{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T17:35:39Z","timestamp":1791221739055,"version":"4.1.0"},"reference-count":40,"publisher":"MDPI AG","issue":"15","license":[{"start":{"date-parts":[[2022,7,30]],"date-time":"2022-07-30T00:00:00Z","timestamp":1659139200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Project of Anhui Province Academic and Technical Leader","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Project of Anhui Province Academic and Technical Leader","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Primary Research and Development Program of Anhui Province","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Natural Science Foundation of Anhui Province","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Natural Science Research Key Project of Anhui Provincial Department of Education","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Provincial of the Anhui Scientific Research Innovation Team of Photoelectric Information Materials and New Energy Devices","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Key Discipline of Material Science and Engineering of Suzhou University","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Doctor of Suzhou University Scientific Research Foundation Project","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["2020D250"],"award-info":[{"award-number":["2020D250"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["201904a05020087"],"award-info":[{"award-number":["201904a05020087"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["1908085ME120"],"award-info":[{"award-number":["1908085ME120"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["KJ2020A0727"],"award-info":[{"award-number":["KJ2020A0727"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["2016SCXPTTD"],"award-info":[{"award-number":["2016SCXPTTD"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["2017XJZDXK3"],"award-info":[{"award-number":["2017XJZDXK3"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["2020BS014"],"award-info":[{"award-number":["2020BS014"]}]},{"name":"Anhui University of Science and Technology Graduate Innovation Fund","award":["2021CX2114"],"award-info":[{"award-number":["2021CX2114"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Flexible supercapacitors (FSCs) are limited in flexible electronics applications due to their low energy density. Therefore, developing electrode materials with high energy density, high electrochemical activity, and remarkable flexibility is challenging. Herein, we designed nitrogen-doped porous MXene (N-MXene), using melamine-formaldehyde (MF) microspheres as a template and nitrogen source. We combined it with an electrospinning process to produce a highly flexible nitrogen-doped porous MXene nanofiber (N-MXene-F) as a self-supporting electrode material and assembled it into a symmetrical supercapacitor (SSC). On the one hand, the interconnected mesh structure allows the electrolyte to penetrate the porous network to fully infiltrate the material surface, shortening the ion transport channels; on the other hand, the uniform nitrogen doping enhances the pseudocapacitive performance. As a result, the as-assembled SSC exhibited excellent electrochemical performance and excellent long-term durability, achieving an energy density of 12.78 Wh kg\u22121 at a power density of 1080 W kg\u22121, with long-term cycling stability up to 5000 cycles. This work demonstrates the impact of structural design and atomic doping on the electrochemical performance of MXene and opens up an exciting possibility for the fabrication of highly FSCs.<\/jats:p>","DOI":"10.3390\/molecules27154890","type":"journal-article","created":{"date-parts":[[2022,8,1]],"date-time":"2022-08-01T04:04:00Z","timestamp":1659326640000},"page":"4890","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Nitrogen-Doped Porous MXene (Ti3C2) for Flexible Supercapacitors with Enhanced Storage Performance"],"prefix":"10.3390","volume":"27","author":[{"given":"Xin","family":"Tao","sequence":"first","affiliation":[{"name":"School of Mechanics and Optoelectronic Physics, Anhui University of Science and Technology, Huainan 232001, China"},{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linlin","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Mechanics and Optoelectronic Physics, Anhui University of Science and Technology, Huainan 232001, China"},{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0368-0019","authenticated-orcid":false,"given":"Xuedong","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Leather of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingzi","family":"Fang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyan","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lianghao","family":"Yu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, School of Mechanical and Electronic Engineering, Suzhou University, Suzhou 234000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,7,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1603","DOI":"10.1126\/science.1182383","article-title":"Materials and mechanics for stretchable electronics","volume":"327","author":"Rogers","year":"2010","journal-title":"Science"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1700259","DOI":"10.1002\/smtd.201700259","article-title":"3D Printing of flexible electronic devices","volume":"2","author":"Yang","year":"2018","journal-title":"Small Methods"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1016\/j.jcis.2021.06.041","article-title":"A fully 3D printed electronic skin with bionic high resolution and air permeable porous structure","volume":"602","author":"Pei","year":"2021","journal-title":"J. Colloid Interf. Sci."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1805921","DOI":"10.1002\/adma.201805921","article-title":"Significance of nanomaterials in wearables: A review on wearable actuators and sensors","volume":"31","author":"Jayatgukaka","year":"2019","journal-title":"Adv. Mater."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.mser.2017.05.001","article-title":"Graphene-based flexible electronic devices","volume":"118","author":"Han","year":"2017","journal-title":"Mat. Sci. Eng. R"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"8099","DOI":"10.1039\/D0TA12299H","article-title":"Electrode materials and device architecture strategies for flexible supercapacitors in wearable energy storage","volume":"9","author":"Zhang","year":"2021","journal-title":"J. Mater. Chem. A"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"315","DOI":"10.1016\/j.ensm.2020.03.009","article-title":"Stretchable electrolytes for stretchable\/flexible energy storage systems\u2013recent developments","volume":"28","author":"Mohanta","year":"2020","journal-title":"Energy Storage Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"500","DOI":"10.1016\/j.ensm.2022.06.044","article-title":"Recent status and future perspectives of 2D MXene for micro-supercapacitors and micro-batteries","volume":"51","author":"Zhu","year":"2022","journal-title":"Energy Storage Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"10475","DOI":"10.1002\/er.7934","article-title":"Last developments in polymers for wearable energy storage devices","volume":"46","author":"Abad","year":"2022","journal-title":"Int. J. Energy Res."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1700515","DOI":"10.1002\/adma.201700515","article-title":"Three-Dimensional binder-free nanoarchitectures for advanced pseudocapacitors","volume":"48","author":"Kang","year":"2017","journal-title":"Adv. Mater."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"269","DOI":"10.1039\/C8TA09810G","article-title":"Electrospun MXene\/carbon nanofibers as supercapacitor electrodes","volume":"7","author":"Levitt","year":"2019","journal-title":"J. Mater. Chem. A"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1601301","DOI":"10.1002\/aenm.201601301","article-title":"Electrospun nanomaterials for supercapacitor electrodes: Designed architectures and electrochemical performance","volume":"7","author":"Lu","year":"2017","journal-title":"Adv. Energy Mater."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"214466","DOI":"10.1016\/j.ccr.2022.214466","article-title":"Review of recent progress in electrospinning-derived freestanding and binder-free electrodes for supercapacitors","volume":"460","author":"Joshi","year":"2022","journal-title":"Coordin. Chem. Rev."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1007\/s12274-018-2219-1","article-title":"All VN-graphene architecture derived self-powered wearable sensors for ultrasensitive health monitoring","volume":"12","author":"Yu","year":"2019","journal-title":"Nano Res."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.jelechem.2014.12.027","article-title":"Nitrogen-doped hollow activated carbon nanofibers as high performance supercapacitor electrodes","volume":"739","author":"Xu","year":"2015","journal-title":"J. Electroanal. Chem."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"44624","DOI":"10.1021\/acsami.9b16458","article-title":"Electrospun core-shell nanofibrous membranes with nanocellulose-stabilized carbon nanotubes for use as high-performance flexible supercapacitor electrodes with enhanced water resistance, thermal stability, and mechanical toughness","volume":"11","author":"Han","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2003656","DOI":"10.1002\/advs.202003656","article-title":"Flexible free-standing MoO3\/Ti3C2Tx MXene composite films with high gravimetric and volumetric capacities","volume":"8","author":"Zheng","year":"2021","journal-title":"Adv. Sci."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1186\/s40580-022-00300-2","article-title":"Boosting capacitive performance of manganese oxide nanorods by decorating with three-dimensional crushed graphene","volume":"9","author":"Reaz","year":"2022","journal-title":"Nano Converg."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"131212","DOI":"10.1016\/j.matlet.2021.131212","article-title":"Electrospun V2O5 nanofibers as high-capacity cathode materials for zinc-ion batteries","volume":"308","author":"Volkov","year":"2022","journal-title":"Mater. Lett."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"109678","DOI":"10.1016\/j.matdes.2021.109678","article-title":"Production and investigation of flexible nanofibers of sPEEK\/PVP loaded with RuO2 nanoparticles","volume":"204","author":"Chamakh","year":"2021","journal-title":"Mater. Design"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"139058","DOI":"10.1016\/j.electacta.2021.139058","article-title":"MOF-derived hierarchical carbon network as an extremely-high-perfomance supercapacitor electrode","volume":"394","author":"Pokharel","year":"2021","journal-title":"Electrochim. Acta"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"39154","DOI":"10.1021\/acsami.0c10235","article-title":"Laser synthesis of MOF-derived Ni@Carbon for high-performance pseudocapacitors","volume":"12","author":"Lam","year":"2020","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1009","DOI":"10.1039\/D1CC04880E","article-title":"Ultrathin nanosheet-assembled nickel-based metal-organic framework microflowers for supercapacitor applications","volume":"7","author":"Wang","year":"2022","journal-title":"Chem. Conmmun."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"123454","DOI":"10.1016\/j.cej.2019.123454","article-title":"MOF-deroved Mo-doped CoP@C grown on CNTs for high-performance supercapacitors","volume":"385","author":"Gu","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Yang, J., Zhong, W., Yu, Q., Zou, J., Gao, Y.S., Liu, S.W., Zhang, S.H., Wang, X.Q., and Lu, L.M. (2022). MXene-AuNP-based electrochemical aptasensor for ultra-sensitive detection of chloramphenicol in honey. Molecules, 27.","DOI":"10.3390\/molecules27061871"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"nwac024","DOI":"10.1093\/nsr\/nwac024","article-title":"Kinetic regulation of MXene with water-in-LiCl electrolyte for high-voltage micro-supercapacitors","volume":"9","author":"Zhu","year":"2022","journal-title":"Natl. Sci. Rev."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Zhu, Y.Y., Zheng, S.H., Qin, J.Q., Ma, J.X., Das, P., Zhou, F., and Wu, Z. (Fundam. Res., 2022). 2.4 V ultrahigh-voltage aqueous MXene-based asymmetric micro-supercapacitors with high volumetric energy density toward a self-sufficient integrated microsystem, Fundam. Res., in press.","DOI":"10.1016\/j.fmre.2022.03.021"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"100803","DOI":"10.1016\/j.nantod.2019.100803","article-title":"Porous MXene: Synthesis, structures, and application","volume":"30","author":"Bu","year":"2020","journal-title":"Nano Today"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1007\/s40820-020-00483-5","article-title":"3D printing of NiCoP\/Ti3C2 MXene architectures for energy devices synergizing high areal and volumetric energy density","volume":"12","author":"Yu","year":"2020","journal-title":"Nano-Micro Lett."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1904293","DOI":"10.1002\/smll.201904293","article-title":"Flexible 3D porous MXene foam for high-performance lithium-ion batteries","volume":"20","author":"Zhao","year":"2019","journal-title":"Small"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1901839","DOI":"10.1002\/aenm.201901839","article-title":"Versatile N-doped MXene ink for printed electrochemical energy storage application","volume":"9","author":"Yu","year":"2019","journal-title":"Adv. Energy Mater."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"1800750","DOI":"10.1002\/advs.201800750","article-title":"Modified MXene\/Holey graphene films for advanced supercapacitor electrodes with superior energy storage","volume":"5","author":"Fan","year":"2018","journal-title":"Adv. Sci."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"104555","DOI":"10.1016\/j.nanoen.2020.104555","article-title":"Rational design of porous nitrogen-doped Ti3C2 MXene as a multifunctional electrocatalyst for Li-S chemistry","volume":"70","author":"Song","year":"2020","journal-title":"Nano Energy"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"336","DOI":"10.1016\/j.nanoen.2018.07.052","article-title":"Two-dimensional mesoporous vanadium phosphate nanoshhets through liquid crystal templating method toward supercapacitor appliacation","volume":"52","author":"Mei","year":"2018","journal-title":"Nano Energy"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"110081","DOI":"10.1016\/j.jpcs.2021.110081","article-title":"Hierarchical PANI-RGO-ZnO ternary nanocomposites for symmetric tandem supercapacitor","volume":"154","author":"Nemade","year":"2021","journal-title":"J. Phys. Chem. Solids"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"675","DOI":"10.1007\/s10008-020-04495-4","article-title":"Controlled nanosheet morphology of titanium carbide Ti3C2Tx MXene via drying methods and its electrochemical analysis","volume":"24","author":"Pan","year":"2020","journal-title":"J. Solid State Electr."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"228472","DOI":"10.1016\/j.jpowsour.2020.228472","article-title":"Non-peripheral octamethyl-substituted copper (II) phthalocyanine nanorods with MXene sheets: An excellent electrode material for symmetric supercapacitor with enhanced electrochemical performance","volume":"47","author":"Ramachandran","year":"2020","journal-title":"J. Power Sources"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"44777","DOI":"10.1021\/acsami.0c13059","article-title":"MXene\/N-Doped carbon foam with three-dimensional hollow neuron-like architecture for freestanding, highly compressible all solid-state supercapacitors","volume":"12","author":"Sun","year":"2020","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"091101","DOI":"10.1063\/5.0015426","article-title":"Self-assembled three-dimensional macroscopic graphene\/MXene-based hydrogel as electrode for supercapacitor","volume":"8","author":"Zhang","year":"2020","journal-title":"APL Mater."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"127150","DOI":"10.1016\/j.surfcoat.2021.127150","article-title":"Electrochemically exfoliated graphene sheets as electrode material for aqueous symmetric supercapacitors","volume":"416","author":"Edison","year":"2021","journal-title":"Surf. Coat. Technol."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/15\/4890\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T00:00:06Z","timestamp":1760140806000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/27\/15\/4890"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,7,30]]},"references-count":40,"journal-issue":{"issue":"15","published-online":{"date-parts":[[2022,8]]}},"alternative-id":["molecules27154890"],"URL":"https:\/\/doi.org\/10.3390\/molecules27154890","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,7,30]]}}}