{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,16]],"date-time":"2026-06-16T02:11:43Z","timestamp":1781575903527,"version":"3.54.5"},"reference-count":55,"publisher":"MDPI AG","issue":"22","license":[{"start":{"date-parts":[[2022,11,14]],"date-time":"2022-11-14T00:00:00Z","timestamp":1668384000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["121031700321-3"],"award-info":[{"award-number":["121031700321-3"]}]},{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["202008090088"],"award-info":[{"award-number":["202008090088"]}]},{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","award":["121031700321-3"],"award-info":[{"award-number":["121031700321-3"]}],"id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","award":["202008090088"],"award-info":[{"award-number":["202008090088"]}],"id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A reaction between 4,4\u2032,4\u2033-(benzene-1,3,5-triyltris(oxy))triphthalic acid (H6L) and lanthanide(III) nitrates (Ln = Eu3+, Tb3+) in water under the same conditions gave a molecular coordination compound [Tb(H4.5L)2(H2O)5]\u22196H2O in the case of terbium(III) and a one-dimensional linear coordination polymer {[Eu2(H3L)2(H2O)6]\u22198H2O}n in the case of europium(III). The crystal structures of both compounds were established by single-crystal X-ray diffraction, and they were further characterized by powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. The compounds demonstrated characteristic lanthanide-centered photoluminescence. The lanthanide-dependent dimensionality of the synthesized compounds, which are the first examples of the coordination compounds of hexacarboxylic acid H6L demonstrates its potential as a linker for new coordination polymers.<\/jats:p>","DOI":"10.3390\/molecules27227849","type":"journal-article","created":{"date-parts":[[2022,11,15]],"date-time":"2022-11-15T02:32:16Z","timestamp":1668479536000},"page":"7849","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand"],"prefix":"10.3390","volume":"27","author":[{"given":"Xiaolin","family":"Yu","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, 2 Pirogov Str., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5996-8062","authenticated-orcid":false,"given":"Dmitry I.","family":"Pavlov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexey A.","family":"Ryadun","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2360-7473","authenticated-orcid":false,"given":"Andrei S.","family":"Potapov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8922-0066","authenticated-orcid":false,"given":"Vladimir P.","family":"Fedin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090 Novosibirsk, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, 2 Pirogov Str., 630090 Novosibirsk, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1070\/RCR4554","article-title":"Metal-organic frameworks: Structure, properties, synthesis and characterization","volume":"85","author":"Butova","year":"2016","journal-title":"Russ. 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