{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T02:13:57Z","timestamp":1775873637222,"version":"3.50.1"},"reference-count":384,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T00:00:00Z","timestamp":1693180800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012190","name":"Ministry of Science and Higher Education of the Russian Federation","doi-asserted-by":"publisher","award":["075-03-2023-642"],"award-info":[{"award-number":["075-03-2023-642"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The review covers more than a century of decaborane chemistry from the first synthesis by Alfred Stock to the present day. The main attention is paid to the reactions of the substitution of hydrogen atoms by various atoms and groups with the formation of exo-polyhedral boron\u2013halogen, boron\u2013oxygen, boron\u2013sulfur, boron\u2013nitrogen, boron\u2013phosphorus, and boron\u2013carbon bonds. Particular attention is paid to the chemistry of conjucto-borane anti-[B18H22], whose structure is formed by two decaborane moieties with a common edge, the chemistry of which has been intensively developed in the last decade.<\/jats:p>","DOI":"10.3390\/molecules28176287","type":"journal-article","created":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T06:10:22Z","timestamp":1693203022000},"page":"6287","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Decaborane: From Alfred Stock and Rocket Fuel Projects to Nowadays"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5442-367X","authenticated-orcid":false,"given":"Igor B.","family":"Sivaev","sequence":"first","affiliation":[{"name":"A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str., 119334 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,8,28]]},"reference":[{"key":"ref_1","unstructured":"Grimes, R.N. (2016). Carboranes, Academic Press. [3rd ed.]."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1726","DOI":"10.1134\/S0036023619140067","article-title":"Chemistry of carba-closo-decaborate anions [CB9H10]\u2212","volume":"64","author":"Sivaev","year":"2019","journal-title":"Russ. J. Inorg. Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"679","DOI":"10.1135\/cccc20020679","article-title":"Chemistry of closo-dodecaborate anion [B12H12]2\u2212: A review","volume":"67","author":"Sivaev","year":"2002","journal-title":"Collect. Czech. Chem. 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