{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T10:51:51Z","timestamp":1781520711917,"version":"3.54.1"},"reference-count":57,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2023,7,22]],"date-time":"2023-07-22T00:00:00Z","timestamp":1689984000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22173053"],"award-info":[{"award-number":["22173053"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["20210302123439"],"award-info":[{"award-number":["20210302123439"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004480","name":"Natural Science Foundation of Shanxi Province","doi-asserted-by":"publisher","award":["22173053"],"award-info":[{"award-number":["22173053"]}],"id":[{"id":"10.13039\/501100004480","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004480","name":"Natural Science Foundation of Shanxi Province","doi-asserted-by":"publisher","award":["20210302123439"],"award-info":[{"award-number":["20210302123439"]}],"id":[{"id":"10.13039\/501100004480","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>As one of the important probes of chemical bonding, planar tetracoordinate carbon (ptC) compounds have been receiving much attention. Compared with ptC clusters, the heavier planar tetracoordinate silicon, germanium, tin, lead (ptSi\/Ge\/Sn\/Pb) systems are scarcer and more exotic. The 18-valence-electron (ve)-counting is one important guide, though not the only rule, for the design of planar tetra-, penta-coordinate carbon and silicon clusters. The 18ve ptSi\/Ge system is very scarce and needs to be expanded. Based on the isoelectronic principle and bonding similarity between the Al atom and the BeH unit, inspired by the previously reported ptSi global minimum (GM) SiAl42\u2212, a series of ternary 18 ve XBe4H5\u2212 (X = Si, Ge, Sn, Pb) clusters were predicted with the ptSi\/Ge\/Sn\/Pb centers. Extensive density functional theory (DFT) global minimum searches and high-level CCSD(T) calculations performed herein indicated that these ptSi\/Ge\/Sn\/Pb XBe4H5\u2212 (X = Si, Ge, Sn, Pb) clusters were all true GMs on their potential energy surfaces. These GMs of XBe4H5\u2212 (X = Si, Ge, Sn, Pb) species possessed the beautiful fan-shaped structures: XBe4 unit can be stabilized by three peripheries bridging H and two terminal H atoms. It should be noted that XBe4H5\u2212 (X = Si, Ge, Sn, Pb) were the first ternary 18 ve ptSi\/Ge\/Sn\/Pb species. The natural bond orbital (NBO), canonical molecular orbitals (CMOs) and adaptive natural densitpartitioning (AdNDP) analyses indicated that 18ve are ideal for these ptX clusters: delocalized one \u03c0 and three \u03c3 bonds for the XBe4 core, three Be-H-Be 3c-2e and two Be-H \u03c3 bonds for the periphery. Additionally, 2\u03c0 plus 6\u03c3 double aromaticity was found to be crucial for the stability of the ptX XBe4H5\u2212 (X = Si, Ge, Sn, Pb) clusters. The simulated photoelectron spectra of XBe4H5\u2212 (X = Si, Ge, Sn, Pb) clusters will provide theoretical basis for further experimental characterization.<\/jats:p>","DOI":"10.3390\/molecules28145583","type":"journal-article","created":{"date-parts":[[2023,7,24]],"date-time":"2023-07-24T01:15:45Z","timestamp":1690161345000},"page":"5583","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Ternary XBe4H5\u2212 (X = Si, Ge, Sn, Pb) Clusters: Planar Tetracoordinate Si\/Ge\/Sn\/Pb Species with 18 Valence Electrons"],"prefix":"10.3390","volume":"28","author":[{"given":"Yong-Xia","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li-Xia","family":"Bai","sequence":"additional","affiliation":[{"name":"Nanocluster Laboratory Institute, Molecular Science Shanxi University, Taiyuan 030006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4773-5541","authenticated-orcid":false,"given":"Jin-Chang","family":"Guo","sequence":"additional","affiliation":[{"name":"Nanocluster Laboratory Institute, Molecular Science Shanxi University, Taiyuan 030006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Monkhorst, H.J. (1968). Activation energy for interconversion of enantiomers containing an asymmetric carbon atom without breaking bonds. Chem. Commun., 1111\u20131112.","DOI":"10.1039\/c19680001111"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"4992","DOI":"10.1021\/ja00719a044","article-title":"Planar tetracoordinate carbon","volume":"92","author":"Hoffmann","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"5419","DOI":"10.1021\/ja00434a001","article-title":"Stabilization of planar tetracoordinate carbon","volume":"98","author":"Collins","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"7886","DOI":"10.1021\/ja00466a021","article-title":"The probable existence of a triple bond between two vanadium atoms","volume":"99","author":"Cotton","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1016\/0166-1280(95)04233-V","article-title":"Planar and inherently non-tetrahedral tetracoordinate carbon: A status report","volume":"338","author":"Sorger","year":"1995","journal-title":"J. Mol. Struct. (Theochem)"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1039\/a708611c","article-title":"Using bent metallocenes for stabilizing unusual coordination geometries at carbon","volume":"28","author":"Erker","year":"1999","journal-title":"Chem. Soc. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"367","DOI":"10.1039\/a801225c","article-title":"Compounds containing a planar-tetracoordinate carbon atom as analogues of planar methane","volume":"28","author":"Siebert","year":"1999","journal-title":"Chem. Soc. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"4787","DOI":"10.1021\/cr050545h","article-title":"Carbon flatland:\u2009 Planar tetracoordinate carbon and fenestranes","volume":"106","author":"Keese","year":"2006","journal-title":"Chem. Rev."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1002\/jcc.20515","article-title":"Recent advances in planar tetracoordinate carbon chemistry","volume":"28","author":"Merino","year":"2007","journal-title":"J. Comput. Chem."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"9468","DOI":"10.1002\/anie.201410407","article-title":"Four decades of the chemistry of planar hypercoordinate compounds","volume":"54","author":"Yang","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"0114","DOI":"10.1038\/s41570-018-0114","article-title":"Planar pentacoordinate carbons","volume":"2","author":"Pan","year":"2018","journal-title":"Nat. Rev. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1723","DOI":"10.3390\/chemistry4040113","article-title":"Structure and bonding in planar hypercoordinate carbon compounds","volume":"4","author":"Das","year":"2022","journal-title":"Chemistry"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"887","DOI":"10.1021\/acs.accounts.0c00025","article-title":"Planar hypercoordinate motifs in two-dimensional materials","volume":"53","author":"Wang","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"6033","DOI":"10.1021\/ja9906204","article-title":"Tetracoordinated planar carbon in the Al4C\u2212 anion. A combined photoelectron spectroscopy and ab initio study","volume":"121","author":"Li","year":"1999","journal-title":"J. Am. Chem. Soc."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3630","DOI":"10.1002\/1521-3773(20001016)39:20<3630::AID-ANIE3630>3.0.CO;2-R","article-title":"Pentaatomic tetracoordinate planar carbon, [CAl4]2\u2212: A new structural unit and its salt complexes","volume":"39","author":"Li","year":"2000","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"7681","DOI":"10.1021\/ja993081b","article-title":"Experimental observation of pentaatomic tetracoordinate planar carbon-containing molecules","volume":"122","author":"Wang","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1536","DOI":"10.1039\/C39910001536","article-title":"A new, general strategy for achieving planar tetracoordinate geometries for carbon and other second row periodic elements","volume":"21","author":"Schleyer","year":"1991","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2326","DOI":"10.1021\/jp5065819","article-title":"Additive covalent radii for single-, double-, and triple-bonded molecules and tetrahedrally bonded crystals: A summary","volume":"119","year":"2015","journal-title":"J. Phys. Chem. A"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"513","DOI":"10.3103\/S1067821214060121","article-title":"Thermodynamic simulation of silicon and iron reduction and zinc and lead distillation in zincoligonite ore\u2013carbon systems","volume":"55","author":"Kolesnikov","year":"2014","journal-title":"Russ. J. Non-Ferr. Met."},{"key":"ref_20","doi-asserted-by":"crossref","unstructured":"(2020). Thermodynamic modeling of chemical and phase transformations in a waelz process-slag-carbon system. Refract. Ind. Ceram., 61, 289\u2013292.","DOI":"10.1007\/s11148-020-00474-4"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3307","DOI":"10.1002\/1521-3773(20000915)39:18<3307::AID-ANIE3307>3.0.CO;2-#","article-title":"Experimental Observation of Pentaatomic Tetracoordinate Planar Si- and Ge-Containing Molecules: MAl4- and MAl4","volume":"39","author":"Boldyrev","year":"2000","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"16227","DOI":"10.1021\/ja045303y","article-title":"Planar tetra-, penta-, hexa-, hepta-, and octacoordinate silicons: A universal structural pattern","volume":"126","author":"Li","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1136","DOI":"10.1021\/ja028786j","article-title":"Hydrometal analogues of aromatic hydrocarbons: A new class of cyclic hydrocoppers(I)","volume":"125","author":"Tsipis","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1016\/j.theochem.2007.03.040","article-title":"Planar tetra-coordinate Si and Ge in perfectly squared Ni4Cl4X complexes","volume":"816","author":"Guo","year":"2007","journal-title":"J. Mol. Struct. THEOCHEM"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"7594","DOI":"10.1021\/jp0530000","article-title":"M5H5X (M = Ag, Au, Pd, Pt; X = Si, Ge, P, S): Hydrometal pentagons with D5h planar pentacoordinate nonmetal centers","volume":"109","author":"Li","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"6331","DOI":"10.1021\/ic049623u","article-title":"Hexacoordinate planar main group atoms centered in hexagonal hydrocopper complexes Cu6H6X (X = Si, P, As)","volume":"43","author":"Li","year":"2004","journal-title":"Inorg. Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1327","DOI":"10.1016\/j.jmgm.2008.01.003","article-title":"Structural, electronic, and magnetic properties of heterofullerene C58Si with odd number of atoms and a near planar tetracoordinate Si atom","volume":"26","author":"Liu","year":"2008","journal-title":"J. Mol. Graph. Model."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"4582","DOI":"10.1021\/jp056829n","article-title":"Planar tetracoordinated silicon in silicon carbonyl complexes: A DFT approach","volume":"110","author":"Belanzoni","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"14815","DOI":"10.1039\/c2cp41821e","article-title":"Selected AB42\u2212\/\u2212 (A = C, Si, Ge; B = Al, Ga, In) ions: A battle between covalency and aromaticity, and prediction of square planar Si in SiIn42\u2212\/\u2212","volume":"14","author":"Alexandrova","year":"2012","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1002\/jcc.23792","article-title":"Pentaatomic planar tetracoordinate silicon with 14 valence electrons: A large-scale global search of SiXnYmq(n +m = 4; q = 0, \u00b11, \u22122; X, Y = Main Group Elements From H to Br)","volume":"36","author":"Xu","year":"2015","journal-title":"J. Comput. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.comptc.2016.03.007","article-title":"D3h X3Li3+ (X = C, Si and Ge): Superalkali cations containing three planar tetracoordinate X atoms","volume":"1083","author":"Guo","year":"2016","journal-title":"Comput. Theor. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.comptc.2014.01.020","article-title":"Planar tetracoordinate Si and Ge in \u03c0-aromatic X3Cu3+ (X = Si, Ge) cations","volume":"1032","author":"Guo","year":"2014","journal-title":"Comput. Theor. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1039\/C5DT03989D","article-title":"A template for a planar tetracoordinate heavier group 14 atom: A global study of C2Si2Xq.(X = C, Si, Ge, Sn, Pb; q = +1, 0, \u22121)","volume":"45","author":"Sui","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"7068","DOI":"10.1039\/D1CP05226H","article-title":"Ternary 14-electron XB2Be2 (X = Si, Ge, Sn, Pb) clusters: A planar tetracoordinate silicon (ptSi) system and its ptGe\/Sn\/Pb congeners","volume":"24","author":"Zhao","year":"2022","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"13772","DOI":"10.1039\/D0CC06107G","article-title":"Planar pentacoordinate silicon and germanium atoms","volume":"56","author":"Wang","year":"2020","journal-title":"Chem. Commun."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"8045","DOI":"10.1039\/D2SC01761J","article-title":"Bare and ligand protected planar hexacoordinate silicon in SiSb3M3+ (M = Ca, Sr, Ba) clusters","volume":"13","author":"Chen","year":"2022","journal-title":"Chem. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"900","DOI":"10.1021\/ja107711m","article-title":"SiC2 silagraphene and its one-dimensional derivatives: Where planar tetracoordinate silicon happens","volume":"133","author":"Li","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"17409","DOI":"10.1021\/jacs.8b11137","article-title":"Calix[4]pyrrole hydridosilicate: The elusive planar tetracoordinate silicon imparts striking stability to its anionic silicon hydride","volume":"140","author":"Ebner","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"9920","DOI":"10.1021\/jacs.0c03874","article-title":"An isolable tetrasilicon analogue of a planar bicyclo[1.1.0]butane with \u03c0-type single-bonding character","volume":"142","author":"Nukazawa","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2151","DOI":"10.1016\/j.chempr.2021.05.002","article-title":"An isolable, crystalline complex of squareplanar silicon(IV)","volume":"7","author":"Ebner","year":"2021","journal-title":"Chem"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"420","DOI":"10.1021\/jacs.0c11628","article-title":"Planar tetracoordinated silicon (ptSi): Room-temperature stable compounds containing anti-van\u2019t Hoff\/Le Bel silicon","volume":"143","author":"Ghana","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"7084","DOI":"10.1021\/jacs.3c00722","article-title":"Synthesis and reactivity of an anti-van\u2019t Hoff\/Le Bel compound with a planar tetracoordinate silicon(II) atom","volume":"145","author":"Shan","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"621","DOI":"10.1002\/jcc.10407","article-title":"Stochastic search for isomers on a quantum mechanical surface","volume":"25","author":"Saunders","year":"2004","journal-title":"J. Comput. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"224304","DOI":"10.1063\/1.3599452","article-title":"All-boron analogues of aromatic hydrocarbons: B17\u2212 and B18\u2212","volume":"134","author":"Sergeeva","year":"2011","journal-title":"J. Chem. Phys."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"6158","DOI":"10.1063\/1.478522","article-title":"Toward reliable density functional methods without adjustable parameters: The PBE0 model","volume":"110","author":"Adamo","year":"1999","journal-title":"J. Chem. Phys."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1039\/b508541a","article-title":"Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"5968","DOI":"10.1063\/1.453520","article-title":"Quadratic configuration interaction. A general technique for determining electron correlation energies","volume":"87","author":"Pople","year":"1987","journal-title":"J. Chem. Phys."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1429","DOI":"10.1002\/jcc.23266","article-title":"NBO 6.0: Natural bond orbital analysis program","volume":"34","author":"Glendening","year":"2013","journal-title":"J. Comput. Chem."},{"key":"ref_49","unstructured":"Glendening, E.D., Badenhoop, J.K., Reed, A.E., Carpenter, J.E., Bohmann, J.A., Morales, C.M., Landis, C.R., and Weinhold, F. (2013). NBO 6.0, Theoretical Chemistry Institute, University of Wisconsin."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"6317","DOI":"10.1021\/ja960582d","article-title":"Nucleus-Independent Chemical Shifts:\u2009 A Simple and Efficient Aromaticity Probe","volume":"118","author":"Schleyer","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"ref_51","unstructured":"Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Mennucci, B., and Petersson, G.A. (2016). Gaussian 16, Revision C.01, Gaussian, Inc."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"5207","DOI":"10.1039\/b804083d","article-title":"Developing paradigms of chemical bonding: Adaptive natural density partitioning","volume":"10","author":"Zubarev","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","article-title":"Multiwfn: A multifunctional wavefunction analyzer","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"ref_54","unstructured":"Legault, C.Y. (2009). CYLview, 1.0b., Universite. de Sherbrooke. Available online: http:\/\/www.cylview.org."},{"key":"ref_55","unstructured":"Varetto, U. (2009). Molekel, Version 5.4.0.8, Swiss National Supercomputing Centre."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"13101","DOI":"10.1021\/acs.jpca.5b10178","article-title":"CBe5Hnn\u22124(n = 2\u20135): Hydrogen-stabilized CBe5 pentagons containing planar or quasi-planar pentacoordinate carbons","volume":"119","author":"Guo","year":"2015","journal-title":"J. Phys. Chem. A"},{"key":"ref_57","first-page":"1893","article-title":"Ab initio calculation of the anisotropy effect of multiple bonds and the ring current effect of arenes\u2013 application in conformational and configurational analysis","volume":"2","author":"Kloda","year":"2001","journal-title":"J. Chem. Soc. Perkin Trans."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5583\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:17:17Z","timestamp":1760127437000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/14\/5583"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,7,22]]},"references-count":57,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2023,7]]}},"alternative-id":["molecules28145583"],"URL":"https:\/\/doi.org\/10.3390\/molecules28145583","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,7,22]]}}}