{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T23:01:48Z","timestamp":1788908508236,"version":"build-2803163510"},"reference-count":63,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2023,10,25]],"date-time":"2023-10-25T00:00:00Z","timestamp":1698192000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100008530","name":"Greece and the European Union (European Regional Development Fund)","doi-asserted-by":"publisher","award":["MIS 5047233"],"award-info":[{"award-number":["MIS 5047233"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008530","name":"Greece and the European Union (European Regional Development Fund)","doi-asserted-by":"publisher","award":["NSRF 2014-2020"],"award-info":[{"award-number":["NSRF 2014-2020"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Mixed-ligand tetranuclear supramolecular coordination complexes (SCCs) of Pt(II)-p-biphenyl and bridging ligands derivatives of 4,4\u2032-bypiridine (8)\u2013(10), were synthesized and characterized. The SCCs were synthesized stepwise, starting from the Pt-p-biphenyl -Pt core. The crystal structure of complex {[Pt(2,2\u2032-bpy)]4(\u03bc-bph)2(\u03bc-(4,4\u2032-bpy)2}{PF6}4 (2,2\u2032-bpy = 2,2\u2032-bipyridine, bph = p-biphenyl and 4,4\u2032-bpy = 4,4\u2032 bipyridine), was determined using single-crystal diffraction methods. The emission profile of the tetranuclear complexes (8)\u2013(10) was influenced by the length of the bridging ligands and was found to depend on solvent polarity. Dual-emission patterns in methanol\u2013water mixtures were observed only in the cases of complexes (9) and (10), attributed to aggregation-induced emission phenomena.<\/jats:p>","DOI":"10.3390\/molecules28217261","type":"journal-article","created":{"date-parts":[[2023,10,25]],"date-time":"2023-10-25T06:19:58Z","timestamp":1698214798000},"page":"7261","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Dual-Emissive Rectangular Supramolecular Pt(II)-p-Biphenyl with 4,4\u2032-Bipyridine Derivative Metallacycles: Stepwise Synthesis and Photophysical Properties"],"prefix":"10.3390","volume":"28","author":[{"given":"Antonia","family":"Garypidou","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Ioannina, GR-45110 Ioannina, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantinos","family":"Ypsilantis","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Ioannina, GR-45110 Ioannina, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4665-6593","authenticated-orcid":false,"given":"John C.","family":"Plakatouras","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Ioannina, GR-45110 Ioannina, Greece"},{"name":"Institute of Materials Science and Computing, University Research Centre of Ioannina (URCI), GR-45110 Ioannina, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0303-0638","authenticated-orcid":false,"given":"Achilleas","family":"Garoufis","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Ioannina, GR-45110 Ioannina, Greece"},{"name":"Institute of Materials Science and Computing, University Research Centre of Ioannina (URCI), GR-45110 Ioannina, Greece"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,10,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Saygili, Y., Stojanovic, M., Flores-D\u00edaz, N., Zakeeruddin, S.M., Vlachopoulos, N., Gr\u00e4tzel, M., and Hagfeldt, A. 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