{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T20:25:21Z","timestamp":1769113521969,"version":"3.49.0"},"reference-count":71,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2022,8,24]],"date-time":"2022-08-24T00:00:00Z","timestamp":1661299200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>This research presents results on the production of biodiesel from the transesterification of acylglycerides present in palm oil, using the biocatalysts ZIF-8-PCL and Gly@ZIF-8-PCL synthesized by immobilization of Pseudomonas Cepacia Lipase as catalytic materials and using pure ZIF-8 and Gly@ZIF-8 (modified ZIF-8) as supports. The Gly@ZIF-8 carbonaceous material was prepared by wet impregnation of ZIF-8 with ethylene glycol as the carbon source, and then thermally modified. The calcination conditions were 900 \u00b0C for two hours with a heating rate of 7 \u00b0C\/min in an inert atmosphere. A textural characterization was performed, and results showed superficial changes of materials at the microporous and mesoporous levels for the Gly@ZIF-8 material. Both the starting materials and biocatalysts were characterized by infrared spectroscopy (FTIR) and Raman spectroscopy. During the transesterification, using the two biocatalysts (ZIF-8-PCL and Gly@ZIF-8-PCL), two supernatant liquids were generated which were characterized by infrared spectroscopy (FTIR), gas chromatography coupled to mass spectrometry (GC-MS), and nuclear magnetic resonance (NMR). The results show that the two routes of synthesis of supports from ZIF-8 will be configured as effective methods for the generation of effective biocatalysts for biodiesel production.<\/jats:p>","DOI":"10.3390\/molecules27175396","type":"journal-article","created":{"date-parts":[[2022,8,24]],"date-time":"2022-08-24T23:48:58Z","timestamp":1661384938000},"page":"5396","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Biocatalysts Synthesized with Lipase from Pseudomonas cepacia on Glycol-Modified ZIF-8: Characterization and Utilization in the Synthesis of Green Biodiesel"],"prefix":"10.3390","volume":"27","author":[{"given":"Jos\u00e9 Manuel","family":"Mart\u00ednez Gil","sequence":"first","affiliation":[{"name":"Grupo de Investigaci\u00f3n Cat\u00e1lisis y Materiales, Facultad de Ciencias B\u00e1sicas y Aplicadas, Universidad de La Guajira, Rioacha 44001, Colombia"},{"name":"Grupo de Investigaci\u00f3n Qu\u00edmica Cu\u00e1ntica y Te\u00f3rica, Facultad de Ciencias Exactas y Naturales, Universidad de Cartagena, Cartagena de Indias 130005, Colombia"},{"name":"Grupo de Investigaci\u00f3n Desarrollo de Estudios y Tecnolog\u00edas Ambientales del Carbono (DESTACAR), Facultad de Ingenier\u00edas, Universidad de La Guajira, Rioacha 44001, Colombia"},{"name":"Departamento de Qu\u00edmica, Grupo de Investigaci\u00f3n en S\u00f3lidos Porosos y Calorimetr\u00eda, Facultad de Cienicas, Universidad de los Andes, Bogot\u00e1 111711, Colombia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7462-1948","authenticated-orcid":false,"given":"Ricardo","family":"Vivas Reyes","sequence":"additional","affiliation":[{"name":"Grupo de Investigaci\u00f3n Qu\u00edmica Cu\u00e1ntica y Te\u00f3rica, Facultad de Ciencias Exactas y Naturales, Universidad de Cartagena, Cartagena de Indias 130005, Colombia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marlon Jos\u00e9","family":"Bastidas Barranco","sequence":"additional","affiliation":[{"name":"Grupo de Investigaci\u00f3n Desarrollo de Estudios y Tecnolog\u00edas Ambientales del Carbono (DESTACAR), Facultad de Ingenier\u00edas, Universidad de La Guajira, Rioacha 44001, Colombia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liliana","family":"Giraldo","sequence":"additional","affiliation":[{"name":"Grupo de Calorimetr\u00eda, Departamento de Qu\u00edmica, Facultad de Ciencias, Universidad Nacional de Colombia, Sede Bogot\u00e1, Carrera 30 No. 45-03, Bogot\u00e1 111321, Colombia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9880-4696","authenticated-orcid":false,"given":"Juan Carlos","family":"Moreno-Piraj\u00e1n","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Grupo de Investigaci\u00f3n en S\u00f3lidos Porosos y Calorimetr\u00eda, Facultad de Cienicas, Universidad de los Andes, Bogot\u00e1 111711, Colombia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,24]]},"reference":[{"key":"ref_1","first-page":"57","article-title":"Intensifi-cation of agricultural systems and its relationship with productivity and efficiency. 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