{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T15:17:03Z","timestamp":1781536623637,"version":"3.54.5"},"reference-count":59,"publisher":"MDPI AG","issue":"23","license":[{"start":{"date-parts":[[2023,11,28]],"date-time":"2023-11-28T00:00:00Z","timestamp":1701129600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"German Federal Ministry of Environment, Nature Conservation, Nuclear Safety and Consumer Protection (BMUV)","award":["1501667"],"award-info":[{"award-number":["1501667"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>In chloroform solution, the reaction of bis(tert-butylamino)dimethylsilane ((tBuNH)2SiMe2) and an \u03b1-amino acid (\u03b1-amino isobutyric acid, H2Aib; D-phenylglycine, H2Phg; L-valine, H2Val) in the presence of N-methylimidazole (NMI) gave rise to the formation of the pentacoordinate silicon complexes (Aib)SiMe2-NMI, (Phg)SiMe2-NMI and (Val)SiMe2-NMI, respectively. Therein, the amino acid building block was a di-anionic bidentate chelator at the silicon atom. In solution, the complexes were involved in rapid coordination\u2013dissociation equilibria between the pentacoordinate Si complex (e.g., (Aib)SiMe2-NMI) and its constituents NMI and a five-membered silaheterocycle (e.g., (Aib)SiMe2), as shown by 29Si NMR spectroscopy. The energetics of the Lewis acid-base adduct formation and the competing solvation of the NMI molecule by chloroform were assessed with the aid of computational methods. In CDCl3 solution, deuteration of the silaheterocycle NH group proceeded rapidly, with more than 50% conversion within two days. Upon cooling to \u221244 \u00b0C, the chloroform solvates of the adducts (Aib)SiMe2-NMI and (Phg)SiMe2-NMI crystallized from their parent solutions and allowed for their single-crystal X-ray diffraction analyses. In both cases, the Si atom was situated in a distorted trigonal bipyramidal coordination sphere with equatorial Si\u2013C bonds and an equatorial Si\u2013N bond (the one of the silaheterocycle). The axial positions were occupied by a carboxylate O atom of the silaheterocycle and the NMI ligand\u2019s donor-N-atom.<\/jats:p>","DOI":"10.3390\/molecules28237816","type":"journal-article","created":{"date-parts":[[2023,11,28]],"date-time":"2023-11-28T07:41:32Z","timestamp":1701157292000},"page":"7816","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Lewis Acid-Base Adducts of \u03b1-Amino Acid-Derived Silaheterocycles and N-Methylimidazole"],"prefix":"10.3390","volume":"28","author":[{"given":"Anne","family":"Seidel","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4669-0206","authenticated-orcid":false,"given":"Robert","family":"Gericke","sequence":"additional","affiliation":[{"name":"Institute of Resource Ecology, Helmholtz-Zentrum Dresden-Rossendorf eV, D-01328 Dresden, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beate","family":"Kutzner","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5968-2331","authenticated-orcid":false,"given":"J\u00f6rg","family":"Wagler","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,11,28]]},"reference":[{"key":"ref_1","first-page":"352","article-title":"XVIII. 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