{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T04:53:28Z","timestamp":1788584008679,"version":"build-2803163510"},"reference-count":69,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2022,9,15]],"date-time":"2022-09-15T00:00:00Z","timestamp":1663200000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Special Project of 2022 Social Development and Transformation of Scientific and Technological Achievements","award":["61703152"],"award-info":[{"award-number":["61703152"]}]},{"name":"Special Project of 2022 Social Development and Transformation of Scientific and Technological Achievements","award":["2018JJ34"],"award-info":[{"award-number":["2018JJ34"]}]},{"name":"Special Project of 2022 Social Development and Transformation of Scientific and Technological Achievements","award":["2021JJ50035"],"award-info":[{"award-number":["2021JJ50035"]}]},{"name":"Doctoral Program Construction of Hunan University of Technology, Postgraduates Innovation Fund of HUT","award":["61703152"],"award-info":[{"award-number":["61703152"]}]},{"name":"Doctoral Program Construction of Hunan University of Technology, Postgraduates Innovation Fund of HUT","award":["2018JJ34"],"award-info":[{"award-number":["2018JJ34"]}]},{"name":"Doctoral Program Construction of Hunan University of Technology, Postgraduates Innovation Fund of HUT","award":["2021JJ50035"],"award-info":[{"award-number":["2021JJ50035"]}]},{"name":"Hunan Provincial Natural Science Foundation","award":["61703152"],"award-info":[{"award-number":["61703152"]}]},{"name":"Hunan Provincial Natural Science Foundation","award":["2018JJ34"],"award-info":[{"award-number":["2018JJ34"]}]},{"name":"Hunan Provincial Natural Science Foundation","award":["2021JJ50035"],"award-info":[{"award-number":["2021JJ50035"]}]},{"name":"Project of Science and Technology Department of Hunan Province","award":["61703152"],"award-info":[{"award-number":["61703152"]}]},{"name":"Project of Science and Technology Department of Hunan Province","award":["2018JJ34"],"award-info":[{"award-number":["2018JJ34"]}]},{"name":"Project of Science and Technology Department of Hunan Province","award":["2021JJ50035"],"award-info":[{"award-number":["2021JJ50035"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Adefovir (ADV) is an anti-retroviral drug, which can be used to treat acquired immune deficiency syndrome (AIDS) and chronic hepatitis B (CHB), so its quantitative analysis is of great significance. In this work, zirconium molybdate (ZrMo2O8) was synthesized by a wet chemical method, and a composite with multi-walled carbon nanotubes (MWCNTs) was made. ZrMo2O8-MWCNTs composite was dropped onto the surface of a glassy carbon electrode (GCE) to prepare ZrMo2O8-MWCNTs\/GCE, and ZrMo2O8-MWCNTs\/GCE was used in the electrochemical detection of ADV for the first time. The preparation method is fast and simple. The materials were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and cyclic voltammetry (CV). It was electrochemically analysed by differential pulse voltammetry (DPV). Compared with single-material modified electrodes, ZrMo2O8-MWCNTs\/GCE showed a vastly improved electrochemical response to ADV. Moreover, the sensor complements the study of the electrochemical detection of ADV. Under optimal conditions, the proposed electrochemical method showed a wide linear range (from 1 to 100 \u03bcM) and a low detection limit (0.253 \u03bcM). It was successfully tested in serum and urine. In addition, the sensor has the advantages of a simple preparation, fast response, good reproducibility and repeatability. It may be helpful in the potential applications of other substances with similar structures.<\/jats:p>","DOI":"10.3390\/molecules27186022","type":"journal-article","created":{"date-parts":[[2022,9,16]],"date-time":"2022-09-16T01:35:10Z","timestamp":1663292110000},"page":"6022","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Zirconium Molybdate Nanocomposites\u2019 Sensing Platform for the Sensitive and Selective Electrochemical Detection of Adefovir"],"prefix":"10.3390","volume":"27","author":[{"given":"Wenming","family":"Li","sequence":"first","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyun","family":"Xiao","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"},{"name":"School of Life Science and Chemistry, Hunan University of Technology, Zhuzhou 412007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangyuan","family":"Yao","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanping","family":"Wei","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"},{"name":"School of Life Science and Chemistry, Hunan University of Technology, Zhuzhou 412007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinsong","family":"Zuo","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"},{"name":"School of Life Science and Chemistry, Hunan University of Technology, Zhuzhou 412007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weili","family":"Zeng","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhua","family":"Ding","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9849-7953","authenticated-orcid":false,"given":"Quanguo","family":"He","sequence":"additional","affiliation":[{"name":"Cardiology Department, Zhuzhou People\u2019s Hospital, Zhuzhou 421007, China"},{"name":"School of Life Science and Chemistry, Hunan University of Technology, Zhuzhou 412007, China"},{"name":"Hunan Qianjin Xiangjiang Pharmaceutical Joint Stock Co., Ltd., Zhuzhou 412001, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,9,15]]},"reference":[{"key":"ref_1","first-page":"10","article-title":"Nonsteroidal anti-inflammatory drugs efficiently reduce the transport and cytotoxicity of Adefovir mediated by the human renal organic anion transporter 1","volume":"295","author":"Mulato","year":"2000","journal-title":"J. Pharmacol. Exp. Ther."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1177\/135965350701200309","article-title":"In vitro susceptibility of Adefovir-associated hepatitis B virus polymerase mutations to other antiviral agents","volume":"12","author":"Qi","year":"2007","journal-title":"Antivir. Ther."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"353","DOI":"10.1177\/135965350400900311","article-title":"In vitro susceptibility of Lamivudine-resistant hepatitis B virus to Adefovir and Tenofovir","volume":"9","author":"Lada","year":"2004","journal-title":"Antivir. Ther."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1002\/hep.22658","article-title":"Early hepatitis B virus DNA reduction in hepatitis B e antigen-positive patients with chronic hepatitis B: A randomized international study of Entecavir versus Adefovir","volume":"49","author":"Leung","year":"2009","journal-title":"Hepatology"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"178","DOI":"10.3103\/S0891416810040075","article-title":"Detection of hepatitis B virus polymerase gene variants associated with Lamivudine, Adefovir and Entecavir resistance and some undefined mutations isolated from chronic hepatitis B patients in the south of Turkey","volume":"25","author":"Mehmet","year":"2010","journal-title":"Mol. Genet. Microbiol. Virol."},{"key":"ref_6","first-page":"821","article-title":"Transport of Adefovir (PMEA) in human T-Lymphoblastoid 9-(2-Phosphonomethoxyethyl) adenine (PMEA; Adefovir) represents the simplest structural type of Acyclic nucleoside phosphonates, an important group of novel antiviral agents","volume":"62","author":"Lsanska","year":"1997","journal-title":"Compound"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1177\/095632029700800101","article-title":"HPMPC (Cidofovir), PMEA (Adefovir) and related acyclic nucleoside phosphonate analogues. A review of their pharmacology and clinical potential in the treatment of viral infections","volume":"8","author":"Naesens","year":"1997","journal-title":"Antivir. Chem. Chemother."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1016\/j.jchromb.2006.10.063","article-title":"Simultaneous quantitation of the nucleotide analog Adefovir, its phosphorylated anabolites and 2\u2032-deoxyadenosine triphosphate by ion-pairing LC\/MS\/MS","volume":"848","author":"Vela","year":"2007","journal-title":"J. Chromatogr. B Anal. Technol. Biomed. Life Sci."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"127","DOI":"10.2165\/00003088-199936020-00004","article-title":"Clinical pharmacokinetics of the antiviral nucleotide analogues Cidofovir and Adefovir","volume":"36","author":"Cundy","year":"1999","journal-title":"Clin. Pharmacokinet."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1681\/ASN.V113383","article-title":"Cytotoxicity of antiviral nucleotides Adefovir and Cidofovir is induced by the expression of human renal organic anion transporter 1","volume":"11","author":"Ho","year":"2000","journal-title":"J. Am. Soc. Nephrol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1016\/j.jpha.2014.08.002","article-title":"Liquid chromatography-tandem mass spectrometry method for the estimation of Adefovir in human plasma: Application to a pharmacokinetic study","volume":"5","author":"Goswami","year":"2015","journal-title":"J. Pharm. Anal."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"372","DOI":"10.1016\/j.jpba.2006.04.019","article-title":"Development and validation of a sensitive LC-MS\/MS method for the determination of Adefovir in human serum and urine","volume":"42","author":"Sun","year":"2006","journal-title":"J. Pharm. Biomed. Anal."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"507","DOI":"10.1093\/chromsci\/bmv172","article-title":"Development and validation of a sensitive LC-MS-MS method for the determination of Adefovir in human serum and urine: Application to a clinical pharmacokinetic study","volume":"54","author":"Zhang","year":"2016","journal-title":"J. Chromatogr. Sci."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"3143","DOI":"10.14233\/ajchem.2015.15412","article-title":"Field-amplified on-line sample stacking for separation and determination of Adefovir and Tenofovir using capillary electrophoresis","volume":"27","author":"Liu","year":"2015","journal-title":"Asian J. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1016\/j.jchromb.2007.03.012","article-title":"HPLC method for determination of in vitro delivery through and into porcine skin of Adefovir (PMEA)","volume":"853","year":"2007","journal-title":"J. Chromatogr. B Anal. Technol. Biomed. Life Sci."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1016\/S0378-4347(99)00447-8","article-title":"Improved and simplified liquid chromatographic assay for Adefovir, a novel antiviral drug, in human plasma using derivatization with chloroacetaldehyde","volume":"736","author":"Sparidans","year":"1999","journal-title":"J. Chromatogr. B Biomed. Sci. Appl."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Ding, Z., Deng, P., Wu, Y., Tian, Y., Li, G., Liu, J., and He, Q. (2019). A novel modified electrode for detection of the food colorant sunset yellow based on nanohybrid of MnO2 nanorods-decorated electrochemically reduced graphene oxide. Molecules, 24.","DOI":"10.3390\/molecules24061178"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"B805","DOI":"10.1149\/2.1271910jes","article-title":"Rapid and sensitive voltammetric detection of Rhodamine B in chili-containing foodstuffs using MnO2 nanorods\/electro-reduced graphene oxide composite","volume":"166","author":"He","year":"2019","journal-title":"J. Electrochem. Soc."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"104885","DOI":"10.1016\/j.microc.2020.104885","article-title":"High sensitive voltammetric sensor for nanomolarity vanillin detection in food samples via manganese dioxide nanowires hybridized electrode","volume":"157","author":"Tian","year":"2020","journal-title":"Microchem. J."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1186\/s12951-020-00672-9","article-title":"Simultaneous and sensitive determination of ascorbic acid, dopamine and uric acid via an electrochemical sensor based on PVP-graphene composite","volume":"18","author":"Wu","year":"2020","journal-title":"J. Nanobiotechnol."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Zhou, S., Deng, Z., Wu, Z., Xie, M., Tian, Y., Wu, Y., Liu, J., Li, G., and He, Q. (2019). Ta2O5\/rGO nanocomposite modified electrodes for detection of tryptophan through electrochemical route. Nanomaterials, 9.","DOI":"10.3390\/nano9060811"},{"key":"ref_22","doi-asserted-by":"crossref","unstructured":"Ning, J., He, Q., Luo, X., Wang, M., Liu, D., Wang, J., Liu, J., and Li, G. (2018). Rapid and sensitive determination of vanillin based on a glassy carbon electrode modified with Cu2O-electrochemically reduced graphene oxide nanocomposite film. Sensors, 18.","DOI":"10.3390\/s18092762"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"e00064","DOI":"10.1016\/j.teac.2019.e00064","article-title":"Graphene and graphene like 2D graphitic carbon nitride: Electrochemical detection of food colorants and toxic substances in environment","volume":"23","author":"Magesa","year":"2019","journal-title":"Trends Environ. Anal. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Tian, Y., Deng, P., Wu, Y., Ding, Z., Li, G., Liu, J., and He, Q. (2019). A simple and efficient molecularly imprinted electrochemical sensor for the selective determination of tryptophan. Biomolecules, 9.","DOI":"10.3390\/biom9070294"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"He, Q., Liu, J., Feng, J., Wu, Y., Tian, Y., Li, G., and Chen, D. (2020). Sensitive voltammetric sensor for tryptophan detection by using polyvinylpyrrolidone functionalized graphene\/GCE. Nanomaterials, 10.","DOI":"10.3390\/nano10010125"},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"He, Q., Liu, J., Liu, X., Li, G., Deng, P., Liang, J., and Chen, D. (2018). Sensitive and selective detection of tartrazine based on TiO2-electrochemically reduced graphene oxide composite-modified electrodes. Sensors, 18.","DOI":"10.3390\/s18061911"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"126","DOI":"10.1016\/j.jpba.2016.05.006","article-title":"From mercury to nanosensors: Past, present and the future perspective of electrochemistry in pharmaceutical and biomedical analysis","volume":"130","author":"Ozkan","year":"2016","journal-title":"J. Pharm. Biomed. Anal."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.jpha.2011.10.002","article-title":"Voltammetric quantification of anti-hepatitis drug Adefovir in biological matrix and pharmaceutical formulation","volume":"2","author":"Jain","year":"2012","journal-title":"J. Pharm. Anal."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"128657","DOI":"10.1016\/j.snb.2020.128657","article-title":"A new approach on sensitive assay of Adefovir in pharmaceutical and biological fluid samples using polypyrrole modified glassy carbon electrode","volume":"323","author":"Zaabal","year":"2020","journal-title":"Sens. Actuators B Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"149104","DOI":"10.1016\/j.apsusc.2021.149104","article-title":"DFT exploration of sensor performances of two-dimensional WO3 to ten small gases in terms of work function and band gap changes and I-V responses","volume":"546","author":"Li","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"ref_31","doi-asserted-by":"crossref","unstructured":"Chen, R., Luo, S., Xie, D., Yu, Y., and Xiang, L. (2022). Highly dispersive palladium loading on ZnO by galvanic replacements with improved methane sensing performance. Chemosensors, 10.","DOI":"10.3390\/chemosensors10080329"},{"key":"ref_32","doi-asserted-by":"crossref","unstructured":"Wang, M., Chen, K., Liu, J., He, Q., Li, G., and Li, F. (2018). Efficiently enhancing electrocatalytic activity of \u03b1-MnO2 nanorods\/N-doped ketjenblack carbon for oxygen reduction reaction and oxygen evolution reaction using facile regulated hydrothermal treatment. Catalysts, 8.","DOI":"10.3390\/catal8040138"},{"key":"ref_33","doi-asserted-by":"crossref","unstructured":"Chen, K., Wang, M., Li, G., He, Q., Liu, J., and Li, F. (2018). Spherical \u03b1-MnO2 supported on N-KB as efficient electrocatalyst for oxygen reduction in Al-air battery. Materials, 11.","DOI":"10.3390\/ma11040601"},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"He, Q., Liu, J., Liu, X., Xia, Y., Li, G., Deng, P., and Chen, D. (2018). Novel electrochemical sensors based on cuprous oxide-electrochemically reduced graphene oxide nanocomposites modified electrode toward sensitive detection of sunset yellow. Molecules, 23.","DOI":"10.3390\/molecules23092130"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"103280","DOI":"10.1016\/j.jfca.2019.103280","article-title":"Construction of effective electrochemical sensor for the determination of quinoline yellow based on different morphologies of manganese dioxide functionalized graphene","volume":"84","author":"Wu","year":"2019","journal-title":"J. Food Compos. Anal."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"111050","DOI":"10.1016\/j.materresbull.2020.111050","article-title":"Ultrasensitive detection of dopamine via electrochemical route on spindle-like \u03b1-Fe2O3 Mesocrystals\/rGO modified GCE","volume":"133","author":"Liu","year":"2021","journal-title":"Mater. Res. Bull."},{"key":"ref_37","doi-asserted-by":"crossref","unstructured":"Li, G., Wu, J., Jin, H., Xia, Y., Liu, J., He, Q., and Chen, D. (2020). Titania\/electro-reduced graphene oxide nanohybrid as an efficient electrochemical sensor for the determination of allura red. Nanomaterials, 10.","DOI":"10.3390\/nano10020307"},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Liu, J., Dong, S., He, Q., Yang, S., Xie, M., Deng, P., Xia, Y., and Li, G. (2019). Facile preparation of Fe3O4\/C nanocomposite and its application for cost-effective and sensitive detection of tryptophan. Biomolecules, 9.","DOI":"10.3390\/biom9060245"},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"He, Q., Tian, Y., Wu, Y., Liu, J., Li, G., Deng, P., and Chen, D. (2019). Electrochemical sensor for rapid and sensitive detection of tryptophan by a Cu2O nanoparticles- coated reduced graphene oxide nanocomposite. Biomolecules, 9.","DOI":"10.3390\/biom9050176"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"104718","DOI":"10.1016\/j.ultsonch.2019.104718","article-title":"Sonochemical synthesis and fabrication of honeycomb like zirconium dioxide with chitosan modified electrode for sensitive electrochemical determination of anti-tuberculosis (TB) drug","volume":"59","author":"Chen","year":"2019","journal-title":"Ultrason. Sonochem."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1002\/ejic.201801314","article-title":"Role of nanostructuring on the properties of oxide materials: The case of zirconia nanoparticles","volume":"2019","author":"Pacchioni","year":"2019","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"2107","DOI":"10.1021\/jp901897s","article-title":"Synthesis, characterization, and photocatalytic properties of ZrMo2O8","volume":"113","author":"Sahoo","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1007\/s12034-009-0048-2","article-title":"Synthesis, structure and photocatalytic properties of \u03b2-ZrMo2O8","volume":"32","author":"Sahoo","year":"2009","journal-title":"Bull. Mater. Sci."},{"key":"ref_44","first-page":"1506","article-title":"Conventional synthesis and characterization of zirconium molybdate, Nd2Zr3(MoO4)9","volume":"10","year":"2016","journal-title":"Int. J. Metall. Mater. Eng."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"126165","DOI":"10.1016\/j.surfcoat.2020.126165","article-title":"Molybdate intercalated hydrotalcite\/graphene oxide composite as corrosion inhibitor for carbon steel","volume":"399","author":"Nguyen","year":"2020","journal-title":"Surf. Coat. Technol."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"118119","DOI":"10.1016\/j.fuel.2020.118119","article-title":"Bioelectricity generation using iron (II) molybdate nanocatalyst coated anode during treatment of sugar wastewater in microbial fuel cell","volume":"277","author":"Mohamed","year":"2020","journal-title":"Fuel"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"136885","DOI":"10.1016\/j.electacta.2020.136885","article-title":"Rare earth erbium molybdate nanoflakes decorated functionalized carbon nanofibers: An affordable and potential catalytic platform for the electrooxidation of phenothiazine","volume":"358","author":"Liu","year":"2020","journal-title":"Electrochim. Acta."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"121982","DOI":"10.1016\/j.matchemphys.2019.121982","article-title":"Highly porous nickel molybdate@graphene oxide nanocomposite for the ultrasensitive electrochemical detection of environmental toxic pollutant catechol","volume":"239","author":"Boopathy","year":"2020","journal-title":"Mater. Chem. Phys."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"6547","DOI":"10.1021\/acsami.6b14242","article-title":"A study of electrocatalytic and photocatalytic activity of cerium molybdate nanocubes decorated graphene oxide for the sensing and degradation of antibiotic drug chloramphenicol","volume":"9","author":"Karthik","year":"2017","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"942","DOI":"10.1016\/j.cherd.2012.09.007","article-title":"Adsorption and diffusion of cesium ions in zirconium(IV) iodomolybdate exchanger","volume":"91","author":"Sheha","year":"2013","journal-title":"Chem. Eng. Res. Des."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/S1381-5148(98)00091-1","article-title":"Studies on a new heteropolyacid-based inorganic ion exchanger; Zirconium(IV) selenomolybdate","volume":"43","author":"Gupta","year":"2000","journal-title":"React. Funct. Polym."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"487","DOI":"10.1021\/cm000788k","article-title":"New high-pressure form of the negative thermal expansion materials zirconium molybdate and hafnium molybdate","volume":"13","author":"Lind","year":"2001","journal-title":"Chem. Mater."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1107\/S0108768100013215","article-title":"High-pressure structures of a- and \u03b4-ZrMo2O8","volume":"57","author":"Carlson","year":"2001","journal-title":"Acta Crystallogr. Sect. B."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"2335","DOI":"10.1021\/cm980438m","article-title":"Synthesis and properties of the negative thermal expansion material cubic ZrMo2O8","volume":"10","author":"Lind","year":"1998","journal-title":"Chem. Mater."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1016\/j.jcis.2017.03.113","article-title":"Evaluation of a new electrochemical sensor for selective detection of non-enzymatic hydrogen peroxide based on hierarchical nanostructures of zirconium molybdate","volume":"500","author":"Kumar","year":"2017","journal-title":"J. Colloid Interface Sci."},{"key":"ref_56","first-page":"460","article-title":"Influence of heat treatment on the phase transition of ZrMo2O8 and photocatalytic activity","volume":"9","author":"Mancheva","year":"2011","journal-title":"Cent. Eur. J. Chem."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"104","DOI":"10.1016\/j.jallcom.2009.06.064","article-title":"Synthesis of ZrMo2O8 polymorphs by a melt quenching method and mechanochemical activation","volume":"485","author":"Iordanova","year":"2009","journal-title":"J. Alloys Compd."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"3354","DOI":"10.1039\/b104283c","article-title":"Preparation of the negative thermal expansion material cubic ZrMo2O8","volume":"11","author":"Lind","year":"2001","journal-title":"J. Mater. Chem."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1023\/A:1016041010949","article-title":"Seeding and the non-hydrolytic sol-gel synthesis of ZrW2O8 and ZrMo2O8","volume":"25","author":"Lind","year":"2002","journal-title":"J. Sol-Gel Sci. Technol."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1007\/BF01038380","article-title":"Catalytic behaviour of a Cu(II) complex sorbed on zirconium molybdate in the decomposition of hydrogen peroxide","volume":"15","author":"Shivanekar","year":"1990","journal-title":"Transit. Met. Chem."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"8321","DOI":"10.20964\/2020.08.42","article-title":"An efficient electrochemical sensor based on zirconium molybdate decorated reduced graphene oxide for the detection of Hydroquinone","volume":"15","author":"Nataraj","year":"2020","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"37046","DOI":"10.1007\/s11356-019-06864-7","article-title":"Enhanced selective removal of arsenic(V) using a hybrid nanoscale zirconium molybdate embedded anion exchange resin","volume":"26","author":"Bui","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.watres.2018.01.061","article-title":"Development of nanoscale zirconium molybdate embedded anion exchange resin for selective removal of phosphate","volume":"134","author":"Bui","year":"2018","journal-title":"Water Res."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"26938","DOI":"10.1038\/srep26938","article-title":"Electrocatalytic oxidation of Epinephrine and Norepinephrine at metal oxide doped phthalocyanine\/MWCNT composite sensor","volume":"6","author":"Mphuthi","year":"2016","journal-title":"Sci. Rep."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"419","DOI":"10.1016\/j.apmt.2017.09.001","article-title":"Applications of conducting polymer composites to electrochemical sensors: A review","volume":"9","author":"Naveen","year":"2017","journal-title":"Appl. Mater. Today"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1016\/j.diamond.2010.06.003","article-title":"Diameter dependence of interwall separation and strain in multiwalled carbon nanotubes probed by X-ray diffraction and Raman scattering studies","volume":"19","author":"Singh","year":"2010","journal-title":"Diam. Relat. Mater."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"103708","DOI":"10.1016\/j.jfca.2020.103708","article-title":"New voltammetric method for determination of tyrosine in foodstuffs using an oxygen-functionalized multi-walled carbon nanotubes modified acetylene black paste electrode","volume":"96","author":"Feng","year":"2020","journal-title":"J. Food Compos. Anal."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"106106","DOI":"10.1016\/j.microc.2021.106106","article-title":"Highly sensitive electrochemical sensor for tyrosine detection using a sub-millimeter electrode","volume":"165","author":"Deng","year":"2021","journal-title":"Microchem. J."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"128601","DOI":"10.1016\/j.colsurfa.2022.128601","article-title":"Ultrasensitive electrochemical detection for nanomolarity Acyclovir at ferrous molybdate nanorods and graphene oxide composited glassy carbon electrode","volume":"641","author":"Wei","year":"2022","journal-title":"Colloids Surf. A Physicochem. Eng. 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