{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:36:19Z","timestamp":1760150179236,"version":"build-2065373602"},"reference-count":42,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2023,10,2]],"date-time":"2023-10-02T00:00:00Z","timestamp":1696204800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Three new products, [Cu2(\u03bc3-dppa)(2,2\u2032-bipy)2(H2O)]n\u00b72nH2O (1), [Co4(\u03bc4-dppa)2(phen)4(H2O)4]\u00b72H2O (2), and [Co2(\u03bc6-dppa)(\u03bc-4,4\u2032-bipy)(H2O)2]n\u00b73nH2O (3) were synthesized using a hydrothermal method from Cu(II) and Co(II) metal(II) chlorides, 3-(3,4-dicarboxyphenoxy)phthalic acid (H4dppa), and different auxiliary ligands, namely 2,2\u2032-bipyridine (2,2\u2032-bipy),1,10-phenanthroline (phen), and 4,4\u2032-bipyridine (4,4\u2032-bipy). Products 1\u20133 were characterized by elemental analysis, FTIR, TGA, PXRD, SEM, and single-crystal X-ray crystallography. The structure of 1 features a 1D chain of the 2C1 topological type. Compound 2 shows a discrete tetrameric complex. Product 3 demonstrates a 3D metal\u2013organic framework (MOF) with the new topology. Their structure and topology, thermal stability, and catalytic activity were studied. In particular, excellent catalytic activity was demonstrated for copper(II)-polymer 1 in the cyanosilylation reaction at 35 \u00b0C.<\/jats:p>","DOI":"10.3390\/molecules28196911","type":"journal-article","created":{"date-parts":[[2023,10,3]],"date-time":"2023-10-03T01:48:17Z","timestamp":1696297697000},"page":"6911","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Syntheses, Crystal Structures, and Catalytic Properties of Three Cu(II) and Cobalt(II) Coordination Compounds Based on an Ether-Bridged Tetracarboxylic Acid"],"prefix":"10.3390","volume":"28","author":[{"given":"Xiuqi","family":"Kang","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongyu","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhenzhong","family":"Mei","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaoxiang","family":"Fan","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6704-7370","authenticated-orcid":false,"given":"Jinzhong","family":"Gu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,10,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3751","DOI":"10.1021\/acs.chemrev.0c01049","article-title":"Two\u2212Dimensional Metal\u2212Organic Framework Materials: Synthesis, Structures, Properties and Applications","volume":"121","author":"Chakraborty","year":"2021","journal-title":"Chem. 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