{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T21:48:02Z","timestamp":1790804882373,"version":"4.1.0"},"reference-count":54,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2024,6,26]],"date-time":"2024-06-26T00:00:00Z","timestamp":1719360000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003032","name":"French National Association for Research and Technology (ANRT)","doi-asserted-by":"publisher","award":["2021\/0625"],"award-info":[{"award-number":["2021\/0625"]}],"id":[{"id":"10.13039\/501100003032","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003032","name":"French National Association for Research and Technology (ANRT)","doi-asserted-by":"publisher","award":["ANR-18-EURE-0021"],"award-info":[{"award-number":["ANR-18-EURE-0021"]}],"id":[{"id":"10.13039\/501100003032","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"French National Agency for Research (ANR)","doi-asserted-by":"publisher","award":["2021\/0625"],"award-info":[{"award-number":["2021\/0625"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001665","name":"French National Agency for Research (ANR)","doi-asserted-by":"publisher","award":["ANR-18-EURE-0021"],"award-info":[{"award-number":["ANR-18-EURE-0021"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>This study was carried out to investigate the continuous aqueous pretreatment of sugarcane bagasse (SCB) through twin-screw extrusion for a new integrated full valorization, where the solid residue (extrudate) was used for the production of bio-based materials by thermocompression and the filtrate for the production of high-value-added molecules. Two configurations, with and without a filtration module, were tested and the influence of the SCB composition and structure on the properties of the materials were determined. The impact of the liquid-to-solid (L\/S) ratio was studied (0.65\u20136.00) in relation to the material properties and the biomolecule extraction yield in the filtrate (with the filtration configuration). An L\/S ratio of at least 1.25 was required to obtain a liquid filtrate, and increasing the L\/S ratio to 2 increased the extraction yield to 11.5 g\/kg of the inlet SCB. The extrudate obtained without filtration yielded materials with properties equivalent to those obtained with filtration for L\/S ratios of at least 1.25. Since the molecule extraction process was limited, a configuration without filtration would make it possible to reduce water consumption in the process while obtaining high material properties. Under the filtration configuration, an L\/S ratio of 2 was the best tradeoff between water consumption, extraction yield, and the material properties, which included 1485 kg\/m3 density, 6.2 GPa flexural modulus, 51.2 MPa flexural strength, and a water absorption (WA) and thickness swelling (TS) of 37% and 44%, respectively, after 24 h of water immersion. The aqueous pretreatment by twin-screw extrusion allowed for the overall valorization of SCB, resulting in materials with significantly improved properties compared to those obtained with raw SCB due to fiber deconstruction.<\/jats:p>","DOI":"10.3390\/molecules29133020","type":"journal-article","created":{"date-parts":[[2024,6,26]],"date-time":"2024-06-26T07:20:06Z","timestamp":1719386406000},"page":"3020","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Aqueous Pretreatment of Lignocellulosic Biomass for Binderless Material Production: Influence of Twin-Screw Extrusion Configuration and Liquid-to-Solid Ratio"],"prefix":"10.3390","volume":"29","author":[{"given":"Julie","family":"Cavailles","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"},{"name":"eRcane, Sainte-Clotilde, 97490 La R\u00e9union, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2652-2520","authenticated-orcid":false,"given":"Guadalupe","family":"Vaca-Medina","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jenny","family":"Wu-Tiu-Yen","sequence":"additional","affiliation":[{"name":"eRcane, Sainte-Clotilde, 97490 La R\u00e9union, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laurent","family":"Labonne","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8777-3000","authenticated-orcid":false,"given":"Philippe","family":"Evon","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00e9r\u00f4me","family":"Peydecastaing","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3432-6768","authenticated-orcid":false,"given":"Pierre-Yves","family":"Pontalier","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Agro-Industrielle (LCA), Universit\u00e9 de Toulouse, INRAE, Toulouse INP, 31030 Toulouse, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,26]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1051\/ocl\/2023028","article-title":"Bio-based materials from sunflower co-products, a way to generate economical value with low environmental footprint","volume":"30","author":"Evon","year":"2023","journal-title":"OCL"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1186\/s10086-023-02092-3","article-title":"Study on preparation of high-performance binderless board from Broussonetia papyrifera","volume":"69","author":"Chen","year":"2023","journal-title":"J. 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