{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T23:37:11Z","timestamp":1770421031666,"version":"3.49.0"},"reference-count":56,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2024,6,8]],"date-time":"2024-06-08T00:00:00Z","timestamp":1717804800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Guangdong Basic and Applied Basic Research Foundation","award":["2020A1515110243"],"award-info":[{"award-number":["2020A1515110243"]}]},{"name":"Guangdong Basic and Applied Basic Research Foundation","award":["2021A1515012344"],"award-info":[{"award-number":["2021A1515012344"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The formation of nitrogen-containing organic interstellar molecules is of great importance to reveal chemical processes and the origin of life on Earth. Benzonitrile (BN) is one of the simplest nitrogen-containing aromatic molecules in the interstellar medium (ISM) that has been detected in recent years. Methanol (CH3OH) exists widely in interstellar space with high reactivity. Herein, we measured the infrared (IR) spectra of neutral and cationic BN\u2013CH3OH clusters by vacuum ultraviolet (VUV) photoionization combined with time-of-flight mass spectrometry. Combining IR spectra with the density functional theory calculations, we reveal that the BN\u2013CH3OH intends to form a cyclic H-bonded structure in neutral clusters. However, after the ionization of BN\u2013CH3OH clusters, proton-shared N\u00b7\u00b7\u00b7H\u00b7\u00b7\u00b7O and N\u00b7\u00b7\u00b7H\u00b7\u00b7\u00b7C structures are confirmed to form between BN and CH3OH, with the minor coexistence of H-bond and O-\u03c0 structures. The formation of the proton-shared structure expands our knowledge of the evolution of the life-related nitrogen-containing molecules in the universe and provides a possible pathway to the further study of biorelevant aromatic organic macromolecules.<\/jats:p>","DOI":"10.3390\/molecules29122744","type":"journal-article","created":{"date-parts":[[2024,6,10]],"date-time":"2024-06-10T08:59:06Z","timestamp":1718009946000},"page":"2744","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Infrared Spectroscopy of Neutral and Cationic Benzonitrile\u2013Methanol Binary Clusters in Supersonic Jets"],"prefix":"10.3390","volume":"29","author":[{"given":"Xianming","family":"Xiong","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science, Guangzhou Key Laboratory of Spectral Analysis and Functional Probes, College of Biophotonics, South China Normal University, Guangzhou 510631, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yongjun","family":"Hu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science, Guangzhou Key Laboratory of Spectral Analysis and Functional Probes, College of Biophotonics, South China Normal University, Guangzhou 510631, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"79","DOI":"10.3847\/0004-637X\/829\/2\/79","article-title":"A new astrobiological model of the atmosphere of Titan","volume":"829","author":"Willacy","year":"2016","journal-title":"Astrophys. 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