{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T21:03:07Z","timestamp":1780606987119,"version":"3.54.1"},"reference-count":60,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2023,4,27]],"date-time":"2023-04-27T00:00:00Z","timestamp":1682553600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"UiO:Energy travel\/internationalisation"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Metal hydrides are an interesting group of chemical compounds, able to store hydrogen in a reversible, compact and safe manner. Among them, A2B7-type intermetallic alloys based on La-Mg-Ni have attracted particular attention due to their high electrochemical hydrogen storage capacity (\u223c400 mAh\/g) and extended cycle life. However, the presence of Mg makes their synthesis via conventional metallurgical routes challenging. Replacing Mg with Y is a viable approach. Herein, we present a systematic study for a series of compounds with a nominal composition of La2-xYxNi6.50Mn0.33Al0.17, x = 0.33, 0.67, 1.00, 1.33, 1.67, focusing on the relationship between the material structural properties and hydrogen sorption performances. The results show that while the hydrogen-induced phase amorphization occurs in the Y-poor samples (x &lt; 1.00) already during the first hydrogen absorption, a higher Y content helps to maintain the material crystallinity during the hydrogenation cycles and increases its H-storage capacity (1.37 wt.% for x = 1.00 vs. 1.60 wt.% for x = 1.67 at 50 \u00b0C). Thermal conductivity experiments on the studied compositions indicate the importance of thermal transfer between powder individual particles and\/or a measuring instrument.<\/jats:p>","DOI":"10.3390\/molecules28093749","type":"journal-article","created":{"date-parts":[[2023,4,27]],"date-time":"2023-04-27T02:18:34Z","timestamp":1682561914000},"page":"3749","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["The Effect of Y Content on Structural and Sorption Properties of A2B7-Type Phase in the La\u2013Y\u2013Ni\u2013Al\u2013Mn System"],"prefix":"10.3390","volume":"28","author":[{"given":"Emil H.","family":"Jensen","sequence":"first","affiliation":[{"name":"Department of Technology Systems, University of Oslo, Gunnar Randers vei 19, 2027 Kjeller, Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2968-6686","authenticated-orcid":false,"given":"Loris","family":"Lombardo","sequence":"additional","affiliation":[{"name":"Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshidahonmachi, Sakyo Ward, Kyoto 606-8317, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2443-2751","authenticated-orcid":false,"given":"Alessandro","family":"Girella","sequence":"additional","affiliation":[{"name":"Department of Chemistry\u2014Physical Chemistry Division, University of Pavia & C.S.G.I., Viale Taramelli 16, I-27100 Pavia, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6349-4659","authenticated-orcid":false,"given":"Matylda N.","family":"Guzik","sequence":"additional","affiliation":[{"name":"Department of Technology Systems, University of Oslo, Gunnar Randers vei 19, 2027 Kjeller, Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5708-1855","authenticated-orcid":false,"given":"Andreas","family":"Z\u00fcttel","sequence":"additional","affiliation":[{"name":"EPFL SB ISIC LMER, EPFL Valais, Rue de I\u2019Industrie 17, CH-1951 Sion, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3763-6657","authenticated-orcid":false,"given":"Chiara","family":"Milanese","sequence":"additional","affiliation":[{"name":"Department of Chemistry\u2014Physical Chemistry Division, University of Pavia & C.S.G.I., Viale Taramelli 16, I-27100 Pavia, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6569-1143","authenticated-orcid":false,"given":"Pamela","family":"Whitfield","sequence":"additional","affiliation":[{"name":"Excelsus Structural Solutions (Swiss) AG, Park InnovAARE, 5234 Villigen, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5257-3909","authenticated-orcid":false,"given":"Dag","family":"Nor\u00e9us","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry, University of Stockholm, Svante Arrhenius V\u00e4g 16C, 106 91 Stockholm, Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9952-6488","authenticated-orcid":false,"given":"Sabrina","family":"Sartori","sequence":"additional","affiliation":[{"name":"Department of Technology Systems, University of Oslo, Gunnar Randers vei 19, 2027 Kjeller, Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,4,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1016\/j.scs.2018.04.008","article-title":"A Critical Review on the Utilization of Storage and Demand Response for the Implementation of Renewable Energy Microgrids","volume":"40","author":"Robert","year":"2018","journal-title":"Sustain. 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