{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T21:50:53Z","timestamp":1791496253301,"version":"4.3.4"},"reference-count":31,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2023,6,28]],"date-time":"2023-06-28T00:00:00Z","timestamp":1687910400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"central government to guide the development of local science and technology in Sichuan Province","award":["2021ZYD0099"],"award-info":[{"award-number":["2021ZYD0099"]}]},{"name":"central government to guide the development of local science and technology in Sichuan Province","award":["2021ZDZX0002"],"award-info":[{"award-number":["2021ZDZX0002"]}]},{"name":"central government to guide the development of local science and technology in Sichuan Province","award":["2023NSFSC1125"],"award-info":[{"award-number":["2023NSFSC1125"]}]},{"name":"central government to guide the development of local science and technology in Sichuan Province","award":["2021DJ2503"],"award-info":[{"award-number":["2021DJ2503"]}]},{"name":"central government to guide the development of local science and technology in Sichuan Province","award":["2021-BS-058"],"award-info":[{"award-number":["2021-BS-058"]}]},{"name":"Sichuan Science and Technology Program","award":["2021ZYD0099"],"award-info":[{"award-number":["2021ZYD0099"]}]},{"name":"Sichuan Science and Technology Program","award":["2021ZDZX0002"],"award-info":[{"award-number":["2021ZDZX0002"]}]},{"name":"Sichuan Science and Technology Program","award":["2023NSFSC1125"],"award-info":[{"award-number":["2023NSFSC1125"]}]},{"name":"Sichuan Science and Technology Program","award":["2021DJ2503"],"award-info":[{"award-number":["2021DJ2503"]}]},{"name":"Sichuan Science and Technology Program","award":["2021-BS-058"],"award-info":[{"award-number":["2021-BS-058"]}]},{"name":"PetroChina Key technical research on Marine oil and gas development and engineering","award":["2021ZYD0099"],"award-info":[{"award-number":["2021ZYD0099"]}]},{"name":"PetroChina Key technical research on Marine oil and gas development and engineering","award":["2021ZDZX0002"],"award-info":[{"award-number":["2021ZDZX0002"]}]},{"name":"PetroChina Key technical research on Marine oil and gas development and engineering","award":["2023NSFSC1125"],"award-info":[{"award-number":["2023NSFSC1125"]}]},{"name":"PetroChina Key technical research on Marine oil and gas development and engineering","award":["2021DJ2503"],"award-info":[{"award-number":["2021DJ2503"]}]},{"name":"PetroChina Key technical research on Marine oil and gas development and engineering","award":["2021-BS-058"],"award-info":[{"award-number":["2021-BS-058"]}]},{"name":"Liaoning Provincial Doctoral Research Foundation of 2021","award":["2021ZYD0099"],"award-info":[{"award-number":["2021ZYD0099"]}]},{"name":"Liaoning Provincial Doctoral Research Foundation of 2021","award":["2021ZDZX0002"],"award-info":[{"award-number":["2021ZDZX0002"]}]},{"name":"Liaoning Provincial Doctoral Research Foundation of 2021","award":["2023NSFSC1125"],"award-info":[{"award-number":["2023NSFSC1125"]}]},{"name":"Liaoning Provincial Doctoral Research Foundation of 2021","award":["2021DJ2503"],"award-info":[{"award-number":["2021DJ2503"]}]},{"name":"Liaoning Provincial Doctoral Research Foundation of 2021","award":["2021-BS-058"],"award-info":[{"award-number":["2021-BS-058"]}]},{"name":"2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China","award":["2021ZYD0099"],"award-info":[{"award-number":["2021ZYD0099"]}]},{"name":"2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China","award":["2021ZDZX0002"],"award-info":[{"award-number":["2021ZDZX0002"]}]},{"name":"2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China","award":["2023NSFSC1125"],"award-info":[{"award-number":["2023NSFSC1125"]}]},{"name":"2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China","award":["2021DJ2503"],"award-info":[{"award-number":["2021DJ2503"]}]},{"name":"2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China","award":["2021-BS-058"],"award-info":[{"award-number":["2021-BS-058"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Hydrogen sulfide (H2S) is widely found in oil and natural gas wells and industrial wastewater tanks. Owing to its high toxicity, the monitoring and detection of H2S in the air is essential. However, recent techniques for the quantitative detection of H2S gas suffer from limitations such as high cost, complicated operation, and insufficient sensitivity, preventing their practical application in industry. Thus, we have developed a portable test paper for real-time and inexpensive monitoring of H2S gas by color changes. The test paper had a significantly low H2S detection limit of 200 ppb, which is considered safe for humans. Moreover, the color of the test paper did not change noticeably when exposed to CO2, N2, O2, and air environments, indicating that the test paper is selective for H2S gas and can be stored for a long time. In addition, we fitted a color difference linear model between the color difference values (\u0394E) and the concentrations of H2S gas. The establishment of the linear model substantiates that the test paper can provide accurate intensity information when detecting H2S gas leakage.<\/jats:p>","DOI":"10.3390\/molecules28135044","type":"journal-article","created":{"date-parts":[[2023,6,29]],"date-time":"2023-06-29T01:43:13Z","timestamp":1688002993000},"page":"5044","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["A Visual Color Response Test Paper for the Detection of Hydrogen Sulfide Gas in the Air"],"prefix":"10.3390","volume":"28","author":[{"given":"Hailong","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyu","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongpeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongzhi","family":"Han","sequence":"additional","affiliation":[{"name":"CNPC Engineering Technology Research Company Limited, Tianjin 300451, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingying","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Optoelectronic Chemical Materials and Devices (Ministry of Education), Jianghan University, Wuhan 430056, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojun","family":"Guo","sequence":"additional","affiliation":[{"name":"CNPC Engineering Technology Research Company Limited, Tianjin 300451, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taigang","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haibing","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianjun","family":"Wu","sequence":"additional","affiliation":[{"name":"Research Institute of Tianfu New Energy, Chengdu 610217, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4114-4409","authenticated-orcid":false,"given":"Junlei","family":"Tang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,6,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"846","DOI":"10.1016\/j.snb.2017.06.114","article-title":"Quantitative, colorimetric paper probe for hydrogen sulfide gas","volume":"253","author":"Carpenter","year":"2017","journal-title":"Sens. Actuators B Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1016\/j.jhazmat.2013.09.070","article-title":"An approach for estimating toxic releases of H2S-containing natural gas","volume":"264","author":"Jianwen","year":"2014","journal-title":"J. Hazard. Mater."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.rser.2016.06.019","article-title":"Eco Friendly nanocomposite materials to scavenge hazard gas H2S through fixed-bed reactor in petroleum application","volume":"65","author":"Nassar","year":"2016","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"106276","DOI":"10.1016\/j.fuproc.2019.106276","article-title":"Detailed kinetic modeling of H2S formation during fuel-rich combustion of pulverized coal","volume":"199","author":"Ma","year":"2020","journal-title":"Fuel Process. Technol."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1016\/j.foodchem.2016.08.046","article-title":"Bin Development of sensitive and selective food sensors using new Re(I)-Pt(II) bimetallic complexes to detect volatile biogenic sulfides formed by meat spoilage","volume":"216","author":"Chow","year":"2017","journal-title":"Food Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/j.wasman.2019.10.003","article-title":"Prospects for biogas production and H2S control from the anaerobic digestion of cattle manure: The influence of microscale waste iron powder and iron oxide nanoparticles","volume":"101","author":"Farghali","year":"2020","journal-title":"Waste Manag."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"124523","DOI":"10.1016\/j.jhazmat.2020.124523","article-title":"A multifunctional fluorescent probe for visualizing H2S in wastewater with portable smartphone via fluorescent paper strip and sensing GSH in vivo","volume":"406","author":"Feng","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"464","DOI":"10.1080\/15428119691014819","article-title":"Effects of 5 ppm hydrogen sulfide inhalation on biochemical properties of skeletal muscle in exercising men and women","volume":"57","author":"Bhambhani","year":"1996","journal-title":"Am. Ind. Hyg. Assoc. J."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1016\/j.snb.2011.08.032","article-title":"Semiconducting metal oxides as sensors for environmentally hazardous gases","volume":"160","author":"Wetchakun","year":"2011","journal-title":"Sens. Actuators B Chem."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"544","DOI":"10.1016\/j.snb.2007.02.050","article-title":"Solid-state potentiometric H2S sensor combining NASICON with Pr6O11-doped SnO2 electrode","volume":"125","author":"Liang","year":"2007","journal-title":"Sens. Actuators B Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"167","DOI":"10.1016\/j.jhazmat.2015.07.003","article-title":"A fast response & recovery H2S gas sensor based on \u03b1-Fe2O3 nanoparticles with ppb level detection limit","volume":"300","author":"Li","year":"2015","journal-title":"J. Hazard. Mater."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"260","DOI":"10.1016\/j.snb.2019.03.101","article-title":"PdCu alloy nanosheets-constructed 3D flowers: New highly sensitive materials for H2S detection","volume":"289","author":"Shang","year":"2019","journal-title":"Sens. Actuators B Chem."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"771","DOI":"10.1016\/S0039-9140(00)00421-5","article-title":"Analytical strategies for the detection of sulfide: A review","volume":"52","author":"Lawrence","year":"2000","journal-title":"Talanta"},{"key":"ref_14","first-page":"1857","article-title":"A review on the electrochemical sensors and biosensors composed of nanogaps as sensing material","volume":"12","author":"Dhahi","year":"2010","journal-title":"J. Optoelectron. Adv. Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"8158","DOI":"10.3390\/s91008158","article-title":"Semiconducting metal oxide based sensors for selective gas pollutant detection","volume":"9","author":"Kanan","year":"2009","journal-title":"Sensors"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.foodhyd.2019.03.008","article-title":"Extract from Lycium ruthenicum Murr. Incorporating \u03ba-carrageenan colorimetric film with a wide pH\u2013sensing range for food freshness monitoring","volume":"94","author":"Liu","year":"2019","journal-title":"Food Hydrocoll."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"115030","DOI":"10.1016\/j.carbpol.2019.115030","article-title":"A novel pH-sensing indicator based on bacterial cellulose nanofibers and black carrot anthocyanins for monitoring fish freshness","volume":"222","author":"Moradi","year":"2019","journal-title":"Carbohydr. Polym."},{"key":"ref_18","unstructured":"(2021, June 19). AFP, Toxic Leak Kills Two in Czech Water Treatment Plant, The News International, Available online: https:\/\/www.thenews.com.pk\/print\/851581-toxic-leak-kills-two-in-czech-water-treatment-plant."},{"key":"ref_19","unstructured":"Pang, S. (China Emergency Management News, 2022). 3 Dead and 3 Injured, Chemical Gas Leakage Accident, China Emergency Management News."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"106617","DOI":"10.1016\/j.porgcoat.2021.106617","article-title":"Ethyl cellulose based peelable coatings with visual sensing of hydrogen sulfide","volume":"163","author":"Tang","year":"2022","journal-title":"Prog. Org. Coatings"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"41540","DOI":"10.1039\/C7RA08137E","article-title":"Gas-solid reaction for: In situ deposition of Cu3SbS4 on a mesoporous TiO2 film","volume":"7","author":"Zhang","year":"2017","journal-title":"RSC Adv."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"16907","DOI":"10.1021\/acsnano.0c05916","article-title":"Colorimetric Dye-Loaded Nanofiber Yarn: Eye-Readable and Weavable Gas Sensing Platform","volume":"14","author":"Kim","year":"2020","journal-title":"ACS Nano"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"132278","DOI":"10.1016\/j.foodchem.2022.132278","article-title":"Multicolor hydrogen sulfide sensor for meat freshness assessment based on Cu2+-modified boron nitride nanosheets-supported subnanometer gold nanoparticles","volume":"381","author":"Lin","year":"2022","journal-title":"Food Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"3047","DOI":"10.1021\/acs.jafc.2c00087","article-title":"Near-Infrared Fluorescent Probe with a Large Stokes Shift for Detection of Hydrogen Sulfide in Food Spoilage, Living Cells, and Zebrafish","volume":"70","author":"Yang","year":"2022","journal-title":"J. Agric. Food Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"5067","DOI":"10.1021\/acs.inorgchem.2c00019","article-title":"Water-Stable Eu6-Cluster-Based fcu-MOF with Exposed Vinyl Groups for Ratiometric and Fluorescent Visual Sensing of Hydrogen Sulfide","volume":"61","author":"Han","year":"2022","journal-title":"Inorg. Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"52312","DOI":"10.1002\/app.52312","article-title":"Functionalized organic\u2013inorganic hybrid composites used as colorimetric chemosensors for hydrogen sulfide detection","volume":"139","author":"Wu","year":"2022","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.surfcoat.2017.11.014","article-title":"Surface anchoring of bi-functional organic linkers on piezoelectric BiFeO3 films and particles: Comparison between carboxylic and phosphonic tethering groups","volume":"343","author":"Tudisco","year":"2018","journal-title":"Surf. Coatings Technol."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"128129","DOI":"10.1016\/j.colsurfa.2021.128129","article-title":"Synthesis of Ce-doped magnetic NaY zeolite for effective Sb removal: Study of its performance and mechanism","volume":"636","author":"Wang","year":"2022","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"1836","DOI":"10.1016\/j.jnoncrysol.2009.05.064","article-title":"X-ray photoelectron spectroscopic studies on Se\/As2S3 and Sb\/As2S3 nanomultilayered film","volume":"355","author":"Naik","year":"2009","journal-title":"J. Non. Cryst. Solids"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"27372","DOI":"10.1007\/s11356-019-05914-4","article-title":"Hyperbranched polyamide\u2013functionalized sodium alginate microsphere as a novel adsorbent for the removal of antimony(III) in wastewater","volume":"26","author":"Wang","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"806","DOI":"10.1007\/s40242-013-2401-7","article-title":"Degradation of Hydrogenated Nitrile-butadiene Rubber in Aqueous Solutions of H2S or HCl","volume":"29","author":"Cong","year":"2013","journal-title":"Chem. Res. Chin. Univ."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/13\/5044\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:02:31Z","timestamp":1760126551000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/13\/5044"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,6,28]]},"references-count":31,"journal-issue":{"issue":"13","published-online":{"date-parts":[[2023,7]]}},"alternative-id":["molecules28135044"],"URL":"https:\/\/doi.org\/10.3390\/molecules28135044","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,6,28]]}}}