{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T17:23:16Z","timestamp":1789060996030,"version":"build-2803163510"},"reference-count":49,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2023,6,15]],"date-time":"2023-06-15T00:00:00Z","timestamp":1686787200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Deanship of Scientific Research at King Khalid University, Abha, Saudi Arabia","award":["RGP.1\/280\/43"],"award-info":[{"award-number":["RGP.1\/280\/43"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>A new chlorobenzylidene imine ligand, (E)-1-((5-chloro-2-hydroxybenzylidene)amino) naphthalen-2-ol (HL), and its [Zn(L)(NO3)(H2O)3], [La(L)(NO3)2(H2O)2], [VO(L)(OC2H5)(H2O)2], [Cu(L)(NO3)(H2O)3], and [Cr(L)(NO3)2(H2O)2], complexes were synthesized and characterized. The characterization involved elemental analysis, FT-IR, UV\/Vis, NMR, mass spectra, molar conductance, and magnetic susceptibility measurements. The obtained data confirmed the octahedral geometrical structures of all metal complexes, while the [VO(L)(OC2H5)(H2O)2] complex exhibited a distorted square pyramidal structure. The complexes were found to be thermally stable based on their kinetic parameters determined using the Coats\u2013Redfern method. The DFT\/B3LYP technique was employed to calculate the optimized structures, energy gaps, and other important theoretical descriptors of the complexes. In vitro antibacterial assays were conducted to evaluate the complexes\u2019 potential against pathogenic bacteria and fungi, comparing them to the free ligand. The compounds exhibited excellent fungicidal activity against Candida albicans ATCC: 10231 (C. albicans) and Aspergillus negar ATCC: 16404 (A. negar), with inhibition zones of HL, [Zn(L)(NO3)(H2O)3], and [La(L)(NO3)2(H2O)2] three times higher than that of the Nystatin antibiotic. The DNA binding affinity of the metal complexes and their ligand was investigated using UV-visible, viscosity, and gel electrophoresis methods, suggesting an intercalative binding mode. The absorption studies yielded Kb values ranging from 4.40 \u00d7 105 to 7.30 \u00d7 105 M\u22121, indicating high binding strength to DNA comparable to ethidium bromide (value 107 M\u22121). Additionally, the antioxidant activity of all complexes was measured and compared to vitamin C. The anti-inflammatory efficacy of the ligand and its metal complexes was evaluated, revealing that [Cu(L)(NO3)(H2O)3] exhibited the most effective activity compared to ibuprofen. Molecular docking studies were conducted to explore the binding nature and affinity of the synthesized compounds with the receptor of Candida albicans oxidoreductase\/oxidoreductase INHIBITOR (PDB ID: 5V5Z). Overall, the combined findings of this work demonstrate the potential of these new compounds as efficient fungicidal and anti-inflammatory agents. Furthermore, the photocatalytic effect of the Cu(II) Schiff base complex\/GO was examined.<\/jats:p>","DOI":"10.3390\/molecules28124777","type":"journal-article","created":{"date-parts":[[2023,6,15]],"date-time":"2023-06-15T02:03:19Z","timestamp":1686794599000},"page":"4777","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Synthesis, Characterization, DFT Studies of Novel Cu(II), Zn(II), VO(II), Cr(III), and La(III) Chloro-Substituted Schiff Base Complexes: Aspects of Its Antimicrobial, Antioxidant, Anti-Inflammatory, and Photodegradation of Methylene Blue"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7375-2885","authenticated-orcid":false,"given":"Laila H.","family":"Abdel-Rahman","sequence":"first","affiliation":[{"name":"Chemistry Department, Faculty of Science, Sohag University, Sohag 82534, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1416-0844","authenticated-orcid":false,"given":"Maram T.","family":"Basha","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science, University of Jeddah, Jeddah 21589, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Badriah Saad","family":"Al-Farhan","sequence":"additional","affiliation":[{"name":"Chemistry Department, Faculty of Girls for Science, King Khalid University, Abha 61421, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walaa","family":"Alharbi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Science and Arts College, King Abdulaziz University, Rabigh 21911, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1289-0285","authenticated-orcid":false,"given":"Mohamed R.","family":"Shehata","sequence":"additional","affiliation":[{"name":"Chemistry Department, Faculty of Science, Cairo University, Giza 12613, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4953-5861","authenticated-orcid":false,"given":"Noura O.","family":"Al Zamil","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Science, Imam Abdurrahman Bin Faisal University, P.O. Box 1982, Dammam 31441, Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8299-7259","authenticated-orcid":false,"given":"Doaa","family":"Abou El-ezz","sequence":"additional","affiliation":[{"name":"Department of Pharmacology and Toxicology, Faculty of Pharmacy, October University for Modern Sciences and Arts (MSA University), Giza 12566, Egypt"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,6,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/j.molstruc.2017.05.092","article-title":"Synthesis, spectral, thermal and biological studies of mixed ligand complexes with newly prepared Schiff base and 1,10-phenanthroline ligands","volume":"1146","author":"Mohamed","year":"2017","journal-title":"J. Mol. Struct."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"316","DOI":"10.1016\/j.saa.2015.01.054","article-title":"New group 6 metal carbonyl complexes with 4,5-dimethyl-N,N-bis(pyridine-2-yl-methylene)benzene-1,2-diimine Schiff base: Synthesis, spectral, cyclic voltammetry and biological activity studies","volume":"141","author":"Mohamed","year":"2015","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.saa.2014.03.127","article-title":"Palladium(II) and zinc(II) complexes of neutral [N2O2] donor Schiff bases derived from furfuraldehyde: Synthesis, characterization, fluorescence and corrosion inhibitors of ligands","volume":"132","author":"Ali","year":"2014","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_4","first-page":"13","article-title":"Synthesis, Characterization and Antimicrobial Activity of Metal Complexes of Schiff \u2019 s Base Derived from S-benzyldithiocarbazate with 2-hydroxyacetophenone","volume":"3","author":"Nasrin","year":"2013","journal-title":"Chem. J."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1016\/j.saa.2013.08.037","article-title":"Spectroscopic and biological activities studies of bivalent transition metal complexes of Schiff bases derived from condensation of 1,4-phenylenediamine and benzopyrone derivatives","volume":"117","author":"Sherif","year":"2014","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"468","DOI":"10.1016\/j.saa.2012.11.077","article-title":"Design, spectral characterization and biological studies of transition metal(II) complexes with triazole Schiff bases","volume":"104","author":"Hanif","year":"2013","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"103737","DOI":"10.1016\/j.arabjc.2022.103737","article-title":"Synthesis, characterization, biological and docking studies of ZrO (II), VO (II) and Zn (II) complexes of a halogenated tetra-dentate Schiff base","volume":"15","author":"Adam","year":"2022","journal-title":"Arab. J. Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"3055","DOI":"10.1016\/j.ccr.2005.05.003","article-title":"Ruthenium complexes bearing bidentate Schiff base ligands as efficient catalysts for organic and polymer syntheses","volume":"249","author":"Drozdzak","year":"2005","journal-title":"Coord. Chem. Rev."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"119443","DOI":"10.1016\/j.ica.2020.119443","article-title":"Design and synthesis of three Fe(III) mixed-ligand complexes: Exploration of their biological and phenoxazinone synthase-like activities","volume":"505","author":"Ismael","year":"2020","journal-title":"Inorg. Chim. Acta"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.molstruc.2013.02.023","article-title":"Synthesis, physicochemical studies, embryos toxicity and DNA interaction of some new Iron(II) Schiff base amino acid complexes","volume":"1040","author":"Nassr","year":"2013","journal-title":"J. Mol. Struct."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"131348","DOI":"10.1016\/j.molstruc.2021.131348","article-title":"[Cu (dipicolinoylamide)(NO3)(H2O)] as anti-COVID-19 and antibacterial drug candidate: Design, synthesis, crystal structure, DFT and molecular docking","volume":"1247","author":"Basha","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"131854","DOI":"10.1016\/j.molstruc.2021.131854","article-title":"Synthesis, biological assay, chemical descriptors, and molecular docking calculations of novel copper (II) mixed-ligand complexes of n-benzoyl-dl-phenylalanine and n-heterocyclic nitrogen bases","volume":"1250","author":"Basha","year":"2022","journal-title":"J. Mol. Struct."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"994","DOI":"10.1080\/00958972.2022.2095267","article-title":"Physicochemical, in vitro therapeutic activity, DNA-binding, and in silico molecular docking studies of samarium (III) complexes bearing N, O-chelated Schiff base ligands","volume":"75","author":"Abdelghani","year":"2022","journal-title":"J. Coord. Chem."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"668","DOI":"10.1080\/00958972.2022.2075742","article-title":"Co(II), Ni(II), and Cu(II) complexes derived from 1,2,4-triazine: Synthesis, characterization, anticancer activity, DFT, and molecular docking studies with a COVID-19 protein receptor","volume":"75","author":"Elantabli","year":"2022","journal-title":"J. Coord. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1265","DOI":"10.2298\/JSC0712265V","article-title":"Interactions of the anti-tumor sesquiterpene hydroquinone avarol with DNA in vitro","volume":"72","author":"Vujcic","year":"2007","journal-title":"J. Serb. Chem. Soc."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1016\/0167-2789(85)90011-9","article-title":"Determining lyapunov exponents from a time series","volume":"16","author":"Wolf","year":"1985","journal-title":"Phys. D Nonlinear Phenom."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"524","DOI":"10.1039\/b509608c","article-title":"The therapeutic application of lanthanides","volume":"35","author":"Fricker","year":"2006","journal-title":"Chem. Soc. Rev."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0020-1693(00)84685-X","article-title":"Syntheses and Spectroscopic Studies on Dioxouranium (VI), Oxovanadium (IV) and Oxozirconium (IV) Complexes with Tetradentate Macrocyclic Ligands","volume":"128","author":"Yadava","year":"1987","journal-title":"Inorg. Chim. Acta"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1016\/j.molstruc.2015.08.008","article-title":"Computational simulation and biological studies on 3-(2-(2-hydroxybenzoyl)hydrazono)-N-(pyridine-2-yl)butanamide complexes","volume":"1101","author":"Ibrahim","year":"2015","journal-title":"J. Mol. Struct."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"3117","DOI":"10.1007\/s13738-022-02514-x","article-title":"New bidentate Schiff base ligands derived from histidine and their metal complexes: Synthesis, structural analysis, antibacterial and antioxidant evaluation","volume":"19","author":"Slassi","year":"2022","journal-title":"J. Iran. Chem. Soc."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"501","DOI":"10.1016\/j.arabjc.2010.09.018","article-title":"Synthesis, spectroscopic characterization and thermal studies of some rare earth metal complexes of unsymmetrical tetradentate Schiff base ligand","volume":"5","author":"Shelke","year":"2012","journal-title":"Arab. J. Chem."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1373","DOI":"10.1007\/s10562-016-1755-0","article-title":"Some New Nano-sized Mononuclear Cu(II) Schiff Base Complexes: Design, Characterization, Molecular Modeling and Catalytic Potentials in Benzyl Alcohol Oxidation","volume":"146","author":"Adam","year":"2016","journal-title":"Catal. Lett."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3199","DOI":"10.1038\/s41598-023-29386-2","article-title":"Novel Bromo and methoxy substituted Schiff base complexes of Mn(II), Fe(III), and Cr(III) for anticancer, antimicrobial, docking, and ADMET studies","volume":"13","author":"Abdelghani","year":"2023","journal-title":"Sci Rep."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"93","DOI":"10.4489\/MYCO.2008.36.2.093","article-title":"Antibacterial and Antifungal Studies on Some Schiff Base Complexes of Zinc(II) Antibacterial and Antifungal Studies on Some Schiff Base Complexes of Zinc (II)","volume":"36","author":"Joseyphus","year":"2008","journal-title":"Mycobiology"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"641","DOI":"10.2298\/JSC0309641K","article-title":"Synthesis and characterization of Co (II), Ni (II), Cu (II) and Zn (II) complexes with 3-salicylidenehydrazono-2-indolinone","volume":"68","author":"Konstantinovi","year":"2003","journal-title":"JSCS"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"e6817","DOI":"10.1002\/aoc.6817","article-title":"Synthesis, spectroscopic, DFT calculations, antimicrobial, cytotoxicity, and DNA binding studies of novel Cu (II), Ni (II), Zn (II), and VO (II) Schiff base complexes based on ibuprofen","volume":"36","author":"Mohamed","year":"2022","journal-title":"Appl. Organomet. Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"114589","DOI":"10.1016\/j.poly.2020.114589","article-title":"Synthesis, coordination properties and biological activity of vanadium complexes with hydrazone Schiff base ligands","volume":"185","author":"Szklarzewicz","year":"2020","journal-title":"Polyhedron"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"e5912","DOI":"10.1002\/aoc.5912","article-title":"Synthesis, Characterization, Theoretical Studies, and Antimicrobial\/Antitumor Potencies of Salen and Salen\/Imidazole Complexes of Co (II), Ni (II), Cu (II), Cd (II), Al (III) and La (III)","volume":"34","author":"Abdalla","year":"2020","journal-title":"Appl. Organomet. Chem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/j.poly.2015.01.017","article-title":"An unusual hydroxy-substituted mononuclear nickel(II) complex with a tetradentate Schiff base: Synthesis, spectroscopy, electrochemistry, crystallography, DNA binding, and theoretical investigation","volume":"89","author":"Gupta","year":"2015","journal-title":"Polyhedron"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1293","DOI":"10.1007\/s10904-019-01269-y","article-title":"Nanostructured Metal Oxides Prepared from Schiff Base Metal Complexes: Study of the Catalytic Activity in Selective Oxidation and C\u2013C Coupling Reactions","volume":"30","author":"Prashar","year":"2020","journal-title":"J. Inorg. Organomet. Polym. Mater."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1023\/A:1007132408648","article-title":"Ruthenium(II) complexes containing bidentate Schiff bases and their antifungal activity","volume":"26","author":"Dharmaraj","year":"2001","journal-title":"Transit. Met. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1023\/A:1006986131435","article-title":"Synthesis, structural and biochemical aspects of titanocene and zirconocene chelates of acetylferrocenyl thiosemicarbazones","volume":"23","author":"Sengupta","year":"1998","journal-title":"Transit. Met. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"e4556","DOI":"10.1002\/aoc.4556","article-title":"Transition metal complexes of nano bidentate organometallic Schiff base: Preparation, structure characterization, biological activity, DFT and molecular docking studies","volume":"33","author":"Mahmoud","year":"2019","journal-title":"Appl. Organomet. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"e5048","DOI":"10.1002\/aoc.5048","article-title":"Synthesis, characterization of Schiff base metal complexes and their biological investigation","volume":"33","author":"Mahmoud","year":"2019","journal-title":"Appl. Organomet. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"118508","DOI":"10.1016\/j.molliq.2022.118508","article-title":"Synthesis, spectroscopic characterizations, biological activity, DNA-binding investigation combined with DFT studies of new proton-transfer complexes of 2,4-diaminopyrimidine with 2,6-dichloro-4-nitrophenol and 3,5-dinitrosalicylic acid","volume":"350","author":"Basha","year":"2022","journal-title":"J. Mol. Liq."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"266","DOI":"10.1016\/j.saa.2013.03.061","article-title":"Design, characterization, teratogenicity testing, antibacterial, antifungal and DNA interaction of few high spin Fe(II) Schiff base amino acid complexes","volume":"111","author":"Nassr","year":"2013","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_37","first-page":"167","article-title":"Novel Co(II) Ni(II) and Cu(II) complexes of tridentate ons donor schiff base ligands: Synthesis, characterization, DNA cleavage, molecular docking, antioxidant and antimicrobial studies","volume":"13","author":"Salomanravi","year":"2022","journal-title":"J. Adv. Sci. Res."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"e6451","DOI":"10.1002\/aoc.6451","article-title":"DNA binding, cleavage, docking, biological and kinetic studies of Cr(III), Fe(III), Co(II) and Cu(II) complexes with ortho-vanillin Schiff base derivative","volume":"36","author":"Bengi","year":"2022","journal-title":"Appl. Organomet. Chem."},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Abou El-ezz, D., Abdel-Rahman, L.H., Al-Farhan, B.S., Mostafa, D.A., Ayad, E.G., Basha, M.T., Abdelaziz, M., and Abdalla, E.M. (2022). Enhanced In Vivo Wound Healing Efficacy of a Novel Hydrogel Loaded with Copper (II) Schiff Base Quinoline Complex (CuSQ) Solid Lipid Nanoparticles. Pharmaceuticals, 15.","DOI":"10.3390\/ph15080978"},{"key":"ref_40","doi-asserted-by":"crossref","unstructured":"Al-Farhan, B.S., Basha, M.T., Abdel Rahman, L.H., El-Saghier, A.M., Abou El-Ezz, D., Marzouk, A.A., Shehata, M.R., and Abdalla, E.M. (2021). Synthesis, DFT Calculations, Antiproliferative, Bactericidal Activity and Molecular Docking of Novel Mixed-Ligand Salen\/8-Hydroxyquinoline Metal Complexes. Molecules, 26.","DOI":"10.3390\/molecules26164725"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"5443","DOI":"10.1039\/c3dt52597j","article-title":"Methylene bridge regulated geometrical preferences of ligands in cobalt(III) coordination chemistry and phenoxazinone synthase mimicking activity","volume":"43","author":"Panja","year":"2014","journal-title":"Dalton Trans."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"e6484","DOI":"10.1002\/aoc.6484","article-title":"Synthesis, characterization, potential antimicrobial, antioxidant, anticancer, DNA binding, and molecular docking activities and DFT on novel Co (II), Ni (II), VO (II), Cr (III), and La (III) Schiff base complexes","volume":"36","author":"Basha","year":"2022","journal-title":"Appl. Organomet. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"853","DOI":"10.1016\/j.catcom.2008.12.010","article-title":"Alkene epoxidation catalyzed by molybdenum supported on functionalized MCM-41 containing N\u2013S chelating Schiff base ligand","volume":"10","author":"Tangestaninejad","year":"2009","journal-title":"Catal. Commun."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"e1800339","DOI":"10.1002\/ardp.201800339","article-title":"Novel ketoprofen\u2013antioxidants mutual codrugs as safer nonsteroidal anti-inflammatory drugs: Synthesis, kinetic and pharmacological evaluation","volume":"352","author":"Sehajpal","year":"2019","journal-title":"Arch. Pharm."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"5225","DOI":"10.1039\/c2dt12287a","article-title":"Modelling the site of bromide binding in vanadate-dependent bromoperoxidases","volume":"41","author":"Kraehmer","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1016\/j.ccr.2018.05.012","article-title":"Lanthanides: Schiff base complexes, applications in cancer diagnosis, therapy, and antibacterial activity","volume":"370","author":"Kaczmarek","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_47","first-page":"125","article-title":"Lanthanum Ion As a Probe of Biological Systems","volume":"Volume 28","author":"Guerra","year":"2000","journal-title":"Handbook on the Physics and Chemistry of Rare Earths"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1016\/j.molstruc.2014.06.028","article-title":"Assembly, structures and properties of four Cu (II) coordination polymers based on a semi-rigid bis-pyridyl-bis-amide ligand and different polycarboxylates","volume":"1074","author":"Wang","year":"2014","journal-title":"J. Mol. Struct."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/j.inoche.2013.08.039","article-title":"Two new Cu (II) complexes constructed by mixed-organic tectonics: Structures, magnetic properties and photocatalytic degradation of organic dyes","volume":"36","author":"Wu","year":"2013","journal-title":"Inorg. Chem. Commun."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/12\/4777\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T19:55:19Z","timestamp":1760126119000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/12\/4777"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,6,15]]},"references-count":49,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2023,6]]}},"alternative-id":["molecules28124777"],"URL":"https:\/\/doi.org\/10.3390\/molecules28124777","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,6,15]]}}}