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Control and Rehabilitation Technology","award":["ZYYCYU202012183"],"award-info":[{"award-number":["ZYYCYU202012183"]}]},{"name":"Opening Project of Henan Province Key Laboratory of Water Pollution Control and Rehabilitation Technology","award":["23B610004"],"award-info":[{"award-number":["23B610004"]}]},{"name":"Opening Project of Henan Province Key Laboratory of Water Pollution Control and Rehabilitation Technology","award":["202003027"],"award-info":[{"award-number":["202003027"]}]},{"name":"Opening Project of Henan Province Key Laboratory of Water Pollution Control and Rehabilitation Technology","award":["CJSP2021007"],"award-info":[{"award-number":["CJSP2021007"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The extensive use of sulfonamides seriously threatens the safety and stability of the ecological environment. Developing green inexpensive and effective adsorbents is critically needed for the elimination of sulfonamides from wastewater. The non-modified biochar exhibited limited adsorption capacity for sulfonamides. In this study, the attapulgite-doped biochar adsorbent (ATP\/BC) was produced from attapulgite and rice straw by calcination. Compared with non-modified biochar, the specific surface area of ATP\/BC increased by 73.53\u2013131.26%, and the average pore width of ATP\/BC decreased 1.77\u20133.60 nm. The removal rates of sulfadiazine and sulfamethazine by ATP\/BC were 98.63% and 98.24%, respectively, at the mass ratio of ATP to rice straw = 1:10, time = 4 h, dosage = 2 g\u2219L\u22121, pH = 5, initial concentration = 1 mg\u2219L\u22121, and temperature = 20 \u00b0C. A pseudo-second-order kinetic model (R2 = 0.99) and the Freundlich isothermal model (R2 = 0.99) well described the process of sulfonamide adsorption on ATP\/BC. Thermodynamic calculations showed that the adsorption behavior of sulfonamides on the ATP\/BC was an endothermic (\u0394H &gt; 0), random (\u0394S &gt; 0), spontaneous reaction (\u0394G &lt; 0) that was dominated by chemisorption (\u221220 kJ\u2219mol\u22121 &gt; \u0394G). The potential adsorption mechanisms include electrostatic interaction, hydrogen bonding, \u03c0\u2013\u03c0 interaction, and Lewis acid\u2013base interactions. This study provides an optional material to treat sulfonamides in wastewater and groundwater.<\/jats:p>","DOI":"10.3390\/molecules27228076","type":"journal-article","created":{"date-parts":[[2022,11,21]],"date-time":"2022-11-21T04:33:32Z","timestamp":1669005212000},"page":"8076","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Enhanced Adsorption of Sulfonamides by Attapulgite-Doped Biochar Prepared with Calcination"],"prefix":"10.3390","volume":"27","author":[{"given":"Jianqiao","family":"Hu","sequence":"first","affiliation":[{"name":"College of Water Conservancy and Civil Engineering, Zhengzhou University, Zhengzhou 450066, China"},{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100086, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Liu","sequence":"additional","affiliation":[{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100086, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongping","family":"Shan","sequence":"additional","affiliation":[{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100086, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenzhen","family":"Huang","sequence":"additional","affiliation":[{"name":"College of Ecology and Environment, Zhengzhou University, Zhengzhou 450066, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingqing","family":"Gao","sequence":"additional","affiliation":[{"name":"College of Ecology and Environment, Zhengzhou University, Zhengzhou 450066, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wentao","family":"Jiao","sequence":"additional","affiliation":[{"name":"Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100086, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"157418","DOI":"10.1016\/j.scitotenv.2022.157418","article-title":"Non-antibiotics matter: Evidence from a one-year investigation of livestock wastewater from six farms in East China","volume":"846","author":"Wu","year":"2022","journal-title":"Sci. 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