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A nanocontainer with a hydrophobic inner cavity and hydrophilic outer cavity called \u03b2\u2212cyclodextrin (\u03b2\u2212CD) was grafted onto the surface of hydroxyapatite (HAp) with a silane coupling agent, encapsulating benzotriazole (BTA) and embedded in epoxy resin to improve the coating anticorrosion performance. The excellent corrosion resistance of the coating in immersion and scratch experiments was derived from the inert protective layer formed by the reaction of the rapidly released corrosion inhibitor with the corrosion products on the metal surface. After 30 days of immersion experiment, the coating could still maintain the low\u2212frequency impedance value of 6.28 \u00d7 107 \u03a9 cm2. In this work, the enhancement of the physical barrier function of HAp nanoparticle and the pH\u2212response function conferred by \u03b2\u2212cyclodextrin provided the coating with good passive and active acting abilities in corrosive environments, respectively.<\/jats:p>","DOI":"10.3390\/molecules28176223","type":"journal-article","created":{"date-parts":[[2023,8,24]],"date-time":"2023-08-24T10:47:08Z","timestamp":1692874028000},"page":"6223","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["A High\u2212Performance Anti\u2212Corrosive Epoxy Coating Based on Ultra\u2212Thin Hydroxyapatite Nanosheets with pH\u2212Responsive Functions"],"prefix":"10.3390","volume":"28","author":[{"given":"Chun","family":"Feng","sequence":"first","affiliation":[{"name":"Tubular Goods Research Institute, China National Petroleum Corporation, Xi\u2019an 710077, China"},{"name":"State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, Xi\u2019an 710077, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijuan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Tubular Goods Research Institute, China National Petroleum Corporation, Xi\u2019an 710077, China"},{"name":"State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, Xi\u2019an 710077, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Legang","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuezhi","family":"Hui","sequence":"additional","affiliation":[{"name":"Petrochina Changqing Oilfield Company, China National Petroleum Corporation, Xi\u2019an 710021, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinling","family":"Liu","sequence":"additional","affiliation":[{"name":"Bureau of Geophysical Prospecting Inc., China National Petroleum Corporation, Zhuozhou 072751, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"He","sequence":"additional","affiliation":[{"name":"Tubular Goods Research Institute, China National Petroleum Corporation, Xi\u2019an 710077, China"},{"name":"State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, Xi\u2019an 710077, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofeng","family":"Bai","sequence":"additional","affiliation":[{"name":"Tubular Goods Research Institute, China National Petroleum Corporation, Xi\u2019an 710077, China"},{"name":"State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, Xi\u2019an 710077, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongxue","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,8,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Ma, B., Zhao, H., Ju, D., Yang, Z., Chen, M., and Liu, Q. 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