{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T03:17:12Z","timestamp":1791688632411,"version":"4.3.4"},"reference-count":62,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2023,6,28]],"date-time":"2023-06-28T00:00:00Z","timestamp":1687910400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003141","name":"CONACyT","doi-asserted-by":"publisher","award":["864427"],"award-info":[{"award-number":["864427"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003141","name":"CONACyT","doi-asserted-by":"publisher","award":["252658"],"award-info":[{"award-number":["252658"]}],"id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In this work, recent research progresses in the formation of Pt3Cu nanoparticles onto the surface of graphene are described, and the obtained results are contrasted with previously published theoretical studies. To form these nanoparticles, tetrabutylammonium hexachloroplatinate, and copper acetylacetonate are used as platinum and copper precursors, respectively. Oleylamine is used as a reductor and a solvent. The obtained catalyst is characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy dispersive spectroscopy X-ray (EDS). To assess the catalytic activity, the graphene-supported Pt3Cu material is tested with cyclic voltammetry, \u201cCO stripping\u201d, and oxygen reduction reaction potentiodynamic curves to find the nature and the intrinsic electrochemical activity of the material. It can be observed that the tetrabutylammonium cation plays a critical role in anchoring and supporting nanoparticles over graphene, from which a broad discussion about the true nature of the anchoring mechanism was derived. The growth mechanism of the nanoparticles on the surface of graphene was observed, supporting the conducted theoretical models. With this study, a reliable, versatile, and efficient synthesis of nanocatalysts is presented, demonstrating the potentiality of Pt3Cu\/graphene as an effective cathode catalyst. This study demonstrates the importance of reliable ab inito theoretical results as a useful source of information for the synthesis of the Pt3Cu alloy system.<\/jats:p>","DOI":"10.3390\/molecules28135072","type":"journal-article","created":{"date-parts":[[2023,6,29]],"date-time":"2023-06-29T01:43:13Z","timestamp":1688002993000},"page":"5072","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["One-Pot Graphene Supported Pt3Cu Nanoparticles\u2014From Theory towards an Effective Molecular Oxygen Reduction Reaction Catalyst"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3262-3694","authenticated-orcid":false,"given":"Carlos Daniel","family":"Galindo-Uribe","sequence":"first","affiliation":[{"name":"Chemistry Department, Research Center for Advanced Studies (CINVESTAV), Av. Instituto Polit\u00e9cnico Nacional 2508, Col. San Pedro Zacatenco, Del. Gustavo A. Madero, Mexico City 07360, Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerald","family":"Geudtner","sequence":"additional","affiliation":[{"name":"Chemistry Department, Research Center for Advanced Studies (CINVESTAV), Av. Instituto Polit\u00e9cnico Nacional 2508, Col. San Pedro Zacatenco, Del. Gustavo A. Madero, Mexico City 07360, Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9842-4271","authenticated-orcid":false,"given":"Patrizia","family":"Calaminici","sequence":"additional","affiliation":[{"name":"Chemistry Department, Research Center for Advanced Studies (CINVESTAV), Av. Instituto Polit\u00e9cnico Nacional 2508, Col. San Pedro Zacatenco, Del. Gustavo A. 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