{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T18:30:49Z","timestamp":1789583449965,"version":"build-2803163510"},"reference-count":86,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2022,7,11]],"date-time":"2022-07-11T00:00:00Z","timestamp":1657497600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100011789","name":"Jilin Provincial Department of Science and Technology","doi-asserted-by":"publisher","award":["20190802027ZG"],"award-info":[{"award-number":["20190802027ZG"]}],"id":[{"id":"10.13039\/501100011789","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011789","name":"Jilin Provincial Department of Science and Technology","doi-asserted-by":"publisher","award":["00321JYT01AL"],"award-info":[{"award-number":["00321JYT01AL"]}],"id":[{"id":"10.13039\/501100011789","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Scientific Research Fund of Zhejiang Provincial Education Department","award":["20190802027ZG"],"award-info":[{"award-number":["20190802027ZG"]}]},{"name":"Scientific Research Fund of Zhejiang Provincial Education Department","award":["00321JYT01AL"],"award-info":[{"award-number":["00321JYT01AL"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Three compounds based on Ge-V-O clusters were hydrothermally synthesized and characterized by IR, UV-Vis, XRD, ESR, elemental analysis and X-ray crystal structural analysis. Both [Cd(phen)(en)]2[Cd2(phen)2V12O40Ge8(OH)8(H2O)]\u221912.5H2O (1) and [Cd(DETA)]2[Cd(DETA)2]0.5[Cd2(phen)2V12O41Ge8(OH)7(0.5H2O)]\u22197.5H2O (2) (1,10-phen = 1,10-phenanthroline, en = ethylenediamine, DETA = diethylenetriamine) are the first Ge-V-O cluster compounds containing aromatic organic ligands. Compound 1 is the first dimer of Ge-V-O clusters, which is linked by a double bridge of two [Cd(phen)(en)]2+. Compound 2 exhibits an unprecedented 1-D chain structure formed by Ge-V-O clusters and [Cd2(DETA)2]4+ transition metal complexes (TMCs). [Cd(en)3]{[Cd(\u03b72-en)2]3[Cd(\u03b72-en)(\u03b72-\u03bc2-en)(\u03b72-en)Cd][Ge6V15O48(H2O)]}\u22195.5H2O (3) is a novel 3-D structure which is constructed from [Ge6V15O48(H2O)]12\u2212 and four different types of TMCs. We also synthesized [Zn2(enMe)3][Zn(enMe)]2[Zn(enMe)2(H2O)]2[Ge6V15O48(H2O)]\u22193H2O (4) and [Cd(en)2]2{H8[Cd(en)]2Ge8V12O48(H2O)}\u22196H2O (5) (enMe = 1,2-propanediamine), which have been reported previously. In addition, the catalytic properties of these five compounds for styrene epoxidation have been assessed.<\/jats:p>","DOI":"10.3390\/molecules27144424","type":"journal-article","created":{"date-parts":[[2022,7,11]],"date-time":"2022-07-11T21:57:53Z","timestamp":1657576673000},"page":"4424","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["First Organic\u2013Inorganic Hybrid Compounds Formed by Ge-V-O Clusters and Transition Metal Complexes of Aromatic Organic Ligands"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9657-6965","authenticated-orcid":false,"given":"Hai-Yang","family":"Guo","sequence":"first","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry and College of Chemistry, Jilin University, Changchun 130021, China"},{"name":"College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing 314001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Qi","sequence":"additional","affiliation":[{"name":"The Second Hospital of Jilin University, Changchun 130021, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Zhang","sequence":"additional","affiliation":[{"name":"MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Bing","family":"Cui","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry and College of Chemistry, Jilin University, Changchun 130021, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,7,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"102178","DOI":"10.1016\/j.cis.2020.102178","article-title":"Nanostructured metal oxides and its hybrids for photocatalytic and biomedical applications","volume":"281","author":"Kannan","year":"2020","journal-title":"Adv. Colloid. Interface. Sci."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"131656","DOI":"10.1016\/j.molstruc.2021.131656","article-title":"Punica granatum pericarp extract catalyzed green chemistry approach for synthesizing novel ligand and its metal(II) complexes: Molecular docking\/DNA interactions","volume":"1249","author":"Vidyavathi","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"7764","DOI":"10.1016\/j.ijhydene.2019.07.241","article-title":"Recent progress in metal-doped TiO2, non-metal doped\/codoped TiO2 and TiO2 nanostructured hybrids for enhanced photocatalysis","volume":"45","author":"Basavarajappa","year":"2020","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.microc.2019.02.061","article-title":"Role of conducting polymer and metal oxide-based hybrids for applications in ampereometric sensors and biosensors","volume":"147","author":"Dakshayini","year":"2019","journal-title":"Microchem. J."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Balakumar, S., Keller, V., and Shankar, M.V. (2021). Nanostructured Materials for Environmental Applications, Springer.","DOI":"10.1007\/978-3-030-72076-6"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"13253","DOI":"10.1002\/chem.201001434","article-title":"A Series of Vanadogermanates from 1D Chain to 3D Framework Built by Ge\u2013V\u2013O Clusters and Transition-Metal-Complex Bridges","volume":"16","author":"Zhou","year":"2010","journal-title":"Chem. Eur. J."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"15872","DOI":"10.1021\/ja8014154","article-title":"Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives","volume":"130","author":"Kikukawa","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"996","DOI":"10.1126\/science.1073979","article-title":"A General Synthetic Procedure for Heteropolyniobates","volume":"297","author":"Nyman","year":"2002","journal-title":"Science"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"844","DOI":"10.1002\/anie.200462662","article-title":"Polyoxometalate Nanostructures, Superclusters, and Colloids: From Functional Clusters to Chemical Aesthetics","volume":"44","author":"Cronin","year":"2005","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"10133","DOI":"10.1021\/ja029348f","article-title":"Electrochemical Investigation of Photooxidation Processes Promoted by Sulfo-polyoxometalates: Coupling of Photochemical and Electrochemical Processes into an Effective Catalytic Cycle","volume":"125","author":"Hultgren","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"3909","DOI":"10.1002\/anie.200705709","article-title":"Designed Synthesis of POM\u2013Organic Frameworks from {Ni6PW9} Building Blocks under Hydrothermal Conditions","volume":"47","author":"Zheng","year":"2008","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1858","DOI":"10.1039\/b617191e","article-title":"Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain","volume":"18","author":"Zheng","year":"2007","journal-title":"Chem. Commun."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"10066","DOI":"10.1021\/ja073153w","article-title":"Chiral Polyoxometalate-Induced Enantiomerically 3D Architectures: A New Route for Synthesis of High-Dimensional Chiral Compounds","volume":"129","author":"Tan","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"6881","DOI":"10.1002\/anie.200802594","article-title":"Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid","volume":"47","author":"Ritchie","year":"2008","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"7579","DOI":"10.1002\/anie.200702698","article-title":"Modular Assembly of a Functional Polyoxometalate-Based Open Framework Constructed from Unsupported AgI\u22c5\u22c5\u22c5AgI Interactions","volume":"46","author":"Streb","year":"2007","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1830","DOI":"10.1021\/ja075940z","article-title":"Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry: Protonation versus Heteroatom Inclusion","volume":"130","author":"Long","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"7055","DOI":"10.1002\/anie.200903275","article-title":"Inorganic Cryptand: Size-Selective Strong Metallic Cation Encapsulation by a Disilicoicosatungstate (Si2W20) Polyoxometalate","volume":"48","author":"Yoshida","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"3466","DOI":"10.1002\/anie.200806247","article-title":"Chiral Recognition of Hybrid Metal Oxide by Peptides","volume":"48","author":"Micoine","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_19","first-page":"1189","article-title":"\u2018Adding\u2019 stable functional complementary, nucleophilic and electrophilic clusters: A synthetic route to [{(SiW11O39)Mo3S4(H2O)3(\u00b5-OH)}2]10\u2212 and [{(P2W17O61)Mo3S4(H2O)3(\u00b5-OH)}2]14\u2212 as examples","volume":"35","author":"Fedin","year":"1999","journal-title":"Chem. Commun."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"492","DOI":"10.1039\/B309255K","article-title":"A host\u2013guest complex between a metal\u2013organic cyclotriveratrylene analog and a polyoxometalate: [Cu6(4,7-phenanthroline)8(MeCN)4]2PM12O40 (M = Mo or W)","volume":"40","author":"Knaust","year":"2004","journal-title":"Chem. Commun."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"2702","DOI":"10.1002\/anie.200453693","article-title":"Porous Organic\u2013Inorganic Assemblies Constructed from Keggin Polyoxometalate Anions and Calix[4]arene\u2013Na+ Complexes: Structures and Guest-Sorption Profiles","volume":"43","author":"Ishii","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"5957","DOI":"10.1021\/ic070274o","article-title":"Zeolite Ionic Crystals Assembled through Direct Incorporation of Polyoxometalate Clusters within 3D Metal\u2013Organic Frameworks","volume":"46","author":"Wei","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2512","DOI":"10.1039\/b201287c","article-title":"1D and 2D polyoxometalate-based composite compounds. Synthesis and crystal structure of [{Ba(DMSO)5(H2O)}2(SiMo12O40)] and [{Ba(DMSO)3(H2O)3}{Ba(DMSO)5(H2O)}(GeMo12O40)]","volume":"31","author":"Niu","year":"2002","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2535","DOI":"10.1021\/cg070438b","article-title":"Assembly of Multitrack Cu\u2013N Coordination Polymeric Chain-Modified Polyoxometalates Influenced by Polyoxoanion Cluster and Ligand","volume":"7","author":"Sha","year":"2007","journal-title":"Cryst. Growth Des."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"259","DOI":"10.1016\/S1387-7003(02)00740-2","article-title":"Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups: [As8IIIV14IVO42(CO3)][Cu(en)2]3\u221910H2O","volume":"6","author":"Cui","year":"2003","journal-title":"Inorg. Chem. Commun."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1051","DOI":"10.1002\/ejic.200300593","article-title":"Hydrothermal Synthesis and Characterization of a Novel Sinusoidal Layer Structure Constructed from Polyoxometalates and Coordination Complex Fragments","volume":"7","author":"Cui","year":"2004","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"58","DOI":"10.1016\/j.inoche.2003.10.004","article-title":"Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments","volume":"7","author":"Cui","year":"2004","journal-title":"Inorg. Chem. Commun."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2251","DOI":"10.1039\/C3CE42450B","article-title":"The synthesis and characterization of three organic\u2013inorganic hybrids based on different transition metal complexes and {As8V14O42(H2O)} clusters","volume":"16","author":"Guo","year":"2014","journal-title":"CrystEngComm"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.ica.2015.12.033","article-title":"Structural influences of arsenic\u2013vanadium clusters and transition metal complexes on final structures of arsenic\u2013vanadium-based hybrids","volume":"443","author":"Guo","year":"2016","journal-title":"Inorg. Chim. Acta"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1039\/C5CE01983D","article-title":"New self-assembly hybrid compounds based on arsenic\u2013vanadium clusters and transition metal mixed-organic-ligand complexes","volume":"18","author":"Guo","year":"2016","journal-title":"CrystEngComm"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"3740","DOI":"10.1016\/j.jssc.2005.09.029","article-title":"Hybrid inorganic\u2013organic 1-D and 2-D frameworks with {As8V14O42} clusters as building blocks","volume":"178","author":"Zheng","year":"2005","journal-title":"J. Solid State Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"5584","DOI":"10.1039\/b806770h","article-title":"The first solid composed of {As4V16O42(H2O)} clusters","volume":"41","author":"Zheng","year":"2008","journal-title":"Dalton Trans."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1002\/ejic.200500682","article-title":"Hybrid Inorganic\u2013Organic 1D and 2D Frameworks with [As6V15O42]6\u2212 Polyoxoanions as Building Blocks","volume":"9","author":"Zheng","year":"2006","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"Zheng, S.T., Zhang, M., and Yang, G.Y. (2004). [{Zn(enMe)2}2(enMe)2{Zn2As8V12O40(H2O)}]\u22194H2O: A Hybrid Molecular Material Based on Covalently Linked Inorganic Zn\u2013As\u2013V Clusters and Transition Metal Complexes via enMe Ligands. Eur. J. Inorg. Chem., 2004\u20132007.","DOI":"10.1002\/ejic.200400019"},{"key":"ref_35","first-page":"5057","article-title":"A New 2-D Network Containing {As4V16O42(H2O)} Cluster Units","volume":"34","author":"Zhou","year":"2009","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1841","DOI":"10.1016\/j.ica.2006.09.021","article-title":"Syntheses and structures of four organic\u2013inorganic hybrids based on the surface restricted building unit and various zinc coordination groups","volume":"360","author":"Qi","year":"2007","journal-title":"Inorg. Chim. Acta"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1016\/j.jssc.2006.10.005","article-title":"Two unprecedented inorganic\u2013organic boxlike and chainlike hybrids based on arsenic\u2013vanadium clusters linked by nickel complexes","volume":"180","author":"Qi","year":"2007","journal-title":"J. Solid State Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"3217","DOI":"10.1021\/ic062338l","article-title":"From Chain to Network: Design and Analysis of Novel Organic\u2013Inorganic Assemblies from Organically Functionalized Zinc-Substituted Polyoxovanadates and Zinc Organoamine Subunits","volume":"46","author":"Qi","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"3275","DOI":"10.1039\/B206250J","article-title":"A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters: [{Co(en)2}2SbIII8VIV14O42(H2O)]\u22196H2O","volume":"31","author":"Zhang","year":"2002","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1016\/j.inoche.2003.11.019","article-title":"A novel one-dimensional framework material constructed from antimony-substituted polyoxovanadium clusters: [(C2N2H10)2\u03b2-{SbIII8VIV14O42(H2O)}](C2N2H8)\u22194H2O","volume":"7","author":"Hu","year":"2004","journal-title":"Inorg. Chem. Commun."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"5130","DOI":"10.1039\/C6CE00616G","article-title":"Vanadoantimonates: From discrete clusters to high dimensional aggregates","volume":"18","author":"Guo","year":"2016","journal-title":"CrystEngComm"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"764","DOI":"10.1002\/anie.201002563","article-title":"Organic Functionalization of Polyoxovanadates: Sb-N Bonds and Charge Control","volume":"50","author":"Antonova","year":"2011","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"6957","DOI":"10.1039\/c2dt30319a","article-title":"A C2-symmetric antimonato polyoxovanadate cluster [V16Sb4O42(H2O)]8\u2212 derived from the {V18O42} archetype","volume":"41","author":"Antonova","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1338","DOI":"10.1039\/C1DT11635E","article-title":"Antimonato polyoxovanadates with structure directing transition metal complexes: Pseudopolymorphic {Ni(dien)2}3[V15Sb6O42(H2O)]\u2219nH2O compounds and {Ni(dien)2}4[V16Sb4O42(H2O)]","volume":"41","author":"Antonova","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"6853","DOI":"10.1039\/c2ce25896j","article-title":"Assembly of [V15Sb6O42(H2O)]6\u2212 cluster shells into higher dimensional aggregates via weak Sb\u22efN\/Sb\u22efO intercluster interactions and a new polyoxovanadate with a discrete [V16Sb4O42(H2O)]8\u2212 cluster shell","volume":"14","author":"Antonova","year":"2012","journal-title":"CrystEngComm"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1916","DOI":"10.1021\/ic800042r","article-title":"[V16Sb4O42(H2O){VO(C6H14N2)2}4]: A Terminal Expansion to a Polyoxovanadate Archetype","volume":"47","author":"Wutkowski","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"3280","DOI":"10.1021\/ic302788w","article-title":"Antimonato Polyoxovanadate Based Three-Dimensional Framework Exhibiting Ferromagnetic Exchange Interactions: Synthesis, Structural Characterization, and Magnetic Investigation of {[Fe(C6H14N2)2]3[V15Sb6O42(H2O)]}\u22198H2O","volume":"52","author":"Wutkowski","year":"2013","journal-title":"Inorg. Chem."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"964","DOI":"10.1016\/j.solidstatesciences.2006.02.046","article-title":"[C6H17N3]4[Sb4V16O42]\u22c52H2O and [NH4]4[Sb8V14O42]\u22c52H2O\u2014The first isolated Sb derivates of the [V18O42] family","volume":"8","author":"Kiebach","year":"2006","journal-title":"Solid. State. Sci."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"3221","DOI":"10.1039\/b708744f","article-title":"[VIV15SbIII6O42]6\u2212: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6\u2212","volume":"36","author":"Kiebach","year":"2007","journal-title":"Dalton Trans."},{"key":"ref_50","first-page":"549","article-title":"Solvothermal synthesis and crystal structure of a heterometal-bridged {V15Sb6} dimer: [Ni2(tren)3(V15Sb6O42(H2O)0.5)]2[Ni(trenH)2]\u2219H2O","volume":"421","author":"Bensch","year":"2014","journal-title":"Inorg. Chim. Acta"},{"key":"ref_51","first-page":"426","article-title":"Hydrothermal Synthesis and Crystal Structure of a New 2D Layer Compound [{Ni(en)2}2Sb8V14O42]\u22195.5H2O","volume":"25","author":"Li","year":"2009","journal-title":"Chem. Res. Chin. Univ."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1007\/s10876-010-0309-7","article-title":"pH-Dependent Assembly of Two Novel Organic\u2013inorganic Hybrids Based on Vanadoantimonate Clusters","volume":"21","author":"Gao","year":"2010","journal-title":"J. Cluster. Sci."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"8443","DOI":"10.1039\/C5CS00531K","article-title":"Semimetal-functionalised polyoxovanadates","volume":"44","author":"Monakhov","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"8005","DOI":"10.1021\/ic0492892","article-title":"A Novel Chainlike As\u2013V\u2013O Polymer Based on a Transition Metal Complex and a Dimeric Polyoxoanion","volume":"43","author":"Cui","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2411","DOI":"10.1039\/c3ce26726a","article-title":"A new type of germanium\u2013vanadate cluster, [Ge5V6O21(heda)6] (Hheda = N-(2-hydroxyethyl)ethylenediamine)","volume":"15","author":"You","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1039\/b208489a","article-title":"The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure: Solvothermal synthesis and characterization","volume":"32","author":"Chen","year":"2003","journal-title":"Dalton Trans."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"3728","DOI":"10.1021\/ic0206185","article-title":"Vanadogermanate Cluster Anions","volume":"42","author":"Whitfield","year":"2003","journal-title":"Inorg. Chem."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1007\/s10876-006-0048-y","article-title":"Polyoxoanion with Octahedral Germanium(IV) Hetero Atom: Synthesis, Structure, Magnetism, EPR, Electrochemistry and XPS Studies on the Mixed-Valence 14-Vanadogermanate [GeVV12VIV2O40]8\u2212","volume":"17","author":"Bi","year":"2006","journal-title":"J. Cluster Sci."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"4399","DOI":"10.1016\/j.ica.2010.06.065","article-title":"Synthesis, crystal structure and magnetism of a new mixed germanium\u2013polyoxovanadate cluster","volume":"363","author":"Wang","year":"2010","journal-title":"Inorg. Chim. Acta"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"10528","DOI":"10.1021\/ja0365173","article-title":"The First Framework Solid Composed of Vanadosilicate Clusters","volume":"125","author":"Tripathi","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"1305","DOI":"10.1002\/anie.200503140","article-title":"Vanadoantimonates: From discrete clusters to high dimensional aggregates Two Compounds Containing the Mixed Germanium\u2013Vanadium Polyoxothioanion [V14Ge8O42S8]12\u2212","volume":"45","author":"Pitzschke","year":"2006","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"3373","DOI":"10.1080\/00958972.2010.511665","article-title":"Syntheses, structures, and magnetism of {V15M6O42(OH)6(Cl)} (M=Si, Ge)","volume":"63","author":"Gao","year":"2010","journal-title":"J. Coord. Chem."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"6122","DOI":"10.1039\/c2dt30199g","article-title":"Two three-dimensional {V16Ge4}\u2212 based open frameworks stabilized by diverse types of CoII-amine bridges and magnetic properties","volume":"41","author":"Gao","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"10283","DOI":"10.1039\/c3ce41512k","article-title":"Chain and layer networks of germanato-polyoxovanadates","volume":"15","author":"Wang","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_65","doi-asserted-by":"crossref","unstructured":"Wang, J., N\u00e4ther, C., K\u00f6gerler, P., and Bensch, W. (2012). [V15Ge6O42S6(H2O)]12\u2212, a Thiogermanatopolyoxovanadate Cluster Featuring the Spin Topology of the Molecular Magnet [V15As6O42(H2O)]6\u2212. Eur. J. Inorg. Chem., 1237\u20131242.","DOI":"10.1002\/ejic.201101187"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"5065","DOI":"10.1021\/ja413218w","article-title":"Two Tetra-CdII-Substituted Vanadogermanate Frameworks","volume":"136","author":"Zhou","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"10838","DOI":"10.1021\/ja801560t","article-title":"CO2 Coordination by Inorganic Polyoxoanion in Water","volume":"130","author":"Gao","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"5956","DOI":"10.1021\/ja101671q","article-title":"Polyoxometalatocyclophanes: Controlled Assembly of Polyoxometalate-Based Chiral Metallamacrocycles from Achiral Building Blocks","volume":"132","author":"Xiao","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref_69","doi-asserted-by":"crossref","unstructured":"Miras, H.N., Wilson, E.F., and Cronin, L. (2009). Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry. Chem. Commun., 1297\u20131311.","DOI":"10.1039\/b819534j"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"11183","DOI":"10.1021\/ic7014308","article-title":"Asymmetrical Polar Modification of a Bivanadium-Capped Keggin POM by Multiple Cu\u2212N Coordination Polymeric Chains","volume":"46","author":"Sha","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"12466","DOI":"10.1021\/acs.chemrev.6b00346","article-title":"Structures of Metal\u2013Organic Frameworks with Rod Secondary Building Units","volume":"116","author":"Schoedel","year":"2016","journal-title":"Chem. Rev."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"6479","DOI":"10.1021\/acs.inorgchem.8b00541","article-title":"Polyoxometalate-Supported Bis(2,2\u2032-bipyridine)mono(aqua)nickel(II) Coordination Complex: An Efficient Electrocatalyst for Water Oxidation","volume":"57","author":"Singh","year":"2018","journal-title":"Inorg. Chem."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. Sec. A"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"3252","DOI":"10.1021\/ic991473d","article-title":"Structural Influences of Organonitrogen Ligands on Vanadium Oxide Solids. Hydrothermal Syntheses and Structures of the Terpyridine Vanadates [V2O4(Terpy)2]3[V10O28], [VO2(Terpy)][V4O10], and [V9O22(Terpy)3]","volume":"39","author":"Hagrman","year":"2000","journal-title":"Inorg. Chem."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"244","DOI":"10.1107\/S0108768185002063","article-title":"The automatic searching for chemical bonds in inorganic crystal structures","volume":"B41","author":"Brown","year":"1985","journal-title":"Acta Cryst."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"1238","DOI":"10.1246\/cl.2002.1238","article-title":"[{(H2O)Ni(enMe)2MoV4MoVI4VIV8(VVO4)O40}2{Ni(enMe)2}][Ni(enMe)2]4\u22198H2O: The First Dimer of Polyoxometalates Linked through Coordination Fragment","volume":"31","author":"Cui","year":"2002","journal-title":"Chem. Lett."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1039\/C6CE02205G","article-title":"Preparation, structure and characterization of a series of vanadates","volume":"19","author":"Guo","year":"2017","journal-title":"CrystEngComm"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"9192","DOI":"10.1021\/ic3001834","article-title":"[V16O38(CN)]9\u2212: A Soluble Mixed-Valence Redox-Active Building Block with Strong Antiferromagnetic Coupling","volume":"51","author":"Keene","year":"2012","journal-title":"Inorg. Chem."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"138","DOI":"10.1016\/j.jcat.2015.10.003","article-title":"Mesoporous niobium-silicates prepared by evaporation-induced self-assembly as catalysts for selective oxidations with aqueous H2O2","volume":"332","author":"Ivanchikova","year":"2015","journal-title":"J. Catal."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"210","DOI":"10.1016\/j.jorganchem.2015.04.020","article-title":"Selective oxidation of pseudocumene and 2-methylnaphthalene with aqueous hydrogen peroxide catalyzed by \u03b3-Keggin divanadium-substituted polyoxotungstate","volume":"793","author":"Zalomaeva","year":"2015","journal-title":"J. Organomet. Chem."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"7354","DOI":"10.1039\/c2cs35136f","article-title":"A comprehensive comparison of transition-metal and actinyl polyoxometalates","volume":"41","author":"Nyman","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/j.cattod.2009.03.011","article-title":"Polyoxometalate as effective catalyst for the deep desulfurization of diesel oil","volume":"149","author":"Wang","year":"2010","journal-title":"Catal. Today"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"1811","DOI":"10.1016\/S1872-2067(15)60919-6","article-title":"Kinetics and mechanism of thymine degradation by TiO2 photocatalysis","volume":"36","author":"Gao","year":"2015","journal-title":"Chin. J. Catal."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"16655","DOI":"10.1039\/C7DT03198J","article-title":"Hybrid compounds assembled from copper-triazole complexes and phosphomolybdic acid as advanced catalysts for the oxidation of olefins with oxygen","volume":"46","author":"Song","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"3249","DOI":"10.1246\/bcsj.67.3249","article-title":"X-Ray Structural Characterization of the Protonation Sites in the Dihydrogenhexaniobate Anion","volume":"67","author":"Ozeki","year":"1994","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"14004","DOI":"10.1021\/ja303723u","article-title":"Self-Assembly and Photocatalytic Properties of Polyoxoniobates: {Nb24O72}, {Nb32O96}, and {K12Nb96O288} Clusters","volume":"134","author":"Huang","year":"2012","journal-title":"J. Am. Chem. Soc."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/14\/4424\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T23:47:47Z","timestamp":1760140067000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/14\/4424"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,7,11]]},"references-count":86,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2022,7]]}},"alternative-id":["molecules27144424"],"URL":"https:\/\/doi.org\/10.3390\/molecules27144424","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,7,11]]}}}