{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,21]],"date-time":"2026-05-21T00:49:43Z","timestamp":1779324583432,"version":"3.51.4"},"reference-count":102,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2022,10,5]],"date-time":"2022-10-05T00:00:00Z","timestamp":1664928000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004281","name":"National Science Center (Poland)","doi-asserted-by":"publisher","award":["2019\/33\/B\/ST4\/02843"],"award-info":[{"award-number":["2019\/33\/B\/ST4\/02843"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>This comprehensive review, covering the years 1968\u20132022, is not only a retrospective investigation of a certain group of linearly fused aromatics, called acenes, but also a presentation of the current state of the knowledge on the synthesis, reactions, and applications of these compounds. Their characteristic feature is substitution of the aromatic system by one, two, or three organophosphorus groups, which determine their properties and applications. The (PIII, PIV, PV) phosphorus atom in organophosphorus groups is linked to the acene directly by a P-Csp2 bond or indirectly through an oxygen atom by a P-O-Csp2 bond.<\/jats:p>","DOI":"10.3390\/molecules27196611","type":"journal-article","created":{"date-parts":[[2022,10,9]],"date-time":"2022-10-09T23:31:43Z","timestamp":1665358303000},"page":"6611","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Comprehensive Review on Synthesis, Properties, and Applications of Phosphorus (PIII, PIV, PV) Substituted Acenes with More Than Two Fused Benzene Rings"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0122-1326","authenticated-orcid":false,"given":"Marek","family":"Koprowski","sequence":"first","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9053-3315","authenticated-orcid":false,"given":"Krzysztof","family":"Owsianik","sequence":"additional","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7351-6997","authenticated-orcid":false,"given":"\u0141ucja","family":"Knopik","sequence":"additional","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1058-8744","authenticated-orcid":false,"given":"Vivek","family":"Vivek","sequence":"additional","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7361-1748","authenticated-orcid":false,"given":"Adrian","family":"Romaniuk","sequence":"additional","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ewa","family":"R\u00f3\u017cycka-Soko\u0142owska","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Faculty of Science and Technology, Jan D\u0142ugosz University in Cz\u0119stochowa, Armii Krajowej 13\/15, 42-200 Cz\u0119stochowa, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5981-551X","authenticated-orcid":false,"given":"Piotr","family":"Ba\u0142czewski","sequence":"additional","affiliation":[{"name":"Division of Organic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 \u0141\u00f3d\u017a, Poland"},{"name":"Institute of Chemistry, Faculty of Science and Technology, Jan D\u0142ugosz University in Cz\u0119stochowa, Armii Krajowej 13\/15, 42-200 Cz\u0119stochowa, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,10,5]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"21453","DOI":"10.1039\/c3ra43017k","article-title":"White Light Emission from an Exciplex Based on a Phosphine Oxide Type Electron Transport Compound in a Bilayer Device Structure","volume":"3","author":"Zhao","year":"2013","journal-title":"RSC Adv."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"7188","DOI":"10.1039\/C4TC00876F","article-title":"High Efficiency Non-Dopant Blue Organic Light-Emitting Diodes Based on Anthracene-Based Fluorophores with Molecular Design of Charge Transport and Red-Shifted Emission Proof","volume":"2","author":"Wu","year":"2014","journal-title":"J. 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