{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T07:40:39Z","timestamp":1784706039840,"version":"3.55.0"},"reference-count":42,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2023,2,11]],"date-time":"2023-02-11T00:00:00Z","timestamp":1676073600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Key Research and Development Program of China","award":["2020YFB1713500"],"award-info":[{"award-number":["2020YFB1713500"]}]},{"name":"National Key Research and Development Program of China","award":["2022040"],"award-info":[{"award-number":["2022040"]}]},{"name":"National Key Research and Development Program of China","award":["2022044"],"award-info":[{"award-number":["2022044"]}]},{"name":"Student Research Training Plan of Henan University of Science and Technology","award":["2020YFB1713500"],"award-info":[{"award-number":["2020YFB1713500"]}]},{"name":"Student Research Training Plan of Henan University of Science and Technology","award":["2022040"],"award-info":[{"award-number":["2022040"]}]},{"name":"Student Research Training Plan of Henan University of Science and Technology","award":["2022044"],"award-info":[{"award-number":["2022044"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Aqueous Zn-ion batteries (AZIBs) are one of the most promising large-scale energy storage devices due to the excellent characteristics of zinc metal anode, including high theoretical capacity, high safety and low cost. Nevertheless, the large-scale applications of AZIBs are mainly limited by uncontrollable Zn deposition and notorious Zn dendritic growth, resulting in low plating\/stripping coulombic efficiency and unsatisfactory cyclic stability. To address these issues, herein, a carbon foam (CF) was fabricated via melamine-foam carbonization as a scaffold for a dendrite-free and stable Zn anode. Results showed that the abundant zincophilicity functional groups and conductive three-dimensional network of this carbon foam could effectively regulate Zn deposition and alleviate the Zn anode\u2019s volume expansion during cycling. Consequently, the symmetric cell with CF@Zn electrode exhibited lower voltage hysteresis (32.4 mV) and longer cycling performance (750 h) than the pure Zn symmetric cell at 1 mA cm\u22122 and 1 mAh cm\u22122. Furthermore, the full battery coupling CF@Zn anode with MnO2 cathode can exhibit a higher initial capacity and better cyclic performance than the one with the bare Zn anode. This work brings a new idea for the design of three-dimensional (3D) current collectors for stable zinc metal anode toward high-performance AZIBs.<\/jats:p>","DOI":"10.3390\/molecules28041742","type":"journal-article","created":{"date-parts":[[2023,2,13]],"date-time":"2023-02-13T02:14:11Z","timestamp":1676254451000},"page":"1742","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Melamine Foam-Derived Carbon Scaffold for Dendrite-Free and Stable Zinc Metal Anode"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2137-1404","authenticated-orcid":false,"given":"Yong","family":"Liu","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering, Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China"},{"name":"Science & Technology Innovation Center for Advanced Materials of Intelligent Equipment, Longmen Laboratory, Luoyang 471023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Tao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yibo","family":"Xing","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifei","family":"Pei","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengzhang","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering, Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China"},{"name":"Henan Key Laboratory of Non-Ferrous Materials Science & Processing Technology, School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,2,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3330","DOI":"10.1039\/D0EE02079F","article-title":"Challenges in the material and structural design of zinc anode towards high-performance aqueous zinc-ion batteries","volume":"13","author":"Du","year":"2020","journal-title":"Energy Environ. 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