{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T15:13:12Z","timestamp":1761491592204,"version":"build-2065373602"},"reference-count":54,"publisher":"MDPI AG","issue":"15","license":[{"start":{"date-parts":[[2023,7,26]],"date-time":"2023-07-26T00:00:00Z","timestamp":1690329600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The design and manufacture of innovative multifunctional materials possessing superior characteristics, quality and standards, rigorously required for future development of existing or emerging advanced technologies, is of great importance. These materials should have a very low degree of influence (or none) on the environmental and human health. Adjusting the properties of epoxy resins with organophosphorus compounds and silver-containing additives is key to the simultaneous improvement of the flame-resistant and antimicrobial properties of advanced epoxy-based materials. These environmentally friendly epoxy resin nanocomposites were manufactured using two additives, a reactive phosphorus-containing bisphenol derived from vanillin, namely, (4-(((4-hidroxyphenyl)amino)(6-oxido-6H-dibenzo[c,e][1,2]oxaphosphinin-6-yl)methyl)-2-methoxyphenyl) phenylphosphonate (BPH), designed as both cross-linking agent and a flame-retardant additive for epoxy resin; and additional silver-loaded zeolite L nanoparticles (Ze\u2013Ag NPs) used as a doping additive to impart antimicrobial activity. The effect of BPH and Ze\u2013Ag NPs content on the structural, morphological, thermal, flame resistance and antimicrobial characteristics of thermosetting epoxy nanocomposites was investigated. The structure and morphology of epoxy nanocomposites were investigated via FTIR spectroscopy and scanning electron microscopy (SEM). In general, the nanocomposites had a glassy and homogeneous morphology. The samples showed a single glass transition temperature in the range of 166\u2013194 \u00b0C and an initiation decomposition temperature in the range of 332\u2013399 \u00b0C. The introduction of Ze\u2013Ag NPs in a concentration of 7\u201315 wt% provided antimicrobial activity to epoxy thermosets.<\/jats:p>","DOI":"10.3390\/molecules28155650","type":"journal-article","created":{"date-parts":[[2023,7,26]],"date-time":"2023-07-26T01:09:01Z","timestamp":1690333741000},"page":"5650","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Simultaneous Enhancement of Flame Resistance and Antimicrobial Activity in Epoxy Nanocomposites Containing Phosphorus and Silver-Based Additives"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9017-9926","authenticated-orcid":false,"given":"T\u0103chi\u021b\u0103","family":"Vlad-Bubulac","sequence":"first","affiliation":[{"name":"Department of Polycondensation and Thermally Stable Polymers, \u201cPetru Poni\u201d Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9454-4399","authenticated-orcid":false,"given":"Corneliu","family":"Hamciuc","sequence":"additional","affiliation":[{"name":"Department of Polycondensation and Thermally Stable Polymers, \u201cPetru Poni\u201d Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8544-5671","authenticated-orcid":false,"given":"Diana","family":"Serbezeanu","sequence":"additional","affiliation":[{"name":"Department of Polycondensation and Thermally Stable Polymers, \u201cPetru Poni\u201d Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5107-6369","authenticated-orcid":false,"given":"Ana-Maria","family":"Macsim","sequence":"additional","affiliation":[{"name":"Department of Polycondensation and Thermally Stable Polymers, \u201cPetru Poni\u201d Institute of Macromolecular Chemistry, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4541-7446","authenticated-orcid":false,"given":"Gabriela","family":"Lisa","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Faculty of Chemical Engineering and Environmental Protection, \u201cGheorghe Asachi\u201d Technical University of Iasi, 73 Bd. Mangeron, 700050 Iasi, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5397-7638","authenticated-orcid":false,"given":"Ion","family":"Anghel","sequence":"additional","affiliation":[{"name":"Fire Officers Faculty, Police Academy \u201cAlexandru Ioan Cuza\u201d, 3 Morarilor St., Sector 2, 022451 Bucharest, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2497-8148","authenticated-orcid":false,"given":"Dana-Maria","family":"Preda","sequence":"additional","affiliation":[{"name":"Fire Officers Faculty, Police Academy \u201cAlexandru Ioan Cuza\u201d, 3 Morarilor St., Sector 2, 022451 Bucharest, Romania"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4084-8458","authenticated-orcid":false,"given":"Yuri","family":"Kalvachev","sequence":"additional","affiliation":[{"name":"Institute of Catalysis, Bulgarian Academy of Sciences, Acad. G. 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