{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T03:05:53Z","timestamp":1787540753940,"version":"build-2736575974"},"reference-count":55,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2023,7,12]],"date-time":"2023-07-12T00:00:00Z","timestamp":1689120000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Natural Science Foundation of Fujian Province of China","award":["2023J01499"],"award-info":[{"award-number":["2023J01499"]}]},{"name":"Natural Science Foundation of Fujian Province of China","award":["21805036"],"award-info":[{"award-number":["21805036"]}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["2023J01499"],"award-info":[{"award-number":["2023J01499"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21805036"],"award-info":[{"award-number":["21805036"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>As an important thermosetting material, flame-retardant epoxy resin has various applications in the aerospace, chemical, and electronics industry, and other fields. However, the flame retardancy of epoxy resins is often improved at the expense of mechanical performance. The contradiction between flame retardancy and mechanical properties seriously impedes the practical applications of epoxy resin (EP). Herein, iron-loaded polydopamine functionalized montmorillonite (D-Mt-Fe3+), which was prepared by dopamine, iron chloride and montmorillonite in an aqueous solution, was introduced to prepare iron-loaded polydopamine functionalized montmorillonite\/epoxy resin composites (D-Mt-Fe3+\/EP). As expected, D-Mt-Fe3+\/EP-10 with 10 phr of D-Mt-Fe3+ passed the UL-94 V-0 rating, achieved a limiting oxygen index (LOI) value of 31.0% and reduced the smoke production rate (SPR) and total smoke production (TSP), indicating that the introduction of D-Mt-Fe3+ could endow EP with satisfactory flame retardancy through the radical scavenging function of dopamine in the gas phase and the catalytic charring effect of iron ions, respectively. Encouragingly, the mechanical property was also enhanced with the flexural strength increased by 25.5%. This work provided an attractive strategy for improving both the mechanical properties and fire resistance of EP, which greatly broadened their applications in the chemical industry and electronics field, etc.<\/jats:p>","DOI":"10.3390\/molecules28145354","type":"journal-article","created":{"date-parts":[[2023,7,13]],"date-time":"2023-07-13T01:58:11Z","timestamp":1689213491000},"page":"5354","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Bio-Inspired Iron-Loaded Polydopamine Functionalized Montmorillonite as an Environmentally Friendly Flame Retardant for Epoxy Resin"],"prefix":"10.3390","volume":"28","author":[{"given":"Jiashui","family":"Lan","sequence":"first","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China"},{"name":"Research and Development Department, Waexim (Xiamen) New Materials Co., Ltd., Xiamen 361023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingsi","family":"Li","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Zhong","sequence":"additional","affiliation":[{"name":"Research and Development Department, Waexim (Xiamen) New Materials Co., Ltd., Xiamen 361023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhui","family":"Luo","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huagui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingfeng","family":"Chen","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1038\/nnano.2014.248","article-title":"Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide","volume":"10","author":"Wicklein","year":"2015","journal-title":"Nat. Nanotechnol."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"5890","DOI":"10.1039\/C6TC01210H","article-title":"An overview of multifunctional epoxy nanocomposites","volume":"4","author":"Gu","year":"2016","journal-title":"J. Mater. Chem. C"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"100977","DOI":"10.1016\/j.pmatsci.2022.100977","article-title":"Toughness and its mechanisms in epoxy resins","volume":"130","author":"Mi","year":"2022","journal-title":"Prog. Mater. Sci."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"100594","DOI":"10.1016\/j.coco.2020.100594","article-title":"Construction of a novel three-in-one biomass based intumescent fire retardant through phosphorus functionalized metal-organic framework and \u03b2-cyclodextrin hybrids in achieving fire safe epoxy","volume":"23","author":"Zhang","year":"2021","journal-title":"Compos. Commun."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.compositesb.2017.08.020","article-title":"A review of extending performance of epoxy resins using carbon nanomaterials","volume":"136","author":"Liu","year":"2018","journal-title":"Compos. Part B-Eng."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"3445","DOI":"10.1016\/S0032-3861(00)00717-5","article-title":"Flame-retardant epoxy resins from novel phosphorus-containing novolac","volume":"42","author":"Liu","year":"2001","journal-title":"Polymer"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"19938","DOI":"10.1021\/acsami.0c02397","article-title":"Mica-based multilayer nanocoating as a highly effective flame retardant and smoke suppressant","volume":"12","author":"Fahami","year":"2020","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"129314","DOI":"10.1016\/j.cej.2021.129314","article-title":"Flame-retarded thermoplastic polyurethane elastomer: From organic materials to nanocomposites and new prospects","volume":"417","author":"Wan","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"143542","DOI":"10.1016\/j.cej.2023.143542","article-title":"Understanding the curing kinetics of boron-based hyperbranched polysiloxane reinforced and toughened epoxy resin by rheology","volume":"467","author":"Qiao","year":"2023","journal-title":"Chem. Eng. J."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"46601","DOI":"10.1002\/app.46601","article-title":"Application of metallic phytates to poly(vinyl chloride) as efficient biobased phosphorous flame retardants","volume":"135","author":"Cheng","year":"2018","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"121916","DOI":"10.1016\/j.cej.2019.121916","article-title":"A novel phosphorus\/nitrogen-containing polycarboxylic acid endowing epoxy resin with excellent flame retardance and mechanical properties","volume":"375","author":"Duan","year":"2019","journal-title":"Chem. Eng. J."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"5956","DOI":"10.1007\/s10853-020-05691-3","article-title":"An effective strategy to enhance the flame retardancy and mechanical properties of epoxy resin by using hyperbranched flame retardant","volume":"56","author":"Chen","year":"2021","journal-title":"J. Mater. Sci."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"20325","DOI":"10.1021\/acsami.9b02357","article-title":"Simultaneous improvement of mechanical and fire-safety properties of polymer composites with phosphonate-loaded MOF additives","volume":"11","author":"Qi","year":"2019","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"101562","DOI":"10.1016\/j.coco.2023.101562","article-title":"Enhancements in LOX compatibility and fracture toughness of carbon fiber\/epoxy composite for liquid oxygen cryotank by simultaneously introducing Al(OH)3 and phosphorous-nitrogen flame retardants","volume":"39","author":"Long","year":"2023","journal-title":"Compos. Commun."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3768","DOI":"10.1021\/acsapm.3c00377","article-title":"Facile construction of inorganic phosphorus\/boron-layered double hydroxide complexes for highly efficient fire-safety epoxy resin","volume":"5","author":"Shao","year":"2023","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2107905","DOI":"10.1002\/adma.202107905","article-title":"Advanced flame-retardant methods for polymeric materials","volume":"34","author":"Liu","year":"2021","journal-title":"Adv. Mater."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Sathish Kumar, P., Senthil, S.M., Pal, S.K., and Rajasekar, R. (2017). Organic\/Montmorillonite Nanocomposite Membranes. Org.-Inorg. Compos. Polym. Electrolyte Membr., 133\u2013164.","DOI":"10.1007\/978-3-319-52739-0_6"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"720","DOI":"10.1039\/C6RA25070J","article-title":"Enhanced flame-retardant effect of a montmorillonite\/phosphaphenanthrene compound in an epoxy thermoset","volume":"7","author":"Tang","year":"2017","journal-title":"RSC Adv."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"102481","DOI":"10.1016\/j.rinp.2019.102481","article-title":"Comparative performance of carbon nanotubes and nanoclays as flame retardants for epoxy composites","volume":"14","author":"Chen","year":"2019","journal-title":"Results Phys."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"47500","DOI":"10.1002\/app.47500","article-title":"Strengthen flame retardancy of epoxy thermoset by montmorillonite particles adhering phosphorus-containing fragments","volume":"137","author":"Liu","year":"2020","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1002\/pc.25831","article-title":"Synthesis of novel phosphonium bromide-montmorillonite nanocompound and its performance in flame retardancy and dielectric properties of epoxy resins","volume":"42","author":"Qin","year":"2021","journal-title":"Polym. Compos."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"124","DOI":"10.1016\/j.compositesa.2017.03.020","article-title":"The characterization of DOPO\/MMT nanocompound and its effect on flame retardancy of epoxy resin","volume":"98","author":"He","year":"2017","journal-title":"Compos. Part A-Appl. S."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"111662","DOI":"10.1016\/j.eurpolymj.2022.111662","article-title":"Improving flame retardant and smoke suppression efficiency for PBS by adding a tannin surface and interfacial modified IFR\/MMT synergist","volume":"181","author":"Yue","year":"2022","journal-title":"Eur. Polym. J."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"e2020035","DOI":"10.1590\/0104-1428.05620","article-title":"Comparison of MA-g-PP effectiveness through mechanical performance of functionalised graphene reinforced polypropylene","volume":"30","author":"Natarajan","year":"2020","journal-title":"Polimeros"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1007\/s42860-020-00098-2","article-title":"Organo-modification of montmorillonite","volume":"68","author":"Guo","year":"2020","journal-title":"Clay Clay Miner."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"15211","DOI":"10.1021\/acssuschemeng.9b02088","article-title":"Crucial role of covalent surface functionalization of clay nanofillers on improvement of the mechanical properties of bioepoxy resin","volume":"7","author":"Vo","year":"2019","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/j.apsusc.2018.12.127","article-title":"Surface modification of MMT and its effect on fatigue and fracture behavior of basalt\/epoxy-based composites in a seawater environment","volume":"473","author":"Kim","year":"2019","journal-title":"Appl. Surf. Sci."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"46079","DOI":"10.1002\/app.46079","article-title":"Layer-by-layer fabrication of nacre inspired epoxy\/MMT multilayered composites","volume":"135","author":"Batool","year":"2018","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"1111","DOI":"10.1007\/s11998-022-00731-w","article-title":"Preparation of modified montmorillonite\/graphene oxide composites to enhance the anticorrosive performance of epoxy coatings","volume":"20","author":"Hua","year":"2023","journal-title":"J. Coat. Technol. Res."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"7523","DOI":"10.1021\/acsami.7b19865","article-title":"Polydopamine surface chemistry\u2014A decade of discovery","volume":"10","author":"Ryu","year":"2018","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1016\/j.matt.2019.05.002","article-title":"Mussel-inspired surface engineering for water-remediation materials","volume":"1","author":"Wang","year":"2019","journal-title":"Matter"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"22493","DOI":"10.1021\/acsami.3c00769","article-title":"Mixed-solvent-mediated strategy for enhancing light absorption of polydopamine and adhesion Persistence of dopamine solutions","volume":"15","author":"Xia","year":"2023","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"26000","DOI":"10.1021\/acsami.3c03577","article-title":"Mussel-inspired fabrication of an environment-friendly and self-adhesive superhydrophobic polydopamine coating with excellent mechanical durability, anti-icing and self-cleaning performances","volume":"15","author":"Tian","year":"2023","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"102742","DOI":"10.1016\/j.surfin.2023.102742","article-title":"Mussel-inspired ferric ion-polydopamine complex as a facile, green and efficient platform to functionalize carbon fiber for improving interfacial adhesion of composites","volume":"37","author":"Wu","year":"2023","journal-title":"Surf. Interfaces"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"115263","DOI":"10.1016\/j.jelechem.2021.115263","article-title":"Electrochemical sensing of phenolics based on copper\/cobalt\/nitrogen co-doped hollow nanocarbon spheres","volume":"892","author":"Ma","year":"2021","journal-title":"J. Electroanal. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"155309","DOI":"10.1016\/j.apsusc.2022.155309","article-title":"Enhanced thermal conductivity of epoxy composites reinforced with oriented polydopamine-graphene foam complexed by metal ions","volume":"610","author":"Wang","year":"2023","journal-title":"Appl. Surf. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"40844","DOI":"10.1021\/acsami.8b14409","article-title":"Assembly of metal-phenolic\/catecholamine networks for synergistically anti-inflammatory, antimicrobial and anticoagulant coatings","volume":"10","author":"Li","year":"2018","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"6376","DOI":"10.1039\/C7TA10961J","article-title":"Simultaneously improving the fire safety and mechanical properties of epoxy resin with Fe-CNTs via large-scale preparation","volume":"6","author":"Zhang","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"107828","DOI":"10.1016\/j.compositesb.2020.107828","article-title":"Nanoparticles of polydopamine for improving mechanical and flame-retardant properties of an epoxy resin","volume":"186","author":"Yang","year":"2020","journal-title":"Compos. Part B-Eng."},{"key":"ref_40","first-page":"132","article-title":"Bio-based flame retardants to polymers: A review","volume":"6","author":"Wang","year":"2023","journal-title":"Adv. Ind. Eng. Polym. Res."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"104690","DOI":"10.1016\/j.reactfunctpolym.2020.104690","article-title":"Surface engineering of magnesium hydroxide via bioinspired iron-loaded polydopamine as green and efficient strategy to epoxy composites with improved flame retardancy and reduced smoke release","volume":"155","author":"Bi","year":"2020","journal-title":"React. Funct. Polym."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.progpolymsci.2019.04.001","article-title":"Recent progress in controlled carbonization of (waste) polymers","volume":"94","author":"Gong","year":"2019","journal-title":"Prog. Polym. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"100959","DOI":"10.1016\/j.coco.2021.100959","article-title":"Chemically inorganic modified ammonium polyphosphate as eco-friendly flame retardant and its high fire safety for epoxy resin","volume":"28","author":"Shao","year":"2021","journal-title":"Compos. Commun."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1637","DOI":"10.1007\/s10973-018-7699-4","article-title":"Synergistic effects and flame-retardant mechanism of aluminum diethyl phosphinate in combination with melamine polyphosphate and aluminum oxide in epoxy resin","volume":"134","author":"Zhong","year":"2018","journal-title":"J. Therm. Anal. Calorim."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1002\/sus2.73","article-title":"Recent advances in fire-retardant carbon-based polymeric nanocomposites through fighting free radicals","volume":"2","author":"Sai","year":"2022","journal-title":"SusMat"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"2529","DOI":"10.1039\/C9TA11021F","article-title":"Wang, Bioinspired iron-loaded polydopamine nanospheres as green flame retardants for epoxy resin via free radical scavenging and catalytic charring","volume":"8","author":"Zhang","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1002\/pat.5073","article-title":"Phosphorylated cellulose\/Fe3+ complex: A novel flame retardant for epoxy resins","volume":"32","author":"Shi","year":"2020","journal-title":"Polym. Advan. Technol."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"12966","DOI":"10.1039\/C8CC06524A","article-title":"Ambient NH3 synthesis via electrochemical reduction of N2 over cubic sub-micron SnO2 particles","volume":"54","author":"Zhang","year":"2018","journal-title":"Chem. Commun."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.compositesa.2017.04.012","article-title":"Dual modification of graphene by polymeric flame retardant and Ni(OH)2 nanosheets for improving flame retardancy of polypropylene","volume":"100","author":"Yuan","year":"2017","journal-title":"Compos Part A-Appl. S."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Wang, L.C., Tawiah, B., Shi, Y.Q., Cai, S.C., Rao, X.H., Liu, C., Yang, Y., Yang, F.Q., Yu, B., and Liang, Y.T. (2019). Highly effective flame-retardant rigid polyurethane foams: Fabrication and applications in inhibition of coal combustion. Polymers, 11.","DOI":"10.3390\/polym11111776"},{"key":"ref_51","doi-asserted-by":"crossref","unstructured":"Chi, C., He, S.Y., Peng, C.H., Zeng, B.R., Xia, L., Miao, Z.X., Xu, H., Wang, S.C., Chen, G.R., and Dai, L.Z. (2023). LDH@boronate polymer core\u2013Shell nanoparticles: Nanostructure design for synergistically enhancing the flame retardancy of epoxy resin. Polymers, 15.","DOI":"10.3390\/polym15092198"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1002\/pat.4809","article-title":"Effect of different ionic layered compounds decorated with zinc hydroxystannate on flame retardancy and smoke performance of epoxy resin","volume":"31","author":"Xu","year":"2020","journal-title":"Polym. Advan. Technol."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"17919","DOI":"10.1021\/acsami.5b04570","article-title":"Novel multifunctional organic\u2013inorganic hybrid curing agent with high flame-retardant efficiency for epoxy resin","volume":"7","author":"Tan","year":"2015","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_54","doi-asserted-by":"crossref","unstructured":"Han, X., Zhang, X., Guo, Y., Liu, X., Zhao, X., Zhou, H., Zhang, S., and Zhao, T. (2021). Synergistic effects of ladder and cage structured phosphorus-containing POSS with tetrabutyl titanate on flame retardancy of vinyl epoxy resins. Polymers, 13.","DOI":"10.3390\/polym13091363"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"110132","DOI":"10.1016\/j.polymdegradstab.2022.110132","article-title":"A universal strategy toward flame retardant epoxy resin with ultra-tough and transparent properties","volume":"205","author":"Chen","year":"2022","journal-title":"Polym. Degrad. Stab."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5354\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:11:08Z","timestamp":1760127068000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5354"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,7,12]]},"references-count":55,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2023,7]]}},"alternative-id":["molecules28145354"],"URL":"https:\/\/doi.org\/10.3390\/molecules28145354","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,7,12]]}}}