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These compounds serve as important active units in biologically active compounds. Herein, carbohydrate anchored OZTs were explored to develop a copper-catalyzed C-S bond formation with aryl iodides. Chemoselective S-arylation was observed, with copper iodide and dimethylethylenediamine (DMEDA) as the best ligand in dioxane at 60\u201390 \u00b0C. The corresponding chiral oxazolines were obtained in reasonable to good yields under relatively mild reaction conditions. This approach is cheap, as using one of the cheapest transition metals, a simple protocol and various functional group tolerance make it a valuable strategy for getting S-substituted furanose-fused OZT. The structures of the novel carbohydrates were confirmed by NMR spectroscopy and an HRMS analysis.<\/jats:p>","DOI":"10.3390\/molecules27175597","type":"journal-article","created":{"date-parts":[[2022,8,31]],"date-time":"2022-08-31T00:13:56Z","timestamp":1661904836000},"page":"5597","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Copper-catalyzed S-arylation of Furanose-Fused Oxazolidine-2-thiones"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7184-6615","authenticated-orcid":false,"given":"Vilija","family":"Kederien\u0117","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry, Kaunas University of Technology, Radvil\u0117n\u0173 pl. 19, LT-50254 Kaunas, Lithuania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5215-9588","authenticated-orcid":false,"given":"Jolanta","family":"Rousseau","sequence":"additional","affiliation":[{"name":"Univ. Artois, CNRS, Centrale Lille, Univ. Lille, UMR 8181\u2013UCCS\u2013Unit\u00e9 de Catalyse et Chimie du Solide, Faculty of Science Jean Perrin, Rue Jean Souvraz SP 18, F-62300 Lens, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1273-0257","authenticated-orcid":false,"given":"Marie","family":"Schuler","sequence":"additional","affiliation":[{"name":"Institute de Chimie Organique et Analitique (ICOA), Universit\u00e9 d\u2019Orl\u00e9ans, UMR-CNRS 7311, BP 6759, F-45067 Orl\u00e9ans, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Algirdas","family":"\u0160a\u010dkus","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry, Kaunas University of Technology, Radvil\u0117n\u0173 pl. 19, LT-50254 Kaunas, Lithuania"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arnaud","family":"Tatibou\u00ebt","sequence":"additional","affiliation":[{"name":"Institute de Chimie Organique et Analitique (ICOA), Universit\u00e9 d\u2019Orl\u00e9ans, UMR-CNRS 7311, BP 6759, F-45067 Orl\u00e9ans, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1846","DOI":"10.1016\/j.bmc.2011.10.089","article-title":"Syntheses of 1,2-annulated and 1-spiroannulated carbohydrate derivatives: Recent developments","volume":"20","author":"Awan","year":"2012","journal-title":"Bioorg. 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