{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T02:19:34Z","timestamp":1785464374637,"version":"3.56.0"},"reference-count":63,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2022,12,13]],"date-time":"2022-12-13T00:00:00Z","timestamp":1670889600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The present work describes the preparation and characterization of a new cobalt(III) porphyrin coordination compound named (chlorido)(nicotinoylchloride)[meso-tetra(para-chlorophenyl)porphyrinato]cobalt(III) dichloromethane monosolvate with the formula [CoIII(TClPP)Cl(NTC)]\u00b7CH2Cl2 (4). The single-crystal X-ray molecular structure of 4 shows very important ruffling and waving distortions of the porphyrin macrocycle. The Soret and Q absorption bands of 4 are very red-shifted as a consequence of the very distorted porphyrin core. This coordination compound was also studied by fluorescence and cyclic voltammetry. The efficiency of our four porphyrinic compounds\u2014the H2TClPP (1) free-base porphyrin, the [CoII(TClPP)] (2) and [CoIII(TClPP)Cl] (3) starting materials, and the new Co(III) metalloporphyrin [CoIII(TClPP)Cl(NTC)]\u00b7CH2Cl2 (4)\u2014as catalysts in the photochemical degradation was tested on malachite green (MG) dye. The current voltage of complexes 3 and 4 was also studied. Electrical parameters, including the saturation current density (Js) and barrier height (\u03d5b), were measured.<\/jats:p>","DOI":"10.3390\/molecules27248866","type":"journal-article","created":{"date-parts":[[2022,12,14]],"date-time":"2022-12-14T03:21:52Z","timestamp":1670988112000},"page":"8866","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Synthesis of New Cobalt(III) Meso-Porphyrin Complex, Photochemical, X-ray Diffraction, and Electrical Properties for Photovoltaic Cells"],"prefix":"10.3390","volume":"27","author":[{"given":"Soumaya","family":"Nasri","sequence":"first","affiliation":[{"name":"Department of Chemistry, College of Science Al-Zulfi, Majmaah University, Majmaah 11952, Saudi Arabia"},{"name":"Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir, Avenue de L\u2019environnement, Monastir 5019, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mouhieddinne","family":"Guergueb","sequence":"additional","affiliation":[{"name":"Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir, Avenue de L\u2019environnement, Monastir 5019, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihed","family":"Brahmi","sequence":"additional","affiliation":[{"name":"Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir, Avenue de L\u2019environnement, Monastir 5019, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youssef O.","family":"Al-Ghamdi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science Al-Zulfi, Majmaah University, Majmaah 11952, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6675-5551","authenticated-orcid":false,"given":"Florian","family":"Molton","sequence":"additional","affiliation":[{"name":"D\u00e9partement de Chimie Mol\u00e9culaire, 301 rue de la Chimie, Universit\u00e9 Grenoble Alpes, CS 40700, CEDEX 9, 38058 Grenoble, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fr\u00e9d\u00e9rique","family":"Loiseau","sequence":"additional","affiliation":[{"name":"D\u00e9partement de Chimie Mol\u00e9culaire, 301 rue de la Chimie, Universit\u00e9 Grenoble Alpes, CS 40700, CEDEX 9, 38058 Grenoble, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8534-1944","authenticated-orcid":false,"given":"Ilona","family":"Turowska-Tyrk","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, Wroc\u0142aw University of Science and Technology, 27 Wybrze\u017ce Wyspia\u0144skiego, 50-370 Wroc\u0142aw, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Habib","family":"Nasri","sequence":"additional","affiliation":[{"name":"Laboratory of Physical Chemistry of Materials, Faculty of Sciences of Monastir, University of Monastir, Avenue de L\u2019environnement, Monastir 5019, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"4580","DOI":"10.1021\/ja01075a013","article-title":"Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes","volume":"86","author":"Maki","year":"1964","journal-title":"J. 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