{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T02:53:51Z","timestamp":1790823231797,"version":"4.1.0"},"reference-count":53,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2023,7,14]],"date-time":"2023-07-14T00:00:00Z","timestamp":1689292800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Natural Science Foundation of China","award":["22102068"],"award-info":[{"award-number":["22102068"]}]},{"name":"National Natural Science Foundation of China","award":["22105093"],"award-info":[{"award-number":["22105093"]}]},{"name":"National Natural Science Foundation of China","award":["232300421083"],"award-info":[{"award-number":["232300421083"]}]},{"name":"National Natural Science Foundation of China","award":["22A150016"],"award-info":[{"award-number":["22A150016"]}]},{"name":"National Natural Science Foundation of China","award":["212102210574"],"award-info":[{"award-number":["212102210574"]}]},{"name":"Natural Science Foundation for Excellent Young Scholars of Henan Province","award":["22102068"],"award-info":[{"award-number":["22102068"]}]},{"name":"Natural Science Foundation for Excellent Young Scholars of Henan Province","award":["22105093"],"award-info":[{"award-number":["22105093"]}]},{"name":"Natural Science Foundation for Excellent Young Scholars of Henan Province","award":["232300421083"],"award-info":[{"award-number":["232300421083"]}]},{"name":"Natural Science Foundation for Excellent Young Scholars of Henan Province","award":["22A150016"],"award-info":[{"award-number":["22A150016"]}]},{"name":"Natural Science Foundation for Excellent Young Scholars of Henan Province","award":["212102210574"],"award-info":[{"award-number":["212102210574"]}]},{"name":"Key Scientific Research Projects of Higher Education of Henan Province","award":["22102068"],"award-info":[{"award-number":["22102068"]}]},{"name":"Key Scientific Research Projects of Higher Education of Henan Province","award":["22105093"],"award-info":[{"award-number":["22105093"]}]},{"name":"Key Scientific Research Projects of Higher Education of Henan Province","award":["232300421083"],"award-info":[{"award-number":["232300421083"]}]},{"name":"Key Scientific Research Projects of Higher Education of Henan Province","award":["22A150016"],"award-info":[{"award-number":["22A150016"]}]},{"name":"Key Scientific Research Projects of Higher Education of Henan Province","award":["212102210574"],"award-info":[{"award-number":["212102210574"]}]},{"name":"Key Science and Technology Program of Henan Province","award":["22102068"],"award-info":[{"award-number":["22102068"]}]},{"name":"Key Science and Technology Program of Henan Province","award":["22105093"],"award-info":[{"award-number":["22105093"]}]},{"name":"Key Science and Technology Program of Henan Province","award":["232300421083"],"award-info":[{"award-number":["232300421083"]}]},{"name":"Key Science and Technology Program of Henan Province","award":["22A150016"],"award-info":[{"award-number":["22A150016"]}]},{"name":"Key Science and Technology Program of Henan Province","award":["212102210574"],"award-info":[{"award-number":["212102210574"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The organic dyes used in printing and dyeing wastewater have complex components, diverse structures and strong chemical stability, which make them not suitable for treatment and difficult to degrade in the environment. Porphyrins are macromolecules with 18 \u03c0 electrons formed by four pyrrole molecules connected with a methylene bridge that has a stable structure. Porphyrin combines with iron to form an active intermediate with a structure similar to the cytochrome P450 enzyme, so they are widely used in the biomimetic field. In the current study, 5,10,15,20-tetra (4-carboxyphenyl) porphine ferric chloride (III) (Fe(III)TCPP) was used as a catalyst and iodosobenzene was used as an oxidant to explore the catalytic degradation of triphenylmethane dyes, such as rhodamine B (RhB) and malachite green (MG). The results of UV-Vis spectral analysis have shown that the conversion rate of the rhodamine B was over 90% when the amount of Fe(III)TCPP was 0.027 mM and the amount of iodosobenzene was eight equivalents. When the catalyst was 0.00681 mM and the amount of the oxidant was five equivalents, the conversion rate of the malachite green reached over 95%. This work provides a feasible method for the degradation of triphenylmethane dyes.<\/jats:p>","DOI":"10.3390\/molecules28145401","type":"journal-article","created":{"date-parts":[[2023,7,14]],"date-time":"2023-07-14T08:40:06Z","timestamp":1689324006000},"page":"5401","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Catalytic Degradation of Triphenylmethane Dyes with an Iron Porphyrin Complex as a Cytochrome P450 Model"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5710-4968","authenticated-orcid":false,"given":"Xiaoyan","family":"Lu","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiman","family":"Che","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinkai","family":"Niu","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"},{"name":"Xinjiang Production & Construction Corps Key Laboratory of Advanced Energy Storage Materials and Technology, College of Science, Shihezi University, Shihezi 832003, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2019e","family":"Chen","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Han","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miaoqing","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihong","family":"Lan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Engineering, Xinxiang University, Xinxiang 453003, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,14]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"101694","DOI":"10.1016\/j.eti.2021.101694","article-title":"Surfactants assisted SiO2-Cu@Fe2O3 nanofibers: Ultra efficient photocatalyst for photodegradation of organic compounds and transesterification of waste edible oil to biodiesel","volume":"23","author":"Haq","year":"2021","journal-title":"Environ. Technol. Innov."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"368","DOI":"10.1016\/j.carbpol.2018.04.112","article-title":"Fabrication of a new polysaccharide-based adsorbent for water purification","volume":"195","author":"Qi","year":"2018","journal-title":"Carbohydr. Polym."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"66","DOI":"10.4236\/jbnb.2017.81005","article-title":"Photocatalytic Degradation of Rhodamine B Dye in Wastewater Using Gelatin\/CuS\/PVA Nanocomposites under Solar Light Irradiation","volume":"8","year":"2017","journal-title":"J. Biomater. Nanobiotechnol."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"2313","DOI":"10.1016\/j.jenvman.2008.11.017","article-title":"Application of low-cost adsorbents for dye removal\u2014A review","volume":"90","author":"Gupta","year":"2009","journal-title":"J. Environ. Manag."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1016\/j.foodcont.2012.02.001","article-title":"Malachite green residues in farmed fish in Croatia","volume":"26","author":"Varenina","year":"2012","journal-title":"Food Control"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1016\/j.foodcont.2013.11.045","article-title":"Determination of malachite green residues in farmed rainbow trout in Iran","volume":"40","author":"Fallah","year":"2014","journal-title":"Food Control"},{"key":"ref_7","first-page":"10","article-title":"Impact of wastewater on surface water quality in developing countries: A case study of South Africa","volume":"10","author":"Edokpayi","year":"2017","journal-title":"Water Qual."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1002\/(SICI)1097-4660(199808)72:4<289::AID-JCTB905>3.0.CO;2-#","article-title":"Review: Treatment and Reuse of Wastewater from the Textile Wet-processing Industry: Review of Emerging Wastewater from the Textile Wet-processing Industry: Review of Emerging Technologies","volume":"72","author":"Vandevivere","year":"1998","journal-title":"Technol. J. Chem. Technol. Biotechnol."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/S1010-6030(01)00435-X","article-title":"Photochemical and Photocatalytic Degradation of an Indigoid Dye: A Case Study of Acid Blue 74 (AB74)","volume":"141","author":"Galindo","year":"2001","journal-title":"J. Photochem. Photobiol. A"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1016\/S0043-1354(96)00258-8","article-title":"Decontamination of Water Using Adsorption and Photocatalytic","volume":"31","author":"Crittenden","year":"1997","journal-title":"Water Res."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"854","DOI":"10.1016\/j.jcis.2022.09.020","article-title":"Enhanced photoactivity and selectivity over BiOI-decorated Bi2WO6 microflower for selective oxidation of benzylamine: Role of BiOI and mechanism","volume":"629","author":"Tantraviwat","year":"2023","journal-title":"J. Colloid Interface Sci."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"e202300140","DOI":"10.1002\/cnma.202300140","article-title":"Bismuth\u2013based oxide photocatalysts for selective oxidation transformations of organic compounds","volume":"9","author":"Boochakiat","year":"2023","journal-title":"ChemNanoMat"},{"key":"ref_13","first-page":"270","article-title":"Photocatalytic degradation of Rhodamine B dye with TiO2 immobilized on SiC foam using full factorial design","volume":"10","author":"Fanou","year":"2020","journal-title":"Appl. Water Sci."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"105580","DOI":"10.1016\/j.jece.2021.105580","article-title":"Photocatalytic degradation of malachite green and methylene blue over reduced graphene oxide (rGO) based metal oxides (rGO-Fe3O4\/TiO2) nanocomposite under UV-visible light irradiation","volume":"9","author":"Bibi","year":"2021","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Lu, X., Wang, S., and Qin, J.-H. (2022). Isolating Fe-O2 intermediates in dioxygen activation by iron porphyrin complexes. Molecules, 27.","DOI":"10.3390\/molecules27154690"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1016\/j.jphotochemrev.2005.12.001","article-title":"Antimony porphyrin complexes as visible-light driven photocatalyst","volume":"6","author":"Shiragami","year":"2005","journal-title":"J. Photochem. Photobiol. C"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.ccr.2017.06.008","article-title":"Design and applications of molecular probes containing porphyrin derivatives","volume":"354","author":"Lee","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_18","first-page":"105","article-title":"Manganese porphines-NH2@SBA-15 as heterogeneous catalytic systems with homogeneous behavior: Effect of length of linker in immobilized manganese porphine catalysts in oxidation of olefins","volume":"423","author":"Rayati","year":"2016","journal-title":"J. Mater. Chem. A"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"7551","DOI":"10.1039\/C7NR00758B","article-title":"Charge stabilizing tris(triphenylamine)-zinc porphyrin-carbon nanotube hybrids: Synthesis, characterization and excited state charge transfer studies","volume":"9","author":"Arellano","year":"2017","journal-title":"Nanoscale"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"17772","DOI":"10.1039\/D0DT03031G","article-title":"Ionic liquid induced highly dense assembly of porphyrin in MOF nanosheets for photodynamic therapy","volume":"49","author":"Qin","year":"2020","journal-title":"Dalton. Trans."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"8468","DOI":"10.1039\/D1CC02847B","article-title":"High loading of Mn(ii)-metalated porphyrin in a MOF for photocatalytic CO2 reduction in gas-solid conditions","volume":"57","author":"Qin","year":"2021","journal-title":"Chem. Commun."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"13234","DOI":"10.1021\/acs.inorgchem.2c01517","article-title":"Anionic Porous Zn-Metalated Porphyrin Metal-Organic Framework with PtS Topology for Gas-Phase Photocatalytic CO2 Reduction","volume":"61","author":"Qin","year":"2022","journal-title":"Inorg. Chem."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"5130","DOI":"10.1039\/D2SC00437B","article-title":"Highly selective synthesis and near-infrared photothermal conversion of metalla-Borromean ring and [2]catenane assemblies","volume":"13","author":"Dang","year":"2022","journal-title":"Chem. Sci."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"e202301516","DOI":"10.1002\/anie.202301516","article-title":"Selective Synthesis and Structural Transformation of a 4-Ravel Containing Four Crossings and Featuring Cp*Rh\/Ir Fragments","volume":"62","author":"Dang","year":"2023","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"102247","DOI":"10.1016\/j.surfin.2022.102247","article-title":"Silver nanoparticle-decorated 2D Co-TCPP MOF nanosheets for synergistic photodynamic and silver ion antibacterial","volume":"33","author":"Li","year":"2022","journal-title":"Surf. Interfaces"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1684","DOI":"10.1039\/D2QM01333A","article-title":"Facile synthesis of 2D Al-TCPP MOF nanosheets for efficient sonodynamic cancer therapy","volume":"7","author":"Zhou","year":"2023","journal-title":"Mater. Chem. Front."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1021\/ar700027f","article-title":"High-valent iron (IV)\u2013oxo complexes of heme and non-heme ligands in oxygenation reactions","volume":"40","author":"Nam","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1016\/j.jphotochem.2015.03.014","article-title":"Comparative studies of various iron-mediated oxidative systems for the photochemical degradation of endosulfan in aqueous solution","volume":"306","author":"Shah","year":"2015","journal-title":"J. Photochem. Photobiol. A"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"617","DOI":"10.1039\/a707552i","article-title":"Mechamism of oxidation of azo dyes by a sterically hindered anionic oxoiron(IV) porphyrin in aqueous solution","volume":"2","author":"Hodges","year":"1998","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1186\/1752-153X-6-161","article-title":"Degradation of textile dyes using immobilized lignin peroxidase-like metalloporphines under mild experimental conditions","volume":"6","author":"Zucca","year":"2012","journal-title":"Chem. Cent. J."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1943","DOI":"10.1039\/a902331c","article-title":"The oxidation of azo dyes by peroxy acids and tert-butyl hydroperoxide in aqueous solution catalysed by iron(III) 5,10,15,20-tetra (2,6-dichloro-3-sulfonatophenyl) porphyrin: Product studies and mechanism","volume":"2","author":"Hodges","year":"1999","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2243","DOI":"10.1016\/j.ica.2007.09.048","article-title":"Metalloporphyrin catalyzed oxidation of methyl yellow and related azo compounds","volume":"361","author":"Emmert","year":"2008","journal-title":"Inorg. Chim. Acta."},{"key":"ref_33","first-page":"830","article-title":"Iron porphyrins as biomimetical models for disperse azo dye oxidation","volume":"24","author":"Barros","year":"2013","journal-title":"J. Braz. Chem. Soc."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"796","DOI":"10.1002\/cctc.201200475","article-title":"Efficient oxidative degradation of azo dyes by a water-soluble manganese porphyrin catalyst","volume":"5","author":"Saha","year":"2013","journal-title":"ChemCatChem"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1346","DOI":"10.1021\/acsnano.1c09301","article-title":"Porphyrin-based two-dimensional layered metal\u2013organic framework with sono-\/photocatalytic activity for water decontamination","volume":"16","author":"Zhu","year":"2021","journal-title":"ACS Nano"},{"key":"ref_36","doi-asserted-by":"crossref","unstructured":"Shee, N.K., and Kim, H.J. (2022). Sn (IV)-Porphyrin-Based Nanostructures Featuring Pd (II)-Mediated Supramolecular Arrays and Their Photocatalytic Degradation of Acid Orange 7 Dye. Int. J. Mol. Sci., 23.","DOI":"10.3390\/ijms232213702"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"3812","DOI":"10.1021\/ja00246a067","article-title":"Olefin epoxidation by manganese (IV) porphyrins: Evidence for two reaction pathways","volume":"109","author":"Groves","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"2067","DOI":"10.1002\/1521-3765(20020503)8:9<2067::AID-CHEM2067>3.0.CO;2-V","article-title":"Isolation of an oxomanganese(V) porphyrin intermediate in the reaction of a manganese (III) porphyrin complex and H2O2 in aqueous solution","volume":"8","author":"Nam","year":"2002","journal-title":"Chem. Eur. J."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"699","DOI":"10.1002\/anie.201005128","article-title":"Chlorite dismutation to chlorine dioxide catalyzed by a water-soluble manganese porphyrin","volume":"50","author":"Hicks","year":"2011","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"8628","DOI":"10.1021\/ja00234a009","article-title":"Synthesis, characterization, and reactivity of oxomanganese(IV) porphyrin complexes","volume":"110","author":"Groves","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"4","DOI":"10.1016\/j.abb.2010.12.035","article-title":"Manganese substituted Compound I of cytochrome P450 biomimetics: A comparative reactivity study of MnV-oxo versus MnIV-oxo species","volume":"507","author":"Latifi","year":"2011","journal-title":"Arch. Biochem. Biophys."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"695","DOI":"10.1002\/anie.201004482","article-title":"Catalytic generation of chlorine dioxide from chlorite using a water-soluble manganese porphyrin","volume":"50","author":"Umile","year":"2011","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"10353","DOI":"10.1021\/ic201430v","article-title":"Dissection of the mechanism of manganese porphyrin-catalyzed chlorine dioxide generation","volume":"50","author":"Umile","year":"2011","journal-title":"Inorg. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"11482","DOI":"10.1002\/chem.200901362","article-title":"Hydrogen-atom abstraction reactions by Manganese (V)-and Manganese (IV)-oxo porphyrin complexes in aqueous solution","volume":"15","author":"Arunkumar","year":"2009","journal-title":"Chem. Eur. J."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"611","DOI":"10.1021\/ja00236a065","article-title":"Detection of high-valent intermediates in the chlorine (I) oxidation of (porphinato) manganese(III) complexes","volume":"109","author":"Rodgers","year":"1987","journal-title":"J. Am. Chem. Soc."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"956","DOI":"10.1177\/004051759906901212","article-title":"Decoloration of azo dyes by hydrogen peroxide catalyzed by water-soluble manganese porphyrins","volume":"69","author":"Tokuda","year":"1999","journal-title":"Text. Res. J."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.1177\/0040517507087682","article-title":"Peroxide decoloration of azo dye catalyzed by manganese porphyrin derivatives in nonaqueous solvent","volume":"78","author":"Nakamura","year":"2008","journal-title":"Text. Res. J."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"3272","DOI":"10.1021\/la970644t","article-title":"Peroxide decoloration of azo dyes catalyzed by polyethylene glycol-linked manganese halogenated porphyrins","volume":"14","author":"Nango","year":"1998","journal-title":"Langmuir"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"2870","DOI":"10.1002\/ejic.202100373","article-title":"Oxidative degradation of azo dyes in aqueous solution by water-soluble Iron porphyrin catalyst","volume":"2021","author":"Saha","year":"2021","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Ren, D.-D., Lu, X., Zhou, L.-P., Tian, H., Wang, S., Ma, L.-F., and Li, D.-S. (2022). Iron Porphyrin as a Cytochrome P450 Model for the Degradation of Dye. Molecules, 27.","DOI":"10.3390\/molecules27227948"},{"key":"ref_51","first-page":"100381","article-title":"Investigation on antibacterial and photocatalytic degradation of Rhodamine-B dye under visible light irradiation by titanium molybdate nanoparticles prepared via microwave method","volume":"23","author":"Mobeen","year":"2021","journal-title":"Surf. Interfaces"},{"key":"ref_52","first-page":"26","article-title":"Hemin Based Biomimetic Oxidative Degradation of Acid Orange 7","volume":"4","author":"Yan","year":"2016","journal-title":"J. Mater. Sci. Chem. Eng."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"7707","DOI":"10.1021\/ja010968a","article-title":"Copper-catalyzed nitrogen transfer mediated by iodosylbenzene PhI=O","volume":"123","author":"Dauban","year":"2001","journal-title":"J. Am. Chem. Soc."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5401\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:11:55Z","timestamp":1760127115000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5401"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,7,14]]},"references-count":53,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2023,7]]}},"alternative-id":["molecules28145401"],"URL":"https:\/\/doi.org\/10.3390\/molecules28145401","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,7,14]]}}}