{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T23:02:45Z","timestamp":1792623765433,"version":"4.5.0"},"reference-count":74,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T00:00:00Z","timestamp":1656547200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A mixed-valent trinuclear complex with 1,3-bis(5-chlorosalicylideneamino)-2-propanol (H3clsalpr) was synthesized, and the crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. The molecule is a trinuclear CoIII-CoII-CoIII complex with octahedral geometries, having a tetradentate chelate of the Schiff-base ligand, bridging acetate, monodentate acetate coordination to each terminal Co3+ ion and four bridging phenoxido-oxygen of two Schiff-base ligands, and two bridging acetate-oxygen atoms for the central Co2+ ion. The electronic spectral feature is consistent with the mixed valent CoIII-CoII-CoIII. Variable-temperature magnetic susceptibility data could be analyzed by consideration of the axial distortion of the central Co2+ ion with the parameters \u0394 = \u2013254 cm\u22121, \u03bb = \u201358 cm\u22121, \u03ba = 0.93, tip = 0.00436 cm3 mol\u22121, \u03b8 = \u20130.469 K, gz = 6.90, and gx = 2.64, in accordance with a large anisotropy. The cyclic voltammogram showed an irreversible reduction wave at approximately \u22121.2 V\u00b7vs. Fc\/Fc+, assignable to the reduction of the terminal Co3+ ions.<\/jats:p>","DOI":"10.3390\/molecules27134211","type":"journal-article","created":{"date-parts":[[2022,7,1]],"date-time":"2022-07-01T00:21:50Z","timestamp":1656634910000},"page":"4211","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Mixed-Valent Trinuclear CoIII-CoII-CoIII Complex with 1,3-Bis(5-chlorosalicylideneamino)-2-propanol"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7918-6802","authenticated-orcid":false,"given":"Masahiro","family":"Mikuriya","sequence":"first","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuko","family":"Naka","sequence":"additional","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ayumi","family":"Inaoka","sequence":"additional","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mika","family":"Okayama","sequence":"additional","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daisuke","family":"Yoshioka","sequence":"additional","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8285-3362","authenticated-orcid":false,"given":"Hiroshi","family":"Sakiyama","sequence":"additional","affiliation":[{"name":"Department of Science, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata 990-8560, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8943-2472","authenticated-orcid":false,"given":"Makoto","family":"Handa","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0716-7332","authenticated-orcid":false,"given":"Motohiro","family":"Tsuboi","sequence":"additional","affiliation":[{"name":"School of Biological and Environmental Sciences, Kwansei Gakuin University, Uegahara 1, Gakuen, Sanda 669-1330, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,6,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"391","DOI":"10.1016\/S0010-8545(00)80080-6","article-title":"Schiff Base Metal Complexes as Ligands","volume":"4","author":"Sinn","year":"1969","journal-title":"Coord. Chem. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1016\/S0010-8545(00)80018-1","article-title":"Structural aspects of metal complexes with some tetradentate Schiff bases","volume":"7","author":"Calligaris","year":"1972","journal-title":"Coord. Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"857","DOI":"10.1016\/S0010-8545(99)00050-8","article-title":"Coordinating ability of ligands derived from phenylenediamines","volume":"193\u2013195","author":"Mederos","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1016\/S0010-8545(01)00341-1","article-title":"d-f Heteronuclear complexes: Synthesis, structures and physicochemical aspects","volume":"219\u2013221","author":"Sakamoto","year":"2001","journal-title":"Coord. Chem. Rev."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1717","DOI":"10.1016\/j.cct.2003.09.003","article-title":"The challenge of cyclic and acyclic schiff bases and related derivatives","volume":"248","author":"Vigato","year":"2004","journal-title":"Coord. Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"2156","DOI":"10.1016\/j.ccr.2005.02.021","article-title":"Metal complexes of polyaza and polyoxaaza Schiff base macrocycles","volume":"249","author":"Patroniak","year":"2005","journal-title":"Coord. Chem. Rev."},{"key":"ref_7","first-page":"411","article-title":"Acyclic and Macrocyclic Schiff Base Ligands","volume":"Volume 1","author":"McCleverty","year":"2004","journal-title":"Comprehensive Coordination Chemistry II"},{"key":"ref_8","first-page":"279","article-title":"Assemblies Based on Schiff Base Chemistry","volume":"Volume 6","author":"Atwood","year":"2017","journal-title":"Comprehensive Supramolecular Chemistry II"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"94","DOI":"10.1016\/j.ccr.2019.03.010","article-title":"Recent developments in penta-, hexa- and heptadentate Schiff base ligands and their metal complexes","volume":"389","author":"Liu","year":"2019","journal-title":"Coord. Chem. Rev."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"3473","DOI":"10.1039\/DT9900003473","article-title":"Synthesis, and Characterization of Trinuclear Schiff-base Complexes containing Sulphur Dioxide or Hydrogensulphite Ions as Bridging Groups. Crystal Structure of [Zn{(\u00b5-CH3CO2)(salpd-\u00b5-O,O\u2019)Cu}2] [salpd = propane-1,3-diylbis(salicylideneiminate)]","volume":"19","author":"Fukuhara","year":"1990","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_11","first-page":"141","article-title":"Synthesis and Crystal Structure of Schiff Base N,N\u2032-Bis(2-Hydroxybenzylidene)-2-Hydroxy-1,3-propanediamine","volume":"16","author":"Liang","year":"1997","journal-title":"Jiegou Huaxue Chin. J. Struct. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1023\/A:1011355601133","article-title":"Conformation and structure of 1,3-bis(2-hydroxy-5-bromosalicylideneamine)propan-2-ol","volume":"30","author":"Elmali","year":"2000","journal-title":"J. Chem. Crystallogr."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"33","DOI":"10.2116\/xraystruct.35.33","article-title":"Synthesis and Crystal Structure of 1,3-Bis(5-chloro-3-methoxysalicylideneamino)-2-propanol Trihydrate","volume":"35","author":"Mikuriya","year":"2019","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_14","first-page":"53","article-title":"Crystal structure of 2-ethoxy-6-((E)-((3-(((E)-3-ethoxy-2-hydroxybenzylidene)amino)-2-hydroxypropyl)imino)methyl)phenolate, C21H26N2O5","volume":"235","author":"Su","year":"2020","journal-title":"Zeitschrift f\u00fcr Kristallographie New Cryst. Struct."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3","DOI":"10.2116\/xraystruct.38.3","article-title":"Crystal Structure of 1,3-Bis(3,5-dibromosalicylideneamino)-2-propanol","volume":"38","author":"Mikuriya","year":"2022","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"11","DOI":"10.2116\/xraystruct.32.11","article-title":"Synthesis and Crystal Structure of 1,3-Bis(5-nitrosalicylideneamino)-2-propanol","volume":"32","author":"Mikuriya","year":"2016","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"3258","DOI":"10.1021\/ic00214a033","article-title":"Magnetic interactions in Metal Complexes of Binucleating Ligands. 2. Synthesis and Properties of Binuclear Copper(II) Compounds Containing Exogenous Ligands That Bridge through Two Arms. Crystal and Molecular Structure of a Binuclear \u00b5-Pyrazolato-N,N\u2032-Bridged Dicopper(II) Complex of 1,3-Bis(salicylideneamino)propan-2-ol","volume":"24","author":"Mazurek","year":"1985","journal-title":"Inorg. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2633","DOI":"10.1039\/dt9860002633","article-title":"Crystal Structures and Magnetism of Binuclear Copper(II) Complexes with Alkoxide Bridges. Importance of Orbital Comlementarity in Spin Coupling through Two Different Bridging Groups","volume":"15","author":"Nishida","year":"1986","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"L55","DOI":"10.1016\/S0020-1693(00)84634-4","article-title":"Copper Complexes of Binucleating N,N\u2032-Hydroxyalkyldiaminebis(salicylidine) Ligands containing a Cu-O-Cu Bridge and an Exogenous Bridge","volume":"111","author":"Butcher","year":"1986","journal-title":"Inorg. Chim. Acta"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"334","DOI":"10.1246\/bcsj.65.334","article-title":"Binuclear Nickel(II) Complexes of Schiff Bases Derived from Salicylaldehydes and 1,n-Diamino-n\u2019-hydroxyalkanes (n,n\u2019 = 3,2; 4,2; and 5,3) Having an Endogenous Alkoxo Bridge and a Pyrazolato Exogenous Bridge","volume":"65","author":"Mikuriya","year":"1992","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3562","DOI":"10.1021\/ic00018a033","article-title":"Manganese(III) Complexes of a Binucleating Schiff-Base Ligand Based on the 1,3-Diaminopropan-2-ol Backbone","volume":"30","author":"Bertoncello","year":"1991","journal-title":"Inorg. Chem."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1466","DOI":"10.1246\/bcsj.65.1466","article-title":"1,3-Bis(salicylideneamino)-2-propanol as the Ligand for Manganese(III) Ions","volume":"65","author":"Mikuriya","year":"1992","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"7928","DOI":"10.1021\/ja00070a069","article-title":"[Mn(III)(2-OHsalpn)]2 Is an Efficient Functional Model for the Manganese Catalases","volume":"115","author":"Gelasco","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1829","DOI":"10.1021\/ic970140i","article-title":"The [Mn2(2-OHsalpn)2]2\u2212,\u2212,0,+ System: Synthesis, Structure, Spectroscopy, and Magnetism of the First Structurally Characterized Dinuclear Manganese Series Containing Four Distinct Oxidation States","volume":"36","author":"Gelasco","year":"1997","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"2037","DOI":"10.1021\/ic00310a008","article-title":"Structurally Diverse Manganese(III) Schiff Base Complexes: Chains, Dimers, and Cages","volume":"28","author":"Bonadies","year":"1989","journal-title":"Inorg. Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"2393","DOI":"10.1080\/00958972.2019.1647339","article-title":"Synthesis of three new binuclear Mn complexes: Characterization and DNA binding and cleavage properties","volume":"72","author":"Kou","year":"2019","journal-title":"J. Coord. Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"7","DOI":"10.2116\/xraystruct.36.7","article-title":"Dinuclear Manganese(III) Complex with a Schiff-base Having a Di-\u00b5-acetato-\u00b5-alkoxido-bridged Core","volume":"36","author":"Mikuriya","year":"2020","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1721","DOI":"10.1039\/b818113f","article-title":"Di-, tetra- and hexanuclear iron(III), manganese(II\/III) and copper(II) complexes of Schiff-base ligands derived from 6-substituted-2-formylphenols","volume":"38","author":"Lan","year":"2009","journal-title":"Dalton Trans."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"55","DOI":"10.2116\/xraystruct.32.55","article-title":"Synthesis and Crystal Structures of Dinuclear Cobalt(III) Complexes with 1,3-Bis(5-nitrosalicylideneamino)-2-propanol and 1,3-Bis(3-nitrosalicylideneamino)-2-propanol","volume":"32","author":"Mikuriya","year":"2016","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/j.ica.2018.09.043","article-title":"Mononuclear Cu(II) and Ni(II) complexes of bis(naphthalen-2-ol) Schiff base ligands","volume":"484","author":"Grundhoefer","year":"2019","journal-title":"Inorg. Chim. Acta"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1141","DOI":"10.1016\/j.saa.2006.05.027","article-title":"Synthesis, molecular structure, spectroscopic studies and second-order nonlinear optical behavior of N,N\u2032-(2-hydroxy-propane-1,3-diyl)-bis(5-nitrosalicylaldiminato-N,O)-copper(II)","volume":"A66","author":"Donmez","year":"2007","journal-title":"Spectrochim. Acta"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"30994","DOI":"10.1039\/C8RA03565B","article-title":"Coordination properties of N,N\u2032-bis(5-methylsalicylidene)-2-hydroxy-1,3-propanediamine with d- and f-electron ions: Crystal structure, stability in solution, spectroscopic and spectroelectrochemical studies","volume":"8","author":"Kaczmarek","year":"2018","journal-title":"RSC Adv."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"10854","DOI":"10.1039\/c2dt31143g","article-title":"Novel Pd(II)-salen complexes showing high in vitro anti-proliferative effects against human hepatoma cancer by modulating specific regulatory genes","volume":"41","author":"Azam","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"126985","DOI":"10.1016\/j.molstruc.2019.126985","article-title":"Synthesis, structural and DFT interpretation of a Schiff base assisted Mn(III) derivative","volume":"1199","author":"Das","year":"2020","journal-title":"J. Mol. Struct."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"446","DOI":"10.1039\/B913865J","article-title":"Is there really a diagnostically useful relationship between the carbon-oxygen stretching frequencies in metal carboxylate complexes and their coordination mode?","volume":"39","author":"Martinez","year":"2010","journal-title":"Dalton Trans."},{"key":"ref_36","first-page":"417","article-title":"Synthesis, Crystal Structures and Spectroscopic Properties of a Trinuclear [Cu3(HL)2(NO3)2](H2O)(CH2CH2OH) Complex and a [Mn(HL)(CH3COOH)]n Polymer With H3L=N,N\u2032-(2-hydroxypropane-1,3-dihyl)-bis-(salicylaldimine)","volume":"53","author":"Dieng","year":"2006","journal-title":"Acta Chim. Slov."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"9","DOI":"10.2116\/xraystruct.38.9","article-title":"Crystal Structure of a Hydrolyzed Product of the Cobalt(III) Complex with 1-(3,5-Dichlorosalicylideneamino)-3-amino-2-propanol","volume":"38","author":"Mikuriya","year":"2022","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1016\/j.ica.2014.06.014","article-title":"A perfectly linear trinuclear zinc-Schiff base complex: Synthesis, luminescence property and photocatalytic activity of zinc oxide nanoparticle","volume":"421","author":"Dey","year":"2014","journal-title":"Inorg. Chim. Acta"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"10233","DOI":"10.1039\/C6DT00380J","article-title":"Synthesis, magnetism and spectral studies of six defective dicubane tetranuclear {M4O6} (M = NiII, CoII, ZnII) and three trinuclear CdII complexes with polydentate Schiff base ligands","volume":"45","author":"Jiang","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"6866","DOI":"10.1002\/slct.201601648","article-title":"Synthesis, Electronic, Magnetic and Structural Characterization of New Trinuclear Mixed-Valence CoIII-CoII-CoIII Complex","volume":"1","author":"Boulon","year":"2016","journal-title":"ChemistrySelect"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1246\/bcsj.74.101","article-title":"Synthesis and Structural Characterization of Tetranuclear Zinc(II) Complexes with a Linear Array","volume":"74","author":"Mikuriya","year":"2001","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"853","DOI":"10.1007\/s11696-017-0305-6","article-title":"Mixed-valent tetranuclear manganese complexes with pentadentate Schiff-base ligand having a Y-shaped core","volume":"72","author":"Mikuriya","year":"2018","journal-title":"Chem. Pap."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Mikuriya, M., Kurahashi, S., Tomohara, S., Koyama, Y., Yoshioka, D., Mitsuhashi, R., and Sakiyama, H. (2019). Synthesis, Crystal Structures, and Magnetic Properties of Mixed-Valent Tetranuclear Complexes with Y-Shaped MnII2MnIII2 Core. Magnetochemistry, 5.","DOI":"10.3390\/magnetochemistry5010008"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"3306","DOI":"10.1039\/b602192a","article-title":"Ligand-induced distortion of a tetranuclear manganese butterfly complex","volume":"35","author":"Bagai","year":"2006","journal-title":"Dalton Trans."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1016\/j.saa.2018.07.050","article-title":"Synthesis, structure, and DNA binding\/cleavage of two novel binuclear Co(II) complexes","volume":"A205","author":"Kou","year":"2018","journal-title":"Spectrochim. Acta"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1652","DOI":"10.1039\/c0dt00923g","article-title":"Isolation of four new CoII\/CoIII and NiII complexes with a pentadentate Schiff base ligand: Synthesis, structural descriptions and magnetic studies","volume":"40","author":"Banerjee","year":"2011","journal-title":"Dalton Trans."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1002\/slct.201601698","article-title":"Structures and Magnetostructural Correlation Analyses for Two Novel Hexanuclear Complexes Based on a Pentadentate Schiff Base Ligand","volume":"2","author":"Yang","year":"2017","journal-title":"ChemistrySelect"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"33","DOI":"10.2116\/xraystruct.38.33","article-title":"Mixed-valent Manganese Complex with a Schiff-base Having a Di-\u00b54-oxido-di-\u00b53-oxido-di-\u00b53-carboxylato-hexa-\u00b5-carboxylato-bridged MnII2MnIII6 Core","volume":"38","author":"Mikuriya","year":"2022","journal-title":"X-ray Struct. Anal. Online"},{"key":"ref_49","doi-asserted-by":"crossref","unstructured":"Winpenny, R. (2006). Synthesis of 3d Metallic Single-Molecule Magnets. Structure and Bonding, Springer.","DOI":"10.1007\/b104234"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"8869","DOI":"10.1039\/C8CC04756A","article-title":"Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(II) complexes: Precise geometrical control by a hydrogen-bonded rigid metalloligand","volume":"54","author":"Mitsuhashi","year":"2018","journal-title":"Chem. Commun."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1016\/j.poly.2007.09.037","article-title":"Anion dependent formation of linear trinuclear mixed valance cobalt(III\/II\/III) complexes and mononuclear cobalt(III) complexes of a pyrazole derived ligand\u2014Synthesis, characterization and X-ray structures","volume":"27","author":"Pal","year":"2008","journal-title":"Polyhedron"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"1305","DOI":"10.1039\/DT9870001305","article-title":"Mixed Oxidation State Trinuclear Cobalt Complexes with Bridging Sulphito and Schiff-base Ligands. Part 1. Preparation of the Complexes [CoII(\u00b5-SO3)2(\u00b5-L)2CoIII2(ROH)2] (L = Schiff base anion, R = alkyl) and Structure Determination of [CoII(\u00b5-SO3)2(\u00b5-a,a\u2019-Me2-salpd)2CoIII2(PrnOH)2]\u00b72PrnOH","volume":"16","author":"Fukuhara","year":"1987","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1053","DOI":"10.1016\/j.inoche.2006.06.017","article-title":"First oxidative synthetic route of a novel linear mixed valence Co(III)\u2014Co(II)\u2014Co(III) complex with bridging acetate and salen","volume":"9","author":"Chattopadhyay","year":"2006","journal-title":"Inorg. Chem. Commun."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"686","DOI":"10.1016\/j.poly.2006.08.035","article-title":"A new trinuclear mixed-valence Co(II)-Co(III) complex stabilized by a bis(salicylidene) based ligand","volume":"26","author":"Banerjee","year":"2007","journal-title":"Polyhedron"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"1693","DOI":"10.1002\/ejic.200701025","article-title":"Methylene Spacer-Regulated Structural Variation in Cobalt(II\/III) Complexes with Bridging Acetate and Salen- or Salpn-Type Schiff-Base Ligands","volume":"2008","author":"Chattopadhyay","year":"2008","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"1405","DOI":"10.1016\/j.ica.2008.06.023","article-title":"Synthesis and crystal structures of mono-, di- and trinuclear cobalt complexes of a salen type ligand","volume":"362","author":"Welby","year":"2009","journal-title":"Inorg. Chim. Acta"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"322","DOI":"10.1016\/S1387-7003(02)00755-4","article-title":"Cobalt complexes with 2-[(3-aminopropyl)amino]ethanethiol","volume":"6","author":"Kotera","year":"2003","journal-title":"Inorg. Chem. Commun."},{"key":"ref_58","first-page":"0210102-01","article-title":"Synthesis, Crystal Structures, Electronic Spectra, and Magnetic Properties of Bis(\u00b5\u2013Thiolato)-Bridged Trinuclear CoII Complexes with Tridentate-N,N,S-Thiolates","volume":"3","author":"Mikuriya","year":"2021","journal-title":"Adv. Sustain. Sci. Eng. Technol."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"387","DOI":"10.3184\/174751912X13366711594575","article-title":"Synthesis and structure of a penta- and hexa-coordinated tri-nuclear cobalt(II) complex","volume":"36","author":"Dong","year":"2012","journal-title":"J. Chem. Res."},{"key":"ref_60","doi-asserted-by":"crossref","unstructured":"Li, X.-Y., Kang, Q.-P., Liu, L.-Z., Ma, J.-C., and Dong, W.-K. (2018). Trinuclear Co(II) and Mononuclear Ni(II) Salamo-Type Bisoxime Coordination Compounds. Crystals, 8.","DOI":"10.3390\/cryst8010043"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1246\/cl.1995.373","article-title":"Dinuclear Manganese(III) Complex with Cyclam-based Dodecadentate Ligand Bearing Schiff-base Pendants (Cyclam = 1,4,8,11-Tetraazacyclotetradecane)","volume":"24","author":"Mikuriya","year":"1995","journal-title":"Chem. Lett."},{"key":"ref_62","doi-asserted-by":"crossref","unstructured":"Nakamoto, K. (2009). Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Application in Coordination, Organometallic, and Bioinorganic Chemistry, John Wiley & Sons. [6th ed.].","DOI":"10.1002\/9780470405888"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1246\/bcsj.20090284","article-title":"Synthesis, Crystal Structures, and Magnetic Properties of Dinuclear and Hexanuclear Copper(II) Complexes with Cyclam-Based Macrocyclic Ligands Having Four Schiff-Base Pendant Arms","volume":"83","author":"Wada","year":"2010","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"126","DOI":"10.1515\/chempap-2015-0164","article-title":"Mononuclear cobalt(III) complexes with N-salicylidene-2-hydroxy-5-bromobenzylamine and N-salicylidene-2-hydroxy-5-chlorobenzylamine","volume":"70","author":"Mikuriya","year":"2016","journal-title":"Chem. Pap."},{"key":"ref_65","unstructured":"Ueno, K. (1976). Kireto Kagaku, Nankodo. (In Japanese)."},{"key":"ref_66","doi-asserted-by":"crossref","unstructured":"Lawrance, G.A. (2010). Introduction to Coordination Chemistry, John Wiley & Sons.","DOI":"10.1002\/9780470687123"},{"key":"ref_67","unstructured":"Grobelny, R., Melnik, M., and Mrozinski, J. (1996). Cobalt Coordination Compounds: Classification and Analysis of Crystallographic and Structural Data, Dolnoslaskie Wydawnictwo Edukacyjne."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1957","DOI":"10.1107\/S0567740876006869","article-title":"Empirical parameters for calculating cation-oxygen bond valences","volume":"32","author":"Brown","year":"1976","journal-title":"Acta Crystallogr. Sect. B"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"244","DOI":"10.1107\/S0108768185002063","article-title":"Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database","volume":"41","author":"Brown","year":"1985","journal-title":"Acta Crystallogr. Sect. B"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"2027","DOI":"10.1002\/1099-0682(200108)2001:8<2027::AID-EJIC2027>3.0.CO;2-Z","article-title":"Dinuclear Cobalt(II) Complexes of an Acyclic Phenol-Based Dinucleating Ligand with Four Methoxyethyl Chelating Arms\u2014First Magnetic Analysis in an Axially Distorted Octahedral Field","volume":"2001","author":"Sakiyama","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"171","DOI":"10.2477\/jchemsoft.7.171","article-title":"Development of MagSaki software for magnetic analysis of dinuclear high-spin cobalt(II) complexes in an axially distorted octahedral field","volume":"7","author":"Sakiyama","year":"2001","journal-title":"J. Chem. Softw."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"123","DOI":"10.2477\/jccj.6.123","article-title":"Development of MagSaki(A) software for the magnetic analysis of dinuclear high-spin cobalt(II) complexes considering anisotropy in exchange interaction","volume":"6","author":"Sakiyama","year":"2007","journal-title":"J. Comput. Chem. Jpn."},{"key":"ref_73","unstructured":"Kahn, O. (1993). Molecular Magnetism, VCH."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. Sect. A"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/13\/4211\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T23:40:59Z","timestamp":1760139659000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/13\/4211"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,6,30]]},"references-count":74,"journal-issue":{"issue":"13","published-online":{"date-parts":[[2022,7]]}},"alternative-id":["molecules27134211"],"URL":"https:\/\/doi.org\/10.3390\/molecules27134211","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,6,30]]}}}