{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T17:10:45Z","timestamp":1789665045380,"version":"4.0.1"},"reference-count":66,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2023,6,2]],"date-time":"2023-06-02T00:00:00Z","timestamp":1685664000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Higher Educational Youth Innovation Science and Technology Program of Shandong Province","award":["2021KJ022"],"award-info":[{"award-number":["2021KJ022"]}]},{"name":"Higher Educational Youth Innovation Science and Technology Program of Shandong Province","award":["tsqn201909107"],"award-info":[{"award-number":["tsqn201909107"]}]},{"name":"Higher Educational Youth Innovation Science and Technology Program of Shandong Province","award":["ZR2020QF077"],"award-info":[{"award-number":["ZR2020QF077"]}]},{"name":"Higher Educational Youth Innovation Science and Technology Program of Shandong Province","award":["62104131"],"award-info":[{"award-number":["62104131"]}]},{"name":"Taishan Scholars Program","award":["2021KJ022"],"award-info":[{"award-number":["2021KJ022"]}]},{"name":"Taishan Scholars Program","award":["tsqn201909107"],"award-info":[{"award-number":["tsqn201909107"]}]},{"name":"Taishan Scholars Program","award":["ZR2020QF077"],"award-info":[{"award-number":["ZR2020QF077"]}]},{"name":"Taishan Scholars Program","award":["62104131"],"award-info":[{"award-number":["62104131"]}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["2021KJ022"],"award-info":[{"award-number":["2021KJ022"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["tsqn201909107"],"award-info":[{"award-number":["tsqn201909107"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2020QF077"],"award-info":[{"award-number":["ZR2020QF077"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["62104131"],"award-info":[{"award-number":["62104131"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["2021KJ022"],"award-info":[{"award-number":["2021KJ022"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["tsqn201909107"],"award-info":[{"award-number":["tsqn201909107"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["ZR2020QF077"],"award-info":[{"award-number":["ZR2020QF077"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62104131"],"award-info":[{"award-number":["62104131"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>ZnIn2S4 (ZIS) is widely used in the field of photocatalytic hydrogen production due to its unique photoelectric properties. Nonetheless, the photocatalytic performance of ZIS usually faces problems of poor conductivity and rapid recombination of charge carriers. Heteroatom doping is often regarded as one of the effective strategies for improving the catalytic activity of photocatalysts. Herein, phosphorus (P)-doped ZIS was prepared by hydrothermal method, whose photocatalytic hydrogen production performance and energy band structure were fully studied. The band gap of P-doped ZIS is about 2.51 eV, which is slightly smaller than that of pure ZIS. Moreover, due to the upward shift of its energy band, the reduction ability of P-doped ZIS is enhanced, and P-doped ZIS also exhibits stronger catalytic activity than pure ZIS. The optimized P-doped ZIS exhibits a hydrogen production rate of 1566.6 \u03bcmol g\u22121 h\u22121, which is 3.8 times that of the pristine ZIS (411.1 \u03bcmol g\u22121 h\u22121). This work provides a broad platform for the design and synthesis of phosphorus-doped sulfide-based photocatalysts for hydrogen evolution.<\/jats:p>","DOI":"10.3390\/molecules28114520","type":"journal-article","created":{"date-parts":[[2023,6,2]],"date-time":"2023-06-02T08:50:31Z","timestamp":1685695831000},"page":"4520","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Facile Synthesis of P-Doped ZnIn2S4 with Enhanced Visible-Light-Driven Photocatalytic Hydrogen Production"],"prefix":"10.3390","volume":"28","author":[{"given":"Xiangrui","family":"Feng","sequence":"first","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongji","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongfei","family":"Yin","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyu","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huijun","family":"Lv","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Fei","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujin","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuyu","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengmeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongzheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,6,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1802106","DOI":"10.1002\/adma.201802106","article-title":"Material design for photocatalytic water splitting from a theoretical perspective","volume":"30","author":"Fu","year":"2018","journal-title":"Adv. Mater."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"919","DOI":"10.1021\/acs.chemrev.9b00201","article-title":"Particulate photocatalysts for light-driven water splitting: Mechanisms, challenges, and design strategies","volume":"120","author":"Wang","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1038\/238037a0","article-title":"Electrochemical photolysis of water at a semiconductor electrode","volume":"238","author":"Fujishima","year":"1972","journal-title":"Nature"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"3561","DOI":"10.1039\/D1CS01182K","article-title":"Recent advances and perspectives for solar-driven water splitting using particulate photocatalysts","volume":"51","author":"Tao","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1043","DOI":"10.1021\/acsenergylett.1c02591","article-title":"Solar-driven hydrogen production: Recent advances, challenges, and future perspectives","volume":"7","author":"Song","year":"2022","journal-title":"ACS Energy Lett."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"58","DOI":"10.1038\/s41467-021-27698-3","article-title":"Single-atom Cu anchored catalysts for photocatalytic renewable H2 production with a quantum efficiency of 56%","volume":"13","author":"Zhang","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_7","first-page":"220029","article-title":"Favorable energy band alignment of TiO2 anatase\/rutile heterophase homojunctions yields photocatalytic hydrogen evolution with quantum efficiency exceeding 45.6%","volume":"12","author":"Ruan","year":"2022","journal-title":"Adv. Energy Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"123496","DOI":"10.1016\/j.cej.2019.123496","article-title":"Perspective and status of polymeric graphitic carbon nitride based Z-scheme photocatalytic systems for sustainable photocatalytic water purification","volume":"391","author":"Kumar","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"998","DOI":"10.1002\/adfm.201401636","article-title":"State-of-the-art progress in diverse heterostructured photocatalysts toward promoting photocatalytic performance","volume":"25","author":"Li","year":"2015","journal-title":"Adv. Funct. Mater."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jmst.2020.09.045","article-title":"A review: Synthesis, modification and photocatalytic applications of ZnIn2S4","volume":"78","author":"Wang","year":"2021","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"109288","DOI":"10.1016\/j.inoche.2022.109288","article-title":"ZnIn2S4 and ZnIn2S4 based advanced hybrid materials: Structure, morphology and applications in environment and energy","volume":"138","author":"Yadav","year":"2022","journal-title":"Inorg. Chem. Commun."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"210245","DOI":"10.1002\/aenm.202102452","article-title":"Sulfur-deficient ZnIn2S4\/oxygen-deficient WO3 hybrids with carbon layer bridges as a novel photothermal\/photocatalytic integrated system for Z-scheme overall water splitting","volume":"11","author":"Wang","year":"2021","journal-title":"Adv. Energy Mater."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1016\/j.gee.2020.12.015","article-title":"A mini-review on ZnIn2S4-based photocatalysts for energy and environmental application","volume":"7","author":"Zhang","year":"2022","journal-title":"Green Energy Environ."},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Cai, Y., Luo, F.X., Guo, Y.J., Guo, F., Shi, W.L., and Yang, S.T. (2023). Near-infrared light driven ZnIn2S4-based photocatalysts for environmental and energy applications: Progress and perspectives. Molecules, 28.","DOI":"10.3390\/molecules28052142"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"214898","DOI":"10.1016\/j.ccr.2022.214898","article-title":"ZnIn2S4-based photocatalysts for photocatalytic hydrogen evolution via water splitting","volume":"475","author":"Zheng","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2200017","DOI":"10.1002\/sstr.202200017","article-title":"ZnIn2S4-based nanostructures in artificial photosynthesis: Insights into photocatalytic reduction toward sustainable energy production","volume":"3","author":"Ren","year":"2022","journal-title":"Small Struct."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"119789","DOI":"10.1016\/j.apcatb.2020.119789","article-title":"Efficient photocatalytic H2 evolution, CO2 reduction and N2 fixation coupled with organic synthesis by cocatalyst and vacancies engineering","volume":"285","author":"Meng","year":"2021","journal-title":"Appl. Catal. B Environ."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1016\/j.jechem.2020.10.032","article-title":"One-step hydrothermal synthesis of S-defect-controlled ZnIn2S4 microflowers with improved kinetics process of charge-carriers for photocatalytic H2 evolution","volume":"58","author":"Jing","year":"2021","journal-title":"J. Energy Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"202209446","DOI":"10.1002\/anie.202209446","article-title":"Low-coordination single Au atoms on ultrathin ZnIn2S4 nanosheets for selective photocatalytic CO2 reduction towards CH4","volume":"61","author":"Si","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"1287","DOI":"10.1038\/s41467-022-28995-1","article-title":"Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution","volume":"13","author":"Shi","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1039\/C9TA11318E","article-title":"Enhanced carrier separation and increased electron density in 2D heavily N-doped ZnIn2S4 for photocatalytic hydrogen production","volume":"8","author":"Du","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"6716","DOI":"10.1002\/anie.201602543","article-title":"Enhanced photoexcited carrier separation in oxygen-doped ZnIn2S4 nanosheets for hydrogen evolution","volume":"55","author":"Yang","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"122500","DOI":"10.1016\/j.jhazmat.2020.122500","article-title":"A novel 2D\/1D core-shell heterostructures coupling MOF-derived iron oxides with ZnIn2S4 for enhanced photocatalytic activity","volume":"392","author":"Liang","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1016\/j.apcatb.2017.09.043","article-title":"Construction of heterostructured ZnIn2S4@NH2-MIL-125(Ti) nanocomposites for visible-light-driven H2 production","volume":"221","author":"Liu","year":"2018","journal-title":"Appl. Catal. B Envrion."},{"key":"ref_25","first-page":"210344","article-title":"In situ irradiated XPS investigation on S-scheme TiO2@ZnIn2S4 photocatalyst for efficient photocatalytic CO2 reduction","volume":"17","author":"Wang","year":"2021","journal-title":"Small"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"5037","DOI":"10.1021\/jacs.8b02200","article-title":"Construction of ZnIn2S4-In2O3 hierarchical tubular heterostructures for efficient CO2 photoreduction","volume":"140","author":"Wang","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"18290","DOI":"10.1039\/C7NR06755K","article-title":"A 2D self-assembled MoS2\/ZnIn2S4 heterostructure for efficient photocatalytic hydrogen evolution","volume":"9","author":"Li","year":"2017","journal-title":"Nanoscale"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/j.pmatsci.2017.09.002","article-title":"Nitrogen-doped simple and complex oxides for photocatalysis: A review","volume":"92","author":"Wang","year":"2018","journal-title":"Prog. Mater. Sci."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1016\/j.cej.2018.08.028","article-title":"Recent advances in synthesis, modification and photocatalytic applications of micro\/nano-structured zinc indium sulfide","volume":"354","author":"Pan","year":"2018","journal-title":"Chem. Eng. J."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"195503","DOI":"10.1103\/PhysRevLett.105.195503","article-title":"Strain-enhanced doping in semiconductors: Effects of dopant size and charge state","volume":"105","author":"Zhu","year":"2010","journal-title":"Phys. Rev. Lett."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"23813","DOI":"10.1021\/acs.jpcc.1c07651","article-title":"Metal-free phosphorus-doped ZnIn2S4 nanosheets for enhanced photocatalytic CO2 reduction","volume":"125","author":"Qin","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"386","DOI":"10.1016\/j.jechem.2020.06.001","article-title":"Construction of hierarchical photocatalysts by growing ZnIn2S4 nanosheets on Prussian blue analogue-derived bimetallic sulfides for solar co-production of H2 and organic chemicals","volume":"54","author":"Zhong","year":"2021","journal-title":"J. Energy Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"4433","DOI":"10.1021\/jp8092513","article-title":"Photocatalytic degradation of dyes by ZnIn2S4 microspheres under visible light irradiation","volume":"113","author":"Chen","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"262","DOI":"10.1016\/j.jcat.2021.08.009","article-title":"Construction of p-n junctions in single-unit-cell ZnIn2S4 nanosheet arrays toward promoted photoelectrochemical performance","volume":"401","author":"Wu","year":"2021","journal-title":"J. Catal."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"8149","DOI":"10.1002\/anie.201501532","article-title":"Extraordinary changes in the electronic structure and properties of CdS and ZnS by anionic substitution: Cosubstitution of P and Cl in place of S","volume":"54","author":"Kouser","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"19701","DOI":"10.1021\/ja307124m","article-title":"InP\/ZnS nanocrystals: Coupling NMR and XPS for fine surface and interface description","volume":"134","author":"Virieux","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"76404","DOI":"10.1007\/s11356-022-21224-8","article-title":"Composite of g-C3N4\/ZnIn2S4 for efficient adsorption and visible light photocatalytic reduction of Cr(VI)","volume":"29","author":"Hu","year":"2022","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"2207031","DOI":"10.1002\/smll.202207031","article-title":"Z-Scheme modulated charge transfer on InVO4@ZnIn2S4 for durable overall water splitting","volume":"19","author":"Zuo","year":"2023","journal-title":"Small"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"122372","DOI":"10.1016\/j.apcatb.2023.122372","article-title":"Non-metal doping induced dual p-n charge properties in a single ZnIn2S4 crystal structure provoking charge transfer behaviors and boosting photocatalytic hydrogen generation","volume":"325","author":"Chong","year":"2023","journal-title":"Appl. Catal. B Environ."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"141926","DOI":"10.1016\/j.scitotenv.2020.141926","article-title":"In situ synthesis of Ag3PO4\/C3N5 Z-scheme heterojunctions with enhanced visible-light-responsive photocatalytic performance for antibiotics removal","volume":"754","author":"Yin","year":"2021","journal-title":"Sci. Total Environ."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"5842","DOI":"10.1016\/j.ceramint.2022.11.256","article-title":"In-situ synthesis of 0D\/1D CeO2\/Zn0.4Cd0.6S S-scheme heterostructures for boosting photocatalytic remove of antibiotic and chromium","volume":"49","author":"Zhang","year":"2023","journal-title":"Ceram. Int."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"2201365","DOI":"10.1002\/smtd.202201365","article-title":"Efficient charge transfer and effective active sites in lead-free halide double perovskite S-scheme heterojunctions for photocatalytic H2 evolution","volume":"7","author":"Lv","year":"2023","journal-title":"Small Methods"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"4951","DOI":"10.1002\/anie.202101234","article-title":"Ultrathin porous carbon nitride bundles with an adjustable energy band structure toward simultaneous solar photocatalytic water splitting and selective phenylcarbinol oxidation","volume":"60","author":"Wu","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"122266","DOI":"10.1016\/j.seppur.2022.122266","article-title":"S-scheme 2D\/2D FeTiO3\/g-C3N4 hybrid architectures as visible-light-driven photo-fenton catalysts for tetracycline hydrochloride degradation","volume":"303","author":"Xu","year":"2022","journal-title":"Sep. Purif. Technol."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"11320","DOI":"10.1016\/j.ceramint.2021.12.355","article-title":"Hierarchical Ti3C2 MXene\/Zn3In2S6 Schottky junction for efficient visible-light-driven Cr(VI) photoreduction","volume":"48","author":"Yin","year":"2022","journal-title":"Ceram. Int."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"120875","DOI":"10.1016\/j.seppur.2022.120875","article-title":"Synergistic effects of interface coupling and defect sites in WO3\/InVO4 architectures for highly efficient nitrogen photofixation","volume":"290","author":"Pei","year":"2022","journal-title":"Sep. Purif. Technol."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"126567","DOI":"10.1016\/j.jhazmat.2021.126567","article-title":"Construction of three-dimensional MgIn2S4 nanoflowers\/two-dimensional oxygen-doped g-C3N4 nanosheets direct Z-scheme heterojunctions for efficient Cr(VI) reduction: Insight into the role of superoxide radicals","volume":"420","author":"Yin","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/j.apsusc.2016.06.101","article-title":"Characterization of TiO2-based semiconductors for photocatalysis by electrochemical impedance spectroscopy","volume":"387","author":"Andrade","year":"2016","journal-title":"Appl. Surf. Sci."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"228741","DOI":"10.1016\/j.jpowsour.2020.228741","article-title":"Rational synthesis of Cu7Se4-CuxCo1-xSe2 double-shell hollow nanospheres for high performance supercapacitors","volume":"480","author":"Yang","year":"2020","journal-title":"J. Power Sources"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"7787","DOI":"10.1039\/C3CS60425J","article-title":"Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting","volume":"43","author":"Ran","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"1900","DOI":"10.1021\/ar300227e","article-title":"Roles of cocatalysts in photocatalysis and photoelectrocatalysis","volume":"46","author":"Yang","year":"2013","journal-title":"ACS Chem. Res."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"13051","DOI":"10.1021\/acs.chemrev.1c00197","article-title":"Cooperative coupling of oxidative organic synthesis and hydrogen production over semiconductor-based photocatalysts","volume":"121","author":"Qi","year":"2021","journal-title":"Chem. Rev."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"10158","DOI":"10.1007\/s12274-022-4593-y","article-title":"Shedding light on the role of interfacial chemical bond in heterojunction photocatalysis","volume":"15","author":"Mao","year":"2022","journal-title":"Nano Res."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/j.jmst.2021.12.028","article-title":"Delaminating Ti3C2 MXene by blossom of ZnIn2S4 microflowers for noble-metal-free photocatalytic hydrogen production","volume":"120","author":"Huang","year":"2022","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2168","DOI":"10.3390\/ma16062168","article-title":"Enhanced photocatalytic hydrogen production of ZnIn2S4 by using surface-engineered Ti3C2Tx MXene as a cocatalyst","volume":"16","author":"Cai","year":"2023","journal-title":"Meterials"},{"key":"ref_56","doi-asserted-by":"crossref","unstructured":"Zhan, J.J., Gu, X.Y., Zhao, Y., Zhang, K., Yan, Y., and Qi, K.Z. (2023). Photocatalytic hydrogen production and tetracycline degradation using ZnIn2S4 quantum dots modified g-C3N4 composites. Nanomaterials, 13.","DOI":"10.3390\/nano13020305"},{"key":"ref_57","first-page":"1447","article-title":"Improved activity and stability of ZnIn2S4 for H2 production under visible light through cerium UiO-66. Sustain","volume":"7","author":"Hou","year":"2023","journal-title":"Energy Fuels"},{"key":"ref_58","doi-asserted-by":"crossref","unstructured":"Ma, Y., Xu, J., Xu, S.M., Liu, Z.L., Liu, X.Y., Li, Z.Z., Shang, Y., and Li, Q. (2023). Construction of 3D\/3D heterojunction between new noble metal free ZnIn2S4 and non-inert metal NiMoO4 for enhanced hydrogen evolution performance under visible light. Int. J. Hydrogen Energy, in press.","DOI":"10.1016\/j.ijhydene.2023.03.286"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"578","DOI":"10.1016\/j.jcis.2023.02.129","article-title":"Photocatalytic hydrogen evolution from glycerol-water mixture under visible light over zinc indium sulfide (ZnIn2S4) nanosheets grown on bismuth oxychloride (BiOCl) microplates","volume":"640","author":"Cavdar","year":"2023","journal-title":"J. Coll. Inter. Sci."},{"key":"ref_60","first-page":"2517","article-title":"Spatial separation of redox centers for boosting cooperative photocatalytic hydrogen evolution with oxidation coupling of benzylamine over Pt@UiO-66-NH2@ZnIn2S4. Cataly","volume":"13","author":"Wang","year":"2023","journal-title":"Sci. Technol."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"3466","DOI":"10.1016\/j.ijhydene.2022.10.192","article-title":"2D NiCo2S4 decorated on ZnIn2S4 formed S-scheme heterojunction for photocatalytic hydrogen production","volume":"48","author":"Li","year":"2023","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"156911","DOI":"10.1016\/j.apsusc.2023.156911","article-title":"Atomically dispersed bismuth on ZnIn2S4 Dual-Functional photocatalyst for photocatalytic hydrogen production coupled with oxidation of aromatic alcohols to aldehydes","volume":"622","author":"He","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"140470","DOI":"10.1016\/j.cplett.2023.140470","article-title":"Highly efficient visible-light photocatalytic hydrogen production using ZIF-derived Co9S8\/N, S-CNTs-ZnIn2S4 composite","volume":"821","author":"Yu","year":"2023","journal-title":"Chem. Phys. Lett."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"2203638","DOI":"10.1002\/adfm.202203638","article-title":"W5+\u2013W5+ pair induced LSPR of W18O49 to sensitize ZnIn2S4 for full-spectrum solar-light-driven photocatalytic hydrogen evolution","volume":"32","author":"Lu","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"5107","DOI":"10.1016\/j.ijhydene.2022.11.047","article-title":"Integration of ReS2 on ZnIn2S4 for boosting the hydrogen evolution coupled with selective oxidation of biomass intermediate under visible light","volume":"48","author":"Cheng","year":"2023","journal-title":"Int. J. Hydrogrn Energy"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"10037","DOI":"10.1021\/acsami.0c21588","article-title":"In situ synthesis of lead-free halide perovskite Cs2AgBiBr6 supported on nitrogen-doped carbon for efficient hydrogen evolution in aqueous HBr solution","volume":"13","author":"Jiang","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/11\/4520\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T19:47:48Z","timestamp":1760125668000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/11\/4520"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,6,2]]},"references-count":66,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2023,6]]}},"alternative-id":["molecules28114520"],"URL":"https:\/\/doi.org\/10.3390\/molecules28114520","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,6,2]]}}}