{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T09:16:52Z","timestamp":1762075012308,"version":"build-2065373602"},"reference-count":49,"publisher":"MDPI AG","issue":"22","license":[{"start":{"date-parts":[[2022,11,12]],"date-time":"2022-11-12T00:00:00Z","timestamp":1668211200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004488","name":"Croatian Science Foundation","doi-asserted-by":"publisher","award":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"],"award-info":[{"award-number":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"]}],"id":[{"id":"10.13039\/501100004488","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"],"award-info":[{"award-number":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"name":"University of Zagreb University Computing Center","award":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"],"award-info":[{"award-number":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"]}]},{"name":"Slovenian Research Agency","award":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"],"award-info":[{"award-number":["IP-2018-01-1982","KK.01.1.1.04.0001","P1-0134","L7-1848"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Sustainable hydrogen production is one of the main challenges today in the transition to a green and sustainable economy. Photocatalytic hydrogen production is one of the most promising technologies, amongst which BiVO4-based processes are highly attractive due to their suitable band gap for solar-driven processes. However, the performance of BiVO4 alone in this role is often unsatisfactory. Herein we report the improvement of BiVO4 performance with reduced graphene oxide (rGO) as a co-catalyst for the photoelectrochemical water splitting (PEC-WS) in the presence of simple functionalized benzene derivatives (SFBDs), i.e., phenol (PH), benzoic acid (BA), salicylic acid (SA), and 5-aminosalicylic acid (5-ASA) as potential photogenerated hole scavengers from contaminated wastewaters. Linear sweep voltammetry and chronoamperometry, along with electrochemical impedance spectroscopy were utilized to elucidate PEC-WS performance under illumination. rGO has remarkably improved the performance of BiVO4 in this role by decreasing photogenerated charge recombination. In addition, 5-ASA greatly improved current densities. After 120 min under LED illumination, 0.53 \u03bcmol of H2 was produced. The type and concentration of SFBDs can have significant and at times opposite effects on the PEC-WS performance of both BiVO4 and rGO-BiVO4.<\/jats:p>","DOI":"10.3390\/molecules27227806","type":"journal-article","created":{"date-parts":[[2022,11,14]],"date-time":"2022-11-14T04:24:10Z","timestamp":1668399850000},"page":"7806","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Effect of Functionalized Benzene Derivatives as Potential Hole Scavengers for BiVO4 and rGO-BiVO4 Photoelectrocatalytic Hydrogen Evolution"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4694-5814","authenticated-orcid":false,"given":"Tayebeh","family":"Sharifi","sequence":"first","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4105-1141","authenticated-orcid":false,"given":"Marin","family":"Kova\u010di\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Monika","family":"Belec","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Klara","family":"Perovi\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marin","family":"Popovi\u0107","sequence":"additional","affiliation":[{"name":"Department of Safety and Protection, Karlovac University of Applied Sciences, Trg Josipa Juraja Strossmayera 9, HR-47000 Karlovac, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gabrijela","family":"Radi\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo\u0161tjan","family":"\u017dener","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, SI-1000 Ljubljana, Slovenia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5735-3745","authenticated-orcid":false,"given":"Anamarija","family":"Pulitika","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marijana","family":"Kralji\u0107 Rokovi\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9652-2257","authenticated-orcid":false,"given":"Ur\u0161ka","family":"Lavren\u010di\u010d \u0160tangar","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve\u010dna pot 113, SI-1000 Ljubljana, Slovenia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ana","family":"Lon\u010dari\u0107 Bo\u017ei\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hrvoje","family":"Ku\u0161i\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemical Engineering and Technology, University of Zagreb, Maruli\u0107ev trg 19, HR-10000 Zagreb, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1801505","DOI":"10.1002\/advs.201801505","article-title":"Rational Design and Construction of Cocatalysts for Semiconductor-Based Photo-Electrochemical Oxygen Evolution: A Comprehensive Review","volume":"6","author":"Xu","year":"2019","journal-title":"Adv. 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