{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:54:13Z","timestamp":1760244853637,"version":"build-2065373602"},"reference-count":29,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2022,11,25]],"date-time":"2022-11-25T00:00:00Z","timestamp":1669334400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Science Foundation of China","award":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"],"award-info":[{"award-number":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"]}]},{"DOI":"10.13039\/501100005230","name":"Natural Science Foundation of Chongqing","doi-asserted-by":"publisher","award":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"],"award-info":[{"award-number":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"]}],"id":[{"id":"10.13039\/501100005230","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006250","name":"Southwest University","doi-asserted-by":"publisher","award":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"],"award-info":[{"award-number":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"]}],"id":[{"id":"10.13039\/501100006250","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Science and Technology Research Program of Chongqing Municipal Education Commission","award":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"],"award-info":[{"award-number":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"]}]},{"name":"Southwest University","award":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"],"award-info":[{"award-number":["22271237","21772231","cstc2020jcyj-msxm2042","SWU-XDZD22007","KJQN202200222, KJZD-K202200201","SWU118129","SWU120046"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In the presence of CuOAc, a series of unsymmetric ureas can be generated in moderate to good yields under mild reaction conditions (10 mol% of CuOAc, 2 equiv t-BuONa or PhONa, 30 \u00b0C), using aryl isocyanides and O-benzoyl hydroxylamines as the readily accessible starting materials. The reactions might undergo a cascade process involving isocyanide insertion into the N-O bond and Mumm-type rearrangement. This work represents a rare example of isocyanide insertion into N-O bonds, which would extend isocyanide insertion chemistry.<\/jats:p>","DOI":"10.3390\/molecules27238219","type":"journal-article","created":{"date-parts":[[2022,11,28]],"date-time":"2022-11-28T06:04:36Z","timestamp":1669615476000},"page":"8219","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Urea Synthesis from Isocyanides and O-Benzoyl Hydroxylamines Catalyzed by a Copper Salt"],"prefix":"10.3390","volume":"27","author":[{"given":"Ning","family":"Yu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing-Fang","family":"Lv","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shi-Mei","family":"He","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanyan","family":"Cui","sequence":"additional","affiliation":[{"name":"Department of Cell Biology and Genetics, Chongqing Medical University, Chongqing 400016, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ye","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kun","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"4828","DOI":"10.1021\/jf070525b","article-title":"Fate of Diuron and terbuthylazine in soils amended with two-phase olive oil mill waste","volume":"55","author":"Cabrera","year":"2007","journal-title":"J. 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