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However, conventional porous materials possess nonpolar building units, which reveal relatively weak affinity for polar organic molecules. Here, two different polarities of superhydrophobic porous aromatic frameworks (PAFs) were synthesized with respective orthoposition and paraposition C=O groups in the PAF linkers. The conjugated structure formed by a large number of alkynyl and benzene ring structures enabled porous and superhydrophobic quality of PAFs. After the successful preparation of the PAF solids, PAF powders were coated on polyester fabrics by a simple dip-coating method, which endowed the resulting polyester fabrics with superhydrophobicity, porosity, and excellent stability. Based on the unique structure, the oil\/water separation efficiency of two superhydrophobic flexible fabrics was more than 90% for various organic solvents. Polar LNU-26 PAF showed better separation performance for the polar oils. This work takes the lead in adopting the polar groups as building units for the preparation of porous networks, which has great guiding significance for the construction of advanced oil\/water separation materials.<\/jats:p>","DOI":"10.3390\/molecules27186113","type":"journal-article","created":{"date-parts":[[2022,9,20]],"date-time":"2022-09-20T04:28:55Z","timestamp":1663648135000},"page":"6113","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Introducing Polar Groups in Porous Aromatic Framework for Achieving High Capacity of Organic Molecules and Enhanced Self-Cleaning Applications"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0521-3059","authenticated-orcid":false,"given":"Zhuojun","family":"Yan","sequence":"first","affiliation":[{"name":"College of Chemistry, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yimin","family":"Qiao","sequence":"additional","affiliation":[{"name":"College of Chemistry, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qiqi","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Environmental Science, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo","family":"Cui","sequence":"additional","affiliation":[{"name":"College of Chemistry, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bin","family":"Feng","sequence":"additional","affiliation":[{"name":"College of Chemistry, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3987-2661","authenticated-orcid":false,"given":"Naishun","family":"Bu","sequence":"additional","affiliation":[{"name":"School of Environmental Science, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9519-3233","authenticated-orcid":false,"given":"Kuo","family":"Chu","sequence":"additional","affiliation":[{"name":"School of Environmental Science, Liaoning University, Shenyang 110036, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xianghui","family":"Ruan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Northeast Normal University, Changchun 130024, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ye","family":"Yuan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Northeast Normal University, Changchun 130024, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yajie","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Northeast Normal University, Changchun 130024, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lixin","family":"Xia","sequence":"additional","affiliation":[{"name":"College of Chemistry, Liaoning University, Shenyang 110036, China"},{"name":"Yingkou Institute of Technology, Yingkou 115014, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,9,19]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"18094","DOI":"10.1021\/ja208408n","article-title":"Fluorous metal-organic frameworks with superior adsorption and hydrophobic properties toward oil spill cleanup and hydrocarbon storage","volume":"133","author":"Yang","year":"2011","journal-title":"J. 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