{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,18]],"date-time":"2026-01-18T04:24:19Z","timestamp":1768710259744,"version":"3.49.0"},"reference-count":41,"publisher":"MDPI AG","issue":"22","license":[{"start":{"date-parts":[[2022,11,17]],"date-time":"2022-11-17T00:00:00Z","timestamp":1668643200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21774029"],"award-info":[{"award-number":["21774029"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22108065"],"award-info":[{"award-number":["22108065"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T201816"],"award-info":[{"award-number":["T201816"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["202023404"],"award-info":[{"award-number":["202023404"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Hubei University Excellent Young and Middle-aged Science and Technology Innovation Team Project","award":["21774029"],"award-info":[{"award-number":["21774029"]}]},{"name":"Hubei University Excellent Young and Middle-aged Science and Technology Innovation Team Project","award":["22108065"],"award-info":[{"award-number":["22108065"]}]},{"name":"Hubei University Excellent Young and Middle-aged Science and Technology Innovation Team Project","award":["T201816"],"award-info":[{"award-number":["T201816"]}]},{"name":"Hubei University Excellent Young and Middle-aged Science and Technology Innovation Team Project","award":["202023404"],"award-info":[{"award-number":["202023404"]}]},{"name":"Opening Fund of Hubei Key Laboratory of Processing and Application of Catalytic materials, and Huanggang Normal University","award":["21774029"],"award-info":[{"award-number":["21774029"]}]},{"name":"Opening Fund of Hubei Key Laboratory of Processing and Application of Catalytic materials, and Huanggang Normal University","award":["22108065"],"award-info":[{"award-number":["22108065"]}]},{"name":"Opening Fund of Hubei Key Laboratory of Processing and Application of Catalytic materials, and Huanggang Normal University","award":["T201816"],"award-info":[{"award-number":["T201816"]}]},{"name":"Opening Fund of Hubei Key Laboratory of Processing and Application of Catalytic materials, and Huanggang Normal University","award":["202023404"],"award-info":[{"award-number":["202023404"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Here, we describe the preparation of copper nanoparticles that are stabilized on a chitosan composite film (CP@Cu). This material could catalyze the 1,6-hydroboration reactions of p-quinone methides with B2pin2 as a boron source under mild conditions. This reaction exhibited very good functional group compatibility, and the organoboron compounds that were formed could easily be converted into corresponding hydroxyl products with good to excellent yields. This newly developed methodology provides an efficient and sequential pathway for the synthesis of gem-disubstituted methanols.<\/jats:p>","DOI":"10.3390\/molecules27227962","type":"journal-article","created":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T06:11:34Z","timestamp":1668751894000},"page":"7962","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of p-Quinone Methides"],"prefix":"10.3390","volume":"27","author":[{"given":"Shuhan","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Wen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xue","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zelang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weishuang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yaoyao","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bojie","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lei","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China"},{"name":"School of Materials Science and Engineering, Hubei University, Wuhan 430062, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Coghi, P.S., Zhu, Y., Xie, H., Hosmane, N.S., and Zhang, Y. 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