{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T00:18:33Z","timestamp":1778717913106,"version":"3.51.4"},"reference-count":95,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2024,3,15]],"date-time":"2024-03-15T00:00:00Z","timestamp":1710460800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Family and Social Policy"},{"name":"Central Institute for Labour Protection\u2014National Research Institute"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The aim of the study was to produce new elastomeric materials containing butyl rubber (IIR) filled with silica and phyllosilicates (vermiculite, montmorillonite, perlite or halloysite tubes) with enhanced hydrophobicity and barrier properties and reduced chemical degradation. It was found that the filler type had a significant impact on the degree of cross-linking of butyl rubber and the properties of its vulcanizates. The highest degree of cross-linking and the highest mechanical strength were achieved for IIR composites filled with Arsil with perlite or halloysite tubes. The highest surface hydrophobicity (119\u00b0) was confirmed for the IIR vulcanizates with Arsil and montmorillonite. All tested samples showed high barrier properties because both the gas diffusion rate coefficient and the permeability coefficient reached low values. Both unfilled and filled IIR vulcanizates retained chemical resistance in contact with methanol for 480 min. Hour-long contact of a polar solvent (methanol) with each of the vulcanizates did not cause material degradation, while the presence of a non-polar solvent (n-heptane) worsened the mechanical parameters by up to 80%. However, the presence of fillers reduced the chemical degradation of vulcanizates (in the case of cured IIR filled with Arsil and halloysite tubes by 40% compared to the composite without fillers).<\/jats:p>","DOI":"10.3390\/molecules29061306","type":"journal-article","created":{"date-parts":[[2024,3,15]],"date-time":"2024-03-15T04:47:05Z","timestamp":1710478025000},"page":"1306","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["The New Elastomeric Compounds Made of Butyl Rubber Filled with Phyllosilicates, Characterized by Increased Barrier Properties and Hydrophobicity and Reduced Chemical Degradation"],"prefix":"10.3390","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7720-1773","authenticated-orcid":false,"given":"Aleksandra","family":"Smejda-Krzewicka","sequence":"first","affiliation":[{"name":"Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego 16, 90-537 Lodz, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8138-5552","authenticated-orcid":false,"given":"Emilia","family":"Irzma\u0144ska","sequence":"additional","affiliation":[{"name":"Central Institute for Labour Protection\u2014National Research Institute, Department of Personal Protective Equipment, Czerniakowska 16, 00-701 Warsaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-5732-5306","authenticated-orcid":false,"given":"Konrad","family":"Mrozowski","sequence":"additional","affiliation":[{"name":"Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego 16, 90-537 Lodz, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Agnieszka","family":"Adamus-W\u0142odarczyk","sequence":"additional","affiliation":[{"name":"Central Institute for Labour Protection\u2014National Research Institute, Department of Personal Protective Equipment, Czerniakowska 16, 00-701 Warsaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Natalia","family":"Litwicka","sequence":"additional","affiliation":[{"name":"Central Institute for Labour Protection\u2014National Research Institute, Department of Personal Protective Equipment, Czerniakowska 16, 00-701 Warsaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6450-4337","authenticated-orcid":false,"given":"Krzysztof","family":"Strzelec","sequence":"additional","affiliation":[{"name":"Institute of Polymer and Dye Technology, Lodz University of Technology, Stefanowskiego 16, 90-537 Lodz, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1959-3849","authenticated-orcid":false,"given":"Ma\u0142gorzata I.","family":"Szynkowska-J\u00f3\u017awik","sequence":"additional","affiliation":[{"name":"Institute of General and Ecological Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,3,15]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"106003","DOI":"10.1016\/j.polymertesting.2019.106003","article-title":"Design of regulable chlorobutyl rubber damping materials with high-damping value for a wide temperature range","volume":"79","author":"Liu","year":"2019","journal-title":"Polym. Test."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"40996","DOI":"10.1021\/acsami.8b18212","article-title":"Design of novel self-healing thermoplastic vulcanizates utilizing thermal\/magnetic\/light-triggered shape memory effects","volume":"10","author":"Huang","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"4922","DOI":"10.1039\/C8TA11587G","article-title":"A robust and stretchable cross-linked rubber network with recyclable and self-healable capabilities based on dynamic covalent bonds","volume":"7","author":"Cao","year":"2019","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Irzma\u0144ska, E., Korzeniewska, E., Pawlak, R., Tomczyk, M., Smejda-Krzewicka, A., and Adamus-W\u0142odarczyk, A. (2021). Enhanced Hydrofobicity of Polymers for Personal Protective Equipment Achieved by Chemical and Physical Modification. Materials, 15.","DOI":"10.3390\/ma15010106"},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Koros, W.J. (1990). Barrier Polymers and Structures, American Chemical Society.","DOI":"10.1021\/bk-1990-0423"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1817","DOI":"10.1002\/app.26189","article-title":"Carboxyl-terminated butadiene acrylonitrile rubber\/epoxy polymer alloys as damping adhesives and energy absorbable resins","volume":"105","author":"Kishi","year":"2007","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"306","DOI":"10.1016\/j.compstruct.2018.03.066","article-title":"Dynamic effective equivalent stiffness analysis on the periodical honeycomb reinforced composite laminated structure filled with viscoelastic damping material","volume":"193","author":"Zhou","year":"2018","journal-title":"Compos. Struct."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.mser.2017.01.002","article-title":"Processing-structure-property relationships of continuous carbon fiber polymer-matrix composites","volume":"113","author":"Chung","year":"2017","journal-title":"Mater. Sci. Eng. R"},{"key":"ref_9","first-page":"10","article-title":"Hydrophobicity of silicone rubber used for outdoor insulation","volume":"16","author":"Amin","year":"2007","journal-title":"Rev. Adv. Mater. Sci."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1431","DOI":"10.1016\/j.matpr.2021.07.134","article-title":"Evaluation of solvent transport and cure characteristics of chlorobutyl rubber graphene oxide nanocomposites","volume":"49","author":"Sreehari","year":"2022","journal-title":"Mater. Today Proc."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.polymertesting.2004.08.004","article-title":"Preparation and properties of isobutylene\u2013isoprene rubber (IIR)\/clay nanocomposites","volume":"24","author":"Liang","year":"2005","journal-title":"Polym. Test."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"311","DOI":"10.14314\/polimery.2008.311","article-title":"The effect of conditions of solvents interactions on barier properties of butyl rubber vulcanizates","volume":"53","author":"Rzymski","year":"2008","journal-title":"Polimery"},{"key":"ref_13","first-page":"309","article-title":"Investigation of natural rubber compatibility with different types of butyl rubber","volume":"66","author":"Ismail","year":"2023","journal-title":"Egypt. J. Chem."},{"key":"ref_14","first-page":"432","article-title":"Effect of blend ratio on the phase structure and ozone aging resistance of ethylene-propylene-diene, butyl, and chlorobutyl rubber blends","volume":"63","author":"Sukharev","year":"2023","journal-title":"Polym.-Plast. Tech. Mat."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1367","DOI":"10.1122\/8.0000414","article-title":"Butyl rubber as a macro-cross-linker in the preparation of a shape-memory and self-healing polymer","volume":"66","author":"Tavsanli","year":"2022","journal-title":"J. Rheol."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Guo, X., and Liu, G. (2023). Electromagnetic Shielding Enhancement of Butyl Rubber\/Single-Walled Carbon Nanotube Composites via Water-Induced Modification. Polymers, 15.","DOI":"10.3390\/polym15092101"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"4629","DOI":"10.1007\/s10854-015-2879-5","article-title":"Preparation and properties of BaTiO3 filled butyl rubber composites for flexible electronic circuit applications","volume":"26","author":"Chameswary","year":"2015","journal-title":"J. Mater. Sci. Mater. Electron."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"9682","DOI":"10.1021\/acsami.9b22787","article-title":"Constructing 3D graphene network in rubber nanocomposite via liquid-phase redispersion and self-assembly","volume":"12","author":"Hao","year":"2020","journal-title":"ACS Appl. Mater. Inter."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"325","DOI":"10.5254\/1.3538376","article-title":"Chemical aspects of rubber reinforcement by fillers","volume":"69","author":"Wolff","year":"1996","journal-title":"Rubber Chem. Technol."},{"key":"ref_20","unstructured":"Katz, H., and Milewski, J. (1987). Handbook of Fillers for Plastics, Van Nostrand. [2nd ed.]."},{"key":"ref_21","unstructured":"Rothon, R. (1995). Particulate-Filled Polymer Composites, Longman."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"992","DOI":"10.3390\/ma2030992","article-title":"Polymer layered silicate nanocomposites: A review","volume":"2","author":"Mittal","year":"2009","journal-title":"Materials"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"571","DOI":"10.1002\/1527-2648(200108)3:8<571::AID-ADEM571>3.0.CO;2-M","article-title":"Polymer based nanocomposites: Effect of filler-filler and filler-matrix interactions","volume":"3","author":"Brechet","year":"2001","journal-title":"Adv. Eng. Mater."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"10","DOI":"10.5254\/rct.13.87951","article-title":"Improvement in physical and mechanical properties of IIR\/CR rubber blend organoclay nanocomposites","volume":"87","author":"Azizli","year":"2014","journal-title":"Rubber Chem. Technol."},{"key":"ref_25","first-page":"671","article-title":"Improvement in physical and mechanical properties of butyl rubber with montmorillonite organo-clay","volume":"16","author":"Hasankhani","year":"2007","journal-title":"Iranian Polym. J."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"256","DOI":"10.1006\/jcis.1995.1032","article-title":"Correlation of line tension and solid\u2013liquid interfacial tension from the measurement of drop size dependence of contact angles","volume":"169","author":"Duncan","year":"1995","journal-title":"J. Colloid Interface Sci."},{"key":"ref_27","first-page":"228","article-title":"Nanoparticle: An overview of preparation and characterization","volume":"1","author":"Pal","year":"2011","journal-title":"J. Appl. Pharm. Sci."},{"key":"ref_28","doi-asserted-by":"crossref","unstructured":"Sonia, T., and Sharma, C. (2014). 4\u2014Experimental techniques involved in the development of oral insulin carriers. Oral Deliv. Insul., 169\u2013217.","DOI":"10.1533\/9781908818683.169"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/s004250050096","article-title":"Purity of the sacred lotus, or escape from contamination in biological surfaces","volume":"202","author":"Barthlott","year":"2018","journal-title":"Planta"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1102","DOI":"10.1021\/acscentsci.8b00504","article-title":"Bioinspired Designs of Superhydrophobic and Superhydrophilic Materials","volume":"4","author":"Si","year":"2018","journal-title":"ACS Cent. Sci."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1820","DOI":"10.1016\/j.jmrt.2021.07.096","article-title":"A flower-like waterborne coating with self-cleaning, self-repairing properties for superhydrophobic applications","volume":"14","author":"Wu","year":"2021","journal-title":"J. Mater. Res. Tech."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"6260","DOI":"10.1021\/acsami.5b00558","article-title":"Mechanically Robust Superhydrophobic Steel Surface with Anti-Icing, UV-Durability, and Corrosion Resistance Properties","volume":"7","author":"Wang","year":"2015","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"127110","DOI":"10.1016\/j.cej.2020.127110","article-title":"Mechanically robust, self-healing superhydrophobic anti-icing coatings based on a novel fluorinated polyurethane synthesized by a two-step thiol click reaction","volume":"404","author":"Fu","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_34","unstructured":"Rabek, J.F. (2013). Polimery: Otrzymywanie, Metody Badawcze, Zastosowanie, Wydawnictwo Naukowe PWN."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1007\/978-3-642-34243-1_1","article-title":"Contact angle and wetting properties","volume":"1","author":"Yuan","year":"2013","journal-title":"Surf. Sci. Tech."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1016\/S0001-8686(01)00097-5","article-title":"Problems of contact angle and solid surface free energy determination","volume":"98","author":"Chibowski","year":"2002","journal-title":"Adv. Colloid. Interface Sci."},{"key":"ref_37","first-page":"29","article-title":"The use of contact angle and the structure free energy as the surface characteristics of the polymers used in medicine","volume":"44","year":"2014","journal-title":"Polim. Med."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"63669","DOI":"10.1039\/C5RA10333A","article-title":"Gas barrier properties of polymer\/clay nanocomposites","volume":"5","author":"Cui","year":"2015","journal-title":"RSC Adv."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1533\/9781845691127.1.273","article-title":"Barrier properties of polymer\/clay nanocomposites","volume":"17","author":"Sorrentino","year":"2006","journal-title":"Polym. Nanocomp."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1930","DOI":"10.1016\/j.polymer.2013.01.049","article-title":"Enhanced mechanical and gas barrier properties of rubber nanocomposites with surface functionalized graphene oxide at low content","volume":"54","author":"Wu","year":"2013","journal-title":"Polymer"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/j.memsci.2007.01.030","article-title":"Barrier properties of nylon 6-montmorillonite nanocomposite membranes prepared by melt blending: Influence of the clay content and dispersion state: Consequences on modelling","volume":"292","author":"Picard","year":"2007","journal-title":"J. Memb. Sci."},{"key":"ref_42","first-page":"202","article-title":"Polymer\/clay nanocomposite based coatings for enhanced gas barrier property","volume":"31","author":"Joshi","year":"2006","journal-title":"Indian J. Fibre Text. Res."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"551","DOI":"10.14314\/polimery.2012.551","article-title":"Effect of layered aluminosilicates on the barier properties of butyl rubber","volume":"57","author":"Rzymski","year":"2012","journal-title":"Polimery"},{"key":"ref_44","first-page":"3","article-title":"Polymer nanocomposites","volume":"4","year":"2004","journal-title":"Composites"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"2904","DOI":"10.1016\/j.polymer.2006.02.069","article-title":"Calculating barrier properties of polymer\/clay nanocomposites: Effects of clay layers","volume":"47","author":"Xu","year":"2006","journal-title":"Polymer"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/s11051-013-1815-y","article-title":"Mechanisms of nanoclay-enhanced plastic foaming processes: Effects of nanoclay intercalation and exfoliation","volume":"15","author":"Wong","year":"2013","journal-title":"J. Nanopart. Res."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"374","DOI":"10.14314\/polimery.2006.374","article-title":"Study on the process of preparation of polypropylene nanocomposite with montmorillonite","volume":"51","year":"2006","journal-title":"Polimery"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"617","DOI":"10.14314\/polimery.2006.617","article-title":"Biodegradable nanocomposites. Part I. Methods of preparation","volume":"51","author":"Rudnik","year":"2006","journal-title":"Polimery"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S0927-796X(00)00012-7","article-title":"Polymer layered silicate nanocomposites: Preparation, properties and uses of a new class of materials","volume":"28","author":"Alexandre","year":"2000","journal-title":"Mater. Sci. Eng. R Rep."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"68","DOI":"10.1002\/macp.200600444","article-title":"Poly(propylene)-layered silicate nanocomposites: Gas permeation properties and clay exfoliation","volume":"208","author":"Osman","year":"2007","journal-title":"Macromol. Chem. Phys."},{"key":"ref_51","doi-asserted-by":"crossref","unstructured":"Salahuddin, N., Hapeez, M., Abidin, A., Hamzah, N., and Mustam, M. (2014, January 16\u201317). Investigation of effectiveness of phyllosilicate into polymeric materials. Proceedings of the 2014 IEEE Student Conference on Research and Development, Penang, Malaysia.","DOI":"10.1109\/SCORED.2014.7072986"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"5483","DOI":"10.1016\/S0032-3861(02)00403-2","article-title":"Influence of clay exfoliation on the physical properties of montmorillonite\/polyethylene composites","volume":"43","author":"Gopakumar","year":"2002","journal-title":"Polymer"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"11716","DOI":"10.1016\/j.polymer.2005.09.057","article-title":"Influence of montmorillonite layered silicate on plasticized poly(l-lactide) blown films","volume":"46","author":"Thellen","year":"2005","journal-title":"Polymer"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"670","DOI":"10.1002\/polb.10420","article-title":"Nanocomposites by melt intercalation based on polycaprolactone and organoclay","volume":"41","author":"Di","year":"2003","journal-title":"J. Polym. Sci. B Polym. Phys."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"1781","DOI":"10.1002\/(SICI)1097-4628(19971128)66:9<1781::AID-APP17>3.0.CO;2-Y","article-title":"Synthesis of polypropylene oligomer-clay intercalation compounds","volume":"66","author":"Kato","year":"1997","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"6333","DOI":"10.1021\/ma961786h","article-title":"Preparation and mechanical properties of polypropylene-clay hybrids","volume":"30","author":"Kawasumi","year":"1997","journal-title":"Macromolecules"},{"key":"ref_57","first-page":"1298","article-title":"Gas permeation properties of polyethylene-layered silicate nanocomposites","volume":"15","author":"Osman","year":"2005","journal-title":"J. Mater. Chem."},{"key":"ref_58","unstructured":"Adeli, M. (2008). Novel Polymers and Nanoscience, Research Signpost Publishers."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1908","DOI":"10.1166\/jnn.2019.16339","article-title":"Influence of phyllosilicate structure on performance of polypropylene nanocomposites prepared via in-situ polymerization","volume":"19","author":"Arias","year":"2019","journal-title":"J. Nanosci. Nanotechnol."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"575","DOI":"10.1177\/0892705707083636","article-title":"Polypropylene-layered silicate nanocomposites: Filler matrix interactions and mechanical properties","volume":"20","author":"Mittal","year":"2007","journal-title":"J. Thermoplast. Compos. Mater."},{"key":"ref_61","first-page":"862","article-title":"A direct blending approach for polypropylene\/clay nanocomposites enhances properties","volume":"26","author":"Manias","year":"2001","journal-title":"MRS Bull."},{"key":"ref_62","first-page":"186","article-title":"The application of halloysite as a filler for modification of polypropylene. Part I. The characteristics of halloysite as a filler","volume":"10","author":"Szczygielska","year":"2010","journal-title":"Composites"},{"key":"ref_63","first-page":"1510","article-title":"The structure, properties and uses of layered minerals","volume":"85","author":"Kunert","year":"2006","journal-title":"Przem. Chem."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"134","DOI":"10.1016\/j.clay.2012.04.024","article-title":"Silane-grafted silica-covered kaolinite as filler of styrene butadiene rubber","volume":"65\u201366","author":"Zhang","year":"2012","journal-title":"Appl. Clay Sci."},{"key":"ref_65","unstructured":"Wypych, G. (1999). Handbook of Fillers, ChemTec Publishing."},{"key":"ref_66","first-page":"376","article-title":"Vermiculite, its properties, occurrence and use","volume":"8","author":"Kubicz","year":"1960","journal-title":"Przegl\u0105d Geol."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"58","DOI":"10.1016\/j.polymer.2006.11.018","article-title":"Grafting of hydrocarbon moieties on smectites by cold acetylene plasma and characterization of plasma-treated clay mineral polyethylene nanocomposites","volume":"48","author":"Bergaya","year":"2007","journal-title":"Polymer"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1177\/00952443211029038","article-title":"Expanded vermiculite-filled flexible polymer composites","volume":"54","author":"Cetin","year":"2022","journal-title":"J. Elastom. Plast."},{"key":"ref_69","doi-asserted-by":"crossref","unstructured":"Vasilev, A.P. (2019). Mechanical and tribological properties of polytetrafluoroethylene composites with carbon fiber and layered silicate fillers. Molecules, 24.","DOI":"10.3390\/molecules24020224"},{"key":"ref_70","doi-asserted-by":"crossref","unstructured":"Khammassi, S., Tarfaoui, M., \u0160krlov\u00e1, K., M\u011b\u0159\u00ednsk\u00e1, D., Plach\u00e1, D., and Erchiqui, F. (2022). Poly(Lactic Acid) (PLA)-Based Nanocomposites: Impact of Vermiculite, Silver, and Graphene Oxide on Thermal Stability, Isothermal Crystallization, and Local Mechanical Behavior. J. Comp. Sci., 6.","DOI":"10.3390\/jcs6040112"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"239","DOI":"10.1590\/S1516-14392008000300002","article-title":"Surface properties of dental polymers: Measurements of contact angles, roughness and fluoride release","volume":"11","author":"Namen","year":"2008","journal-title":"Mater. Res."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"146","DOI":"10.1016\/j.surfin.2018.12.008","article-title":"Super-hydrophobic zinc oxide\/silicone rubber nanocomposite surfaces","volume":"14","author":"Mendoza","year":"2019","journal-title":"Surf. Interfaces"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"5073","DOI":"10.1021\/la050033y","article-title":"Tuning the surface hydrophobicity of polymer\/nanoparticle composite films in the wenzel regime by composition","volume":"21","author":"Demirel","year":"2005","journal-title":"Langmuir"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"106978","DOI":"10.1016\/j.compositesb.2019.106978","article-title":"Super-hydrophobic graphene oxide-azobenzene hybrids for improved hydrophobicity of polyurethane","volume":"173","author":"Karthika","year":"2019","journal-title":"Compos. Part B Eng."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"532","DOI":"10.1080\/01694243.2014.996963","article-title":"Hybrid elastomer-nanotube matrix for hydrophobic surface functionalization","volume":"29","author":"Omar","year":"2015","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"736","DOI":"10.1016\/j.jnucmat.2018.04.038","article-title":"Compatibility between high-flux helium plasma irradiated molybdenum and liquid lithium","volume":"509","author":"He","year":"2018","journal-title":"J. Nucl. Mater."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"620","DOI":"10.1016\/j.rser.2016.01.017","article-title":"Highly efficient antireflective and self-cleaning coatings that incorporate carbon nanotubes (CNTs) into solar cells: A review","volume":"59","author":"Hanaei","year":"2016","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"3083","DOI":"10.1016\/j.polymer.2006.02.077","article-title":"Gas barrier properties of butyl rubber\/vermiculite nanocomposite coatings","volume":"47","author":"Takahashi","year":"2006","journal-title":"Polymer"},{"key":"ref_79","unstructured":"(2016). Protective Gloves against Dangerous Chemicals and Micro-Organisms\u2014Part 1: Terminology and Performance Requirements for Chemical Risks (Standard No. EN ISO 374-1:2016)."},{"key":"ref_80","unstructured":"Pinnavaia, T.J., and Beall, G.W. (1997). Polymer-Clay Nanocomposites, Wiley."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1016\/j.memsci.2018.03.085","article-title":"How the shape of fillers affects the barrier properties of polymer\/non-porous particles nanocomposites: A review","volume":"556","author":"Wolf","year":"2018","journal-title":"J. Membr. Sci."},{"key":"ref_82","doi-asserted-by":"crossref","unstructured":"Szadkowski, B., Marzec, A., Rybi\u0144ski, P., \u017bukowski, W., and Zaborski, M. (2020). Characterization of ethylene-propylene composites filled with perlite and vermiculite minerals: Mechanical, barrier, and flammability properties. Materials, 13.","DOI":"10.3390\/ma13030585"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"2151","DOI":"10.1016\/j.matdes.2009.11.009","article-title":"Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes","volume":"31","author":"Rooj","year":"2010","journal-title":"Mater. Des."},{"key":"ref_84","unstructured":"(2018). Protective Gloves against Mechanical Risks (Standard No. EN 388:2016+A1:2018)."},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"347","DOI":"10.1520\/JTE101942","article-title":"Rubber-Filler Interactions and Its effect in rheological and mechanical properties of filled compounds","volume":"38","author":"Mostafa","year":"2010","journal-title":"J. Test. Eval."},{"key":"ref_86","unstructured":"(2017). Standard Test Method for Rubber Property\u2014Vulcanization Using Rotorless Cure Meters (Standard No. ASTM D5289-17)."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"E204","DOI":"10.1002\/app.34231","article-title":"Vulcanization Kinetics of Butyl Rubber-Clay Nano Composites and Its Dependence on Clay Microstructure","volume":"125","author":"Sepehri","year":"2012","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_88","unstructured":"(2016). Standard Test Method for Rubber Property\u2014Effect of Liquids (Standard No. ASTM D471)."},{"key":"ref_89","unstructured":"(2022). Rubber, Vulcanized or Thermoplastic Determination of Tear Strength\u2014Part 1: Trouser, Angle and Crescent Test Pieces (Standard No. ISO 34-1:2022)."},{"key":"ref_90","unstructured":"(2018). Rubber, Vulcanized or Thermoplastic Determination of Hardness\u2014Part 4: Indentation Hardness by Durometer Method (Shore Hardness) (Standard No. ISO 48-4:2018)."},{"key":"ref_91","unstructured":"(2022). Rubber, Vulcanized or Thermoplastic Determination of Dynamic Properties\u2014Part 1: General Guidance (Standard No. ISO 4664-1:2022)."},{"key":"ref_92","unstructured":"(2019). Protective Gloves against Dangerous Chemicals and Micro-Organisms\u2014Part 4: Determination of Resistance to Degradation by Chemicals (Standard No. EN ISO 374-4:2019)."},{"key":"ref_93","unstructured":"(1999). Rubber- or Plastics-Coated Fabrics. Standard Atmospheres for Conditioning and Testing (Standard No. EN ISO 2231:1995\/PN-EN ISO 2231:1999)."},{"key":"ref_94","unstructured":"(2017). R\u0119kawice chroni\u0105ce przed zagro\u017ceniami mechanicznymi (Standard No. PN-EN 388:2017-02)."},{"key":"ref_95","unstructured":"(2020). R\u0119kawice chroni\u0105ce przed niebezpiecznymi substancjami chemicznymi i mikroorganizmami\u2014Cz\u0119\u015b\u0107 4: Wyznaczanie odporno\u015bci na degradacj\u0119 w wyniku dzia\u0142ania substancji chemicznych (Standard No. PN-EN ISO 374-4:2020-03)."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/6\/1306\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T14:14:07Z","timestamp":1760105647000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/6\/1306"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,3,15]]},"references-count":95,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2024,3]]}},"alternative-id":["molecules29061306"],"URL":"https:\/\/doi.org\/10.3390\/molecules29061306","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,3,15]]}}}