\u00e4t Greifswald, Felix-Hausdorff-Str. 4, 17489 Greifswald, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mareile","family":"Steuer","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Biochemie, Universit\u00e4t Greifswald, Felix-Hausdorff-Str. 4, 17489 Greifswald, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7530-539X","authenticated-orcid":false,"given":"Carola","family":"Schulzke","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Biochemie, Universit\u00e4t Greifswald, Felix-Hausdorff-Str. 4, 17489 Greifswald, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,6,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1039","DOI":"10.1016\/j.ccr.2010.11.027","article-title":"Bioinorganic chemistry of molybdenum and tungsten enzymes: A structural-functional modeling approach","volume":"255","author":"Majumdar","year":"2011","journal-title":"Coord. 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