{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T17:11:21Z","timestamp":1791911481008,"version":"4.3.4"},"reference-count":132,"publisher":"MDPI AG","issue":"22","license":[{"start":{"date-parts":[[2022,11,15]],"date-time":"2022-11-15T00:00:00Z","timestamp":1668470400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002674","name":"Russian Academy of Sciences","doi-asserted-by":"publisher","award":["AAAA-A19-119011290117-6"],"award-info":[{"award-number":["AAAA-A19-119011290117-6"]}],"id":[{"id":"10.13039\/501100002674","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated \u03b2-diketonates. Heterometallic systems are of high interest in terms of their potential use in catalysis, medicine and diagnostics, as well as in the development of effective sensor devices and functional materials. Having a rich history in coordination chemistry, fluorinated \u03b2-diketones are well-known ligands generating a wide variety of heterometallic complexes. In this context, we focused on both the synthetic approaches to \u03b2-dicarbonyl ligands with additional coordination centers and their possible transformations in complexation reactions. The review describes bi- and polynuclear structures in which \u03b2-diketones are the key building blocks in the formation of a heterometallic framework, including the examples of both homo- and heteroleptic complexes.<\/jats:p>","DOI":"10.3390\/molecules27227894","type":"journal-article","created":{"date-parts":[[2022,11,16]],"date-time":"2022-11-16T02:36:36Z","timestamp":1668566196000},"page":"7894","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["Heterometallic Molecular Architectures Based on Fluorinated \u03b2-Diketone Ligands"],"prefix":"10.3390","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1976-7861","authenticated-orcid":false,"given":"Viktor I.","family":"Saloutin","sequence":"first","affiliation":[{"name":"Postovsky Institute of Organic Synthesis, The Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620108, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8955-6272","authenticated-orcid":false,"given":"Yulia O.","family":"Edilova","sequence":"additional","affiliation":[{"name":"Postovsky Institute of Organic Synthesis, The Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620108, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0637-1606","authenticated-orcid":false,"given":"Yulia S.","family":"Kudyakova","sequence":"additional","affiliation":[{"name":"Postovsky Institute of Organic Synthesis, The Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620108, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanina V.","family":"Burgart","sequence":"additional","affiliation":[{"name":"Postovsky Institute of Organic Synthesis, The Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620108, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3972-6995","authenticated-orcid":false,"given":"Denis N.","family":"Bazhin","sequence":"additional","affiliation":[{"name":"Postovsky Institute of Organic Synthesis, The Ural Branch of the Russian Academy of Sciences, Ekaterinburg 620108, Russia"},{"name":"Department of Organic and Biomolecular Chemistry, Ural Federal University Named after the First President of Russia B.N. Yeltsin, Ekaterinburg 620002, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"213067","DOI":"10.1016\/j.ccr.2019.213067","article-title":"Multifunctional, heterometallic ruthenium-platinum complexes with medicinal applications","volume":"401","author":"Jain","year":"2019","journal-title":"Coord. Chem. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"214521","DOI":"10.1016\/j.ccr.2022.214521","article-title":"Recent advances of functional heterometallic-organic framework (HMOF) materials: Design strategies and applications","volume":"463","author":"Liu","year":"2022","journal-title":"Coord. Chem. 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