{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T21:33:21Z","timestamp":1792272801222,"version":"4.4.0"},"reference-count":63,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2023,2,24]],"date-time":"2023-02-24T00:00:00Z","timestamp":1677196800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["075-15-2022-263"],"award-info":[{"award-number":["075-15-2022-263"]}]},{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["121031700321-3"],"award-info":[{"award-number":["121031700321-3"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Five new metal\u2013organic frameworks based on Mn(II) and 2,2\u2032-bithiophen-5,5\u2032-dicarboxylate (btdc2\u2013) with various chelating N-donor ligands (2,2\u2032-bipyridyl = bpy; 5,5\u2032-dimethyl-2,2\u2032-bipyridyl = 5,5\u2032-dmbpy; 4,4\u2032-dimethyl-2,2\u2032-bipyridyl = 4,4\u2032-dmbpy) [Mn3(btdc)3(bpy)2]\u03874DMF, 1; [Mn3(btdc)3(5,5\u2032-dmbpy)2]\u03875DMF, 2; [Mn(btdc)(4,4;-dmbpy)], 3; [Mn2(btdc)2(bpy)(dmf)]\u03870.5DMF, 4; [Mn2(btdc)2(5,5\u2032-dmbpy)(dmf)]\u0387DMF, 5 (dmf, DMF = N,N-dimethylformamide) have been synthesized, and their crystal structure has been established using single-crystal X-ray diffraction analysis (XRD). The chemical and phase purities of Compounds 1\u20133 have been confirmed via powder X-ray diffraction, thermogravimetric, and chemical analyses as well as IR spectroscopy. The influence of the bulkiness of the chelating N-donor ligand on the dimensionality and structure of the coordination polymer has been analyzed, and the decrease in the framework dimensionality, as well as the secondary building unit\u2019s nuclearity and connectivity, has been observed for bulkier ligands. For three-dimensional (3D) coordination polymer 1, the textural and gas adsorption properties have been studied, revealing noticeable ideal adsorbed solution theory (IAST) CO2\/N2 and CO2\/CO selectivity factors (31.0 at 273 K and 19.1 at 298 K and 25.7 at 273 K and 17.0 at 298 K, respectively, for the equimolar composition and the total pressure of 1 bar). Moreover, significant adsorption selectivity for binary C2\u2013C1 hydrocarbons mixtures (33.4 and 24.9 for C2H6\/CH4, 24.8 and 17.7 for C2H4\/CH4, 29.3 and 19.1 for C2H2\/CH4 at 273 K and 298 K, respectively, for the equimolar composition and the total pressure of 1 bar) has been observed, making it possible to separate on 1 natural, shale, and associated petroleum gas into valuable individual components. The ability of Compound 1 to separate benzene and cyclohexane in a vapor phase has also been analyzed based on the adsorption isotherms of individual components measured at 298 K. The preferable adsorption of C6H6 over C6H12 by 1 at high vapor pressures (VB\/VCH = 1.36) can be explained by the existence of multiple van der Waals interactions between guest benzene molecules and the metal\u2013organic host revealed by the XRD analysis of 1 immersed in pure benzene for several days (1\u22452C6H6). Interestingly, at low vapor pressures, an inversed behavior of 1 with preferable adsorption of C6H12 over C6H6 (KCH\/KB = 6.33) was observed; this is a very rare phenomenon. Moreover, magnetic properties (the temperature-dependent molar magnetic susceptibility, \u03c7p(T) and effective magnetic moments, \u03bceff(T), as well as the field-dependent magnetization, M(H)) have been studied for Compounds 1\u20133, revealing paramagnetic behavior consistent with their crystal structure.<\/jats:p>","DOI":"10.3390\/molecules28052139","type":"journal-article","created":{"date-parts":[[2023,2,27]],"date-time":"2023-02-27T02:10:46Z","timestamp":1677463846000},"page":"2139","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["A Series of Metal\u2013Organic Frameworks with 2,2\u2032-Bipyridyl Derivatives: Synthesis vs. Structure Relationships, Adsorption, and Magnetic Studies"],"prefix":"10.3390","volume":"28","author":[{"given":"Vadim A.","family":"Dubskikh","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aleksei A.","family":"Kolosov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"},{"name":"Department of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7817-6370","authenticated-orcid":false,"given":"Anna A.","family":"Lysova","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2688-4521","authenticated-orcid":false,"given":"Denis G.","family":"Samsonenko","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander N.","family":"Lavrov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1337-5106","authenticated-orcid":false,"given":"Konstantin A.","family":"Kovalenko","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8779-0612","authenticated-orcid":false,"given":"Danil N.","family":"Dybtsev","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8922-0066","authenticated-orcid":false,"given":"Vladimir P.","family":"Fedin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,2,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"688","DOI":"10.1021\/cr100160e","article-title":"One-dimensional coordination polymers: Complexity and diversity in structures, properties, and applications","volume":"111","author":"Leong","year":"2011","journal-title":"Chem. 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