{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,25]],"date-time":"2026-07-25T18:57:30Z","timestamp":1785005850561,"version":"3.55.0"},"reference-count":83,"publisher":"MDPI AG","issue":"15","license":[{"start":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T00:00:00Z","timestamp":1722297600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Cotton is used for the production of textiles, hygiene and cosmetic materials. During cultivation and technological processes, various types of substances (surfactants, softeners, lubricants, etc.) penetrate cotton, which can have a harmful effect on both the human body and the environment. The aim of this study was to analyze selected cotton products in order to identify the substances contained and to describe the potential possibilities of inducing textile contact dermatitis (CD). The impact of the identified compounds on the aquatic environment was also taken into account. Nine samples of cotton clothing and seven samples of cotton pads from various manufacturers were tested. Samples after extraction using the FUSLE (Focused Ultrasonic Liquid Extraction) technique were analyzed with GC\/MS. Qualitative analysis was based on comparing mass spectra with library spectra using the following mass spectra deconvolution programs: MassHunter (Agilent), AMDIS (NIST), and PARADISE (University of Copenhagen). The parameter confirming the identification of the substance was the retention index. Through the non-target screening process, a total of 36 substances were identified, with an average AMDIS match factor of approximately 900 (\u201cexcellent match\u201d). Analyzing the properties of the identified compounds, it can be concluded that most of them have potential properties that can cause CD, also due to the relatively high content in samples. This applies primarily to long-chain alkanes (C25\u2013C31), saturated fatty acids, fatty alcohols (e.g., oleyl alcohol), and fatty acid amides (e.g., oleamide). However, there are not many reports describing cases of cotton CD. Information on the identified groups of compounds may be helpful in the case of unexplained sources of sensitization when the skin comes into contact with cotton materials. Some of the identified compounds are also classified as dangerous for aquatic organisms, especially if they can be released during laundering.<\/jats:p>","DOI":"10.3390\/molecules29153584","type":"journal-article","created":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T08:51:42Z","timestamp":1722329502000},"page":"3584","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Non-Target Screening of Chemicals in Selected Cotton Products by GC\/MS and Their Safety Assessment"],"prefix":"10.3390","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8997-8838","authenticated-orcid":false,"given":"\u0141ukasz","family":"D\u0105browski","sequence":"first","affiliation":[{"name":"Department of Food Analysis and Environmental Protection, Faculty of Chemical Technology and Engineering, Bydgoszcz University of Science and Technology, 3 Seminaryjna Street, 85-326 Bydgoszcz, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,7,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Gordon, S., and Hsieh, Y.-L. (2007). Cotton: Science and Technology, Woodehead Publishing Limited.","DOI":"10.1533\/9781845692483"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"413","DOI":"10.1021\/ie50436a021","article-title":"COTTON WAX... Properties and Constituents","volume":"38","author":"Tonn","year":"1946","journal-title":"Ind. Eng. Chem. Anal. Ed."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"745","DOI":"10.1021\/i560136a007","article-title":"Determination of Wax in Cotton Fiber a New Alcohol Extraction Method","volume":"16","author":"Conrad","year":"1944","journal-title":"Ind. Eng. Chem. Anal. Ed."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1021\/i560152a019","article-title":"Isopropyl Alcohol in Cotton Wax Determination","volume":"18","author":"Kettering","year":"1946","journal-title":"Ind. Eng. Chem. Anal. Ed."},{"key":"ref_5","first-page":"1","article-title":"Lubrication and Tribological Problem in Textile Industry","volume":"10","author":"Hawlader","year":"2021","journal-title":"Int. J. Adv. Res. Sci. Eng."},{"key":"ref_6","doi-asserted-by":"crossref","unstructured":"U\u011fur, \u015e.S., Karaboyac\u0131, M., and Boguniewicz-Zablocka, J. (2023). Influence of Cotton Bleaching Methods on the Parameters of Generated Textile Industrial Wastewater. Sustainability, 15.","DOI":"10.3390\/su152115592"},{"key":"ref_7","first-page":"26","article-title":"Allergies in the Workplace","volume":"26","author":"Kakande","year":"2013","journal-title":"Curr. Allergy Clin. Immunol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"5559","DOI":"10.1021\/acs.est.9b00272","article-title":"Clothing-Mediated Exposures to Chemicals and Particles","volume":"53","author":"Licina","year":"2019","journal-title":"Environ. Sci. Technol."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"968","DOI":"10.1520\/JFS14819J","article-title":"The Petroleum-Laced Background","volume":"45","author":"Lentini","year":"2000","journal-title":"J. Forensic Sci."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1403","DOI":"10.1007\/s00216-021-03766-x","article-title":"Suspect and Non-Target Screening of Chemicals in Clothing Textiles by Reversed-Phase Liquid Chromatography\/Hybrid Quadrupole-Orbitrap Mass Spectrometry","volume":"414","author":"Carlsson","year":"2022","journal-title":"Anal. Bioanal. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"8","DOI":"10.1186\/s12302-016-0076-7","article-title":"Natural Personal Care Products\u2014Analysis of Ingredient Lists and Legal Situation","volume":"28","author":"Klaschka","year":"2016","journal-title":"Environ. Sci. Eur."},{"key":"ref_12","unstructured":"(2024, April 16). OEKO-TEX International Association for Research and Testing in the Field of Textile and Leather Ecology, OEKO-TEX Standard STANDARD 100, Edition 02.2024. Available online: https:\/\/www.oeko-tex.com\/importedmedia\/downloadfiles\/OEKO-TEX_STANDARD_100_Standard_EN_DE.pdf."},{"key":"ref_13","first-page":"97","article-title":"The Eco-Legalization and Quality Requirements for Textiles, State of the Art and Current Developments","volume":"2","year":"2022","journal-title":"J. Meas. Sci. Appl. JMSA"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1016\/j.microc.2013.04.008","article-title":"Determination of Organochlorine Pesticides in Textiles Using Solid-Phase Microextraction with Gas Chromatography-Mass Spectrometry","volume":"110","author":"Cai","year":"2013","journal-title":"Microchem. J."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.aca.2012.05.036","article-title":"Determination of Organophosphorus Pesticides in Ecological Textiles by Solid-Phase Microextraction with a Siloxane-Modified Polyurethane Acrylic Resin Fiber","volume":"736","author":"Hu","year":"2012","journal-title":"Anal. Chim. Acta"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"202","DOI":"10.1016\/j.aca.2009.07.050","article-title":"Application of Solid-Phase Microextraction for the Determination of Organophosphorus Pesticides in Textiles by Gas Chromatography with Mass Spectrometry","volume":"650","author":"Zhu","year":"2009","journal-title":"Anal. Chim. Acta"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1016\/j.talanta.2015.08.069","article-title":"Hollow Fiber Based Liquid Phase Microextraction for the Determination of Organochlorine Pesticides in Ecological Textiles by Gas Chromatography-Mass Spectrometry","volume":"146","author":"Cai","year":"2016","journal-title":"Talanta"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"106134","DOI":"10.1016\/j.microc.2021.106134","article-title":"Screening of Some Banned Aromatic Amines in Textile Products from Indian Bandhani and Gamthi Fabric and in Human Sweat Using Micellar Liquid Chromatography","volume":"165","author":"Pahade","year":"2021","journal-title":"Microchem. J."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.chroma.2013.10.050","article-title":"Determination of Chlorobenzenes in Textiles by Pressurized Hot Water Extraction Followed by Vortex-Assisted Liquid-Liquid Microextraction and Gas Chromatography-Mass Spectrometry","volume":"1319","author":"Lu","year":"2013","journal-title":"J. Chromatogr. A"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1093\/chromsci\/45.7.375","article-title":"Multiresidue Determination of 77 Pesticides in Textiles by Gas Chromatography-Mass Spectrometry","volume":"45","author":"Zhou","year":"2007","journal-title":"J. Chromatogr. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Hrouzkov\u00e1, S., and Szarka, A. (2021). Development of a Modified Quechers Procedure for the Isolation of Pesticide Residues from Textile Samples, Followed by GC\u2013MS Determination. Separations, 8.","DOI":"10.3390\/separations8080106"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2747","DOI":"10.1007\/s00216-014-7688-9","article-title":"Quinolines in Clothing Textiles-A Source of Human Exposure and Wastewater Pollution?","volume":"406","author":"Luongo","year":"2014","journal-title":"Anal. Bioanal. Chem."},{"key":"ref_23","unstructured":"(2019). Textiles and Textile Products\u2014Determination of Polycyclic Aromatic Hydrocarbons (PAH), Method Using Gas Chromatography (Standard No. EN 17132:2019)."},{"key":"ref_24","unstructured":"(2002). Textiles\u2014Determination of the Phthalate Content\u2014Tetrahydrofuran Method (Standard No. EN ISO 14389:2002)."},{"key":"ref_25","unstructured":"(2016). Textiles\u2014Determination of Certain Flame Retardants Part 1: Brominated Flame Retardants (Standard No. EN ISO 17881-1:2016)."},{"key":"ref_26","unstructured":"(2021). Textiles\u2014Determination of Short-Chain Chlorinated Paraffins (SCCP) and Middle-Chain Chlorinated Paraffins (MCCP) in Textile Products out of Different Matrices by Use of Gas Chromatography Negative Ion Chemical Ionization Mass Spectrometry (GC-NCI-MS) (Standard No. EN ISO 22818:2021)."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"592","DOI":"10.1016\/j.envint.2019.04.013","article-title":"Concentrations of Bisphenol A and Parabens in Socks for Infants and Young Children in Spain and Their Hormone-like Activities","volume":"127","author":"Freire","year":"2019","journal-title":"Environ. Int."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.2116\/analsci.33.1027","article-title":"Determination of Eleven Organophosphorus Pesticide Residues in Textiles by Using HPLC-HRMS","volume":"33","author":"Hu","year":"2017","journal-title":"Anal. Sci."},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Szadkowska, D., Zawadzki, J., Kozakiewicz, P., and Radomski, A. (2021). Identification of Extractives from Various Poplar Species. Forests, 12.","DOI":"10.3390\/f12050647"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/j.talanta.2018.09.054","article-title":"Rapid Mapping of Various Chemicals in Personal Care and Healthcare Products by Direct Analysis in Real Time Mass Spectrometry","volume":"192","author":"Kuki","year":"2019","journal-title":"Talanta"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1038\/s41370-023-00547-9","article-title":"Evaluating Non-Targeted Analysis Methods for Chemical Characterization of Organic Contaminants in Different Matrices to Estimate Children\u2019s Exposure","volume":"33","author":"Cui","year":"2023","journal-title":"J. Expo. Sci. Environ. Epidemiol."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2097","DOI":"10.1021\/es5002105","article-title":"Identifying Small Molecules via High Resolution Mass Spectrometry: Communicating Confidence","volume":"48","author":"Schymanski","year":"2014","journal-title":"Environ. Sci. Technol."},{"key":"ref_33","doi-asserted-by":"crossref","unstructured":"D\u0105browski, \u0141. (2020). Evaluation of a Simplified Method for GC\/MS Qualitative Analysis of Polycyclic Aromatic. Molecules, 25.","DOI":"10.3390\/molecules25163727"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"464376","DOI":"10.1016\/j.chroma.2023.464376","article-title":"Use and Abuse of Retention Indices in Gas Chromatography","volume":"1708","author":"Bizzo","year":"2023","journal-title":"J. Chromatogr. A"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"2537","DOI":"10.1007\/s11356-015-5405-7","article-title":"The Washout Effect during Laundry on Benzothiazole, Benzotriazole, Quinoline, and Their Derivatives in Clothing Textiles","volume":"23","author":"Luongo","year":"2016","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"109043","DOI":"10.1016\/j.intimp.2022.109043","article-title":"Allergies Caused by Textiles: Control, Research and Future Perspective in the Medical Field","volume":"110","author":"Laffleur","year":"2022","journal-title":"Int. Immunopharmacol."},{"key":"ref_37","unstructured":"(2024, April 16). The Wet Processing of Cotton Scouring, Bleaching, Dyeing, & Finishing. Available online: https:\/\/csitc.org\/sitecontent\/RTCWA\/internal_wa\/02_Activites_du_RTC\/022_Formation\/0222_documents_de_formation\/02222_TICS\/Yarn_Fabric_Processing\/0222252_TICS_wet_processing.pdf."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/S1081-1206(10)60096-8","article-title":"Cutaneous Allergy to Cotton","volume":"102","author":"Subiza","year":"2009","journal-title":"Ann. Allergy Asthma Immunol."},{"key":"ref_39","first-page":"e51802","article-title":"Allergic Contact Dermatitis in the Right Forearm Following Splint Application for Distal Radius Fracture: A Rare Case of Plaster Cotton Allergy","volume":"16","author":"Demirdas","year":"2024","journal-title":"Cureus"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1046\/j.1440-0960.2001.00469.x","article-title":"Allergic Contact Dermatitis Due to Benzalkonium Chloride in Plaster of Paris","volume":"42","author":"Wong","year":"2001","journal-title":"Australas. J. Dermatol."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1007\/s40521-019-0197-5","article-title":"Textile Contact Dermatitis: How Fabrics Can Induce Dermatitis","volume":"6","author":"Svedman","year":"2019","journal-title":"Curr. Treat. Options Allergy"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"371","DOI":"10.1111\/j.1600-0536.1996.tb02427.x","article-title":"Allergic Contact Dermatitis from Benzalkonium Chloride in Plaster of Paris","volume":"35","author":"Lovell","year":"1996","journal-title":"Contact Dermat."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1111\/j.1600-0536.1981.tb04104.x","article-title":"Contact Allergy to Benzalkonium Chloride in Plaster of Paris","volume":"7","author":"Lovell","year":"1981","journal-title":"Contact Dermat."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1016\/0098-8472(96)00128-1","article-title":"Effect of Water Stress on the Epicuticular Wax Composition and Ultrastructure of Cotton (Gossypium hirsutum L.) Leaf, Bract, and Boll","volume":"36","author":"Bondada","year":"1996","journal-title":"Environ. Exp. Bot."},{"key":"ref_45","unstructured":"Kezic, S., Kruse, J., Jakasa, I., Boogaard, P., and Minsavage, G. (2010). Review of Dermal Effects and Uptake of Petroleum Hydrocarbons, CONCAWE. CONCAWE Report 5\/10."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"2392","DOI":"10.1007\/s11356-022-24059-5","article-title":"Use of Paraffin Oils in Agriculture and beyond: Back to the Future","volume":"30","author":"Baliota","year":"2023","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"586","DOI":"10.1002\/ps.1385","article-title":"The Efficacy of a Petroleum Spray Oil against Aphis Gossypii Glover on Cotton. Part 1: Mortality Rates and Sources of Variation","volume":"63","author":"Walter","year":"2007","journal-title":"Pest Manag. Sci."},{"key":"ref_48","unstructured":"Mensah, R., Liang, W., and Coates, R.W. (1997). Petroleum Spray Oils-Lubricating the Path to IPM: Part I. Use of Petroleum Spray Oil as Insecticide to Control Helicoverpa Spp on Commercial Cotton Fields. Integration of Biological and Microbial Control with Transgenic Bt Cotton View Project, Australian Cotton Research Institute."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1080\/09670870400028334","article-title":"Improving the Efficacy of Nuclear Polyhedrosis Virus and Bacillus Thuringiensis against Helicoverpa Spp. with Ultra-Violet Light Protected Petroleum Spray Oils on Cotton Crops in Australia","volume":"51","author":"Mensah","year":"2005","journal-title":"Int. J. Pest Manag."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Corazza, M., Catani, M., Franchina, F.A., Cavazzini, A., Bianchi, A., Borghi, A., Pacetti, L., and Schettini, N. (2024). Allergic Contact Dermatitis to Petrolatum: A Timeless Problem. Dermatitis.","DOI":"10.1089\/derm.2024.0009"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1111\/j.1600-0536.1995.tb00550.x","article-title":"Sensitization to White Petrolatum Used as a Vehicle for Patch Testing","volume":"33","author":"Conti","year":"1995","journal-title":"Contact Dermat."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"201","DOI":"10.2310\/6620.2006.06010","article-title":"Allegric Contact Dermatitis Caused by White Petrolatum on Damaged Skin","volume":"17","author":"Tam","year":"2006","journal-title":"Dermatitis"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"587","DOI":"10.1007\/BF02638577","article-title":"Textile Assistants from Fatty Acids and Their Derivatives","volume":"31","author":"McLeod","year":"1954","journal-title":"J. Am. Oil Chem. Soc."},{"key":"ref_54","unstructured":"(2024, April 16). PubChem (nih.gov), Available online: https:\/\/pubchem.ncbi.nlm.nih.gov\/."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1111\/j.0105-1873.2003.00208.x","article-title":"Nonanoic Acid\u2014An Experimental Irritant","volume":"49","author":"Wahlberg","year":"2003","journal-title":"Contact Dermat."},{"key":"ref_56","unstructured":"(2024, April 16). Haz-Map Database (Information on Hazardous Chemicals and Occupational Diseases). Available online: https:\/\/haz-map.com\/."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"228S","DOI":"10.1177\/1091581811428980","article-title":"Final Report of the Cosmetic Ingredient Review Expert Panel on the Safety Assessment of Pelargonic Acid (Nonanoic Acid) and Nonanoate Esters","volume":"30","author":"Johnson","year":"2011","journal-title":"Int. J. Toxicol."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1111\/1523-1747.ep12292040","article-title":"Acne Vulgaris. Studies in Pathogenesis: Free Fatty Acid Irritancy in Patients with and without Acne","volume":"57","author":"Ray","year":"1971","journal-title":"J. Investig. Dermatol."},{"key":"ref_59","unstructured":"(2024, April 16). Stearin\/Palmitic Acid (C18\/C16)\u2014Ataman Kimya. Available online: https:\/\/www.atamanchemicals.com\/stearic-palmitic-acid-c18-c16_u30006\/."},{"key":"ref_60","unstructured":"Tomasino, C. (1992). Chemistry & Technology of Fabric Preparation & Finishing, Department of Textile Engineering, Chemistry & Science College of Textiles North Carolina State University."},{"key":"ref_61","first-page":"217","article-title":"The Use of Non-Ionic Surfactants in the Textiles Industry","volume":"20","author":"Hassabo","year":"2023","journal-title":"J. Text. Color. Polym. Sci."},{"key":"ref_62","first-page":"35","article-title":"Mechanism of Softening Effect of Fabric Softener","volume":"8","author":"Igarashi","year":"2018","journal-title":"J. Mater. Sci. Res."},{"key":"ref_63","unstructured":"Guenin, E.P., and Smith, L.C. (1995). Method of Controlling Viscosity of Fabric Softeners. (95302910.5), European Patent Applications."},{"key":"ref_64","doi-asserted-by":"crossref","unstructured":"Hinchliffe, D.J., Naoumkina, M., Thyssen, G.N., Nam, S., Chang, S.C., McCarty, J.C., and Jenkins, J.N. (2024). Multi-Omics Analysis of Pigmentation Related to Proanthocyanidin Biosynthesis in Brown Cotton (Gossypium hirsutum L.). Front. Plant Sci., 15.","DOI":"10.3389\/fpls.2024.1372232"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"1016","DOI":"10.1016\/j.ecoenv.2008.07.012","article-title":"Human Health Risk Assessment of Long Chain Alcohols","volume":"72","author":"Veenstra","year":"2009","journal-title":"Ecotoxicol. Environ. Saf."},{"key":"ref_66","first-page":"516","article-title":"Saturated Fatty Acids Derivatives as Assistants Materials for Textile Processes","volume":"1","year":"2018","journal-title":"J. Text. Sci. Fash. Technol."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1097\/DER.0000000000000871","article-title":"Lanolin Allergic Reactions: North American Contact Dermatitis Group Experience, 2001 to 2018","volume":"33","author":"Silverberg","year":"2022","journal-title":"Dermatitis"},{"key":"ref_68","doi-asserted-by":"crossref","unstructured":"Dobler, D., Schmidts, T., Wildenhain, S., Seewald, I., Merzh\u00e4user, M., and Runkel, F. (2019). Impact of Selected Cosmetic Ingredients on Common Microorganisms of Healthy Human Skin. Cosmetics, 6.","DOI":"10.3390\/cosmetics6030045"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"30","DOI":"10.1680\/jsuin.22.01073","article-title":"Greenly Prepared Antimicrobial Cotton Fabrics Using Bioactive Agents from Cupressaceae Pods","volume":"12","author":"Syed","year":"2022","journal-title":"Surf. Innov."},{"key":"ref_70","doi-asserted-by":"crossref","unstructured":"Huang, L., Zhu, X., Zhou, S., Cheng, Z., Shi, K., Zhang, C., and Shao, H. (2021). Phthalic acid esters: Natural sources and biological activities. Toxins, 13.","DOI":"10.3390\/toxins13070495"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"2544","DOI":"10.1080\/00032719.2015.1043665","article-title":"Determination of Phthalate Esters in Textiles by Solid Phase Extraction and Gas Chromatography\u2013Mass Spectrometry","volume":"48","author":"Xin","year":"2015","journal-title":"Anal. Lett."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.envres.2018.09.027","article-title":"Human Health Risks Due to Exposure to Inorganic and Organic Chemicals from Textiles: A Review","volume":"168","author":"Rovira","year":"2019","journal-title":"Environ. Res."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"105706","DOI":"10.1016\/j.envint.2020.105706","article-title":"Phthalate Exposure and Allergic Diseases: Review of Epidemiological and Experimental Evidence","volume":"139","author":"Sripada","year":"2020","journal-title":"Environ. Int."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1034\/j.1600-0536.2002.460115.x","article-title":"Allergic Contact Dermatitis from Dibutyl Phthalate and Benzalkonium Chloride in Timodine\u00ae Cream","volume":"46","author":"Chowdhury","year":"2002","journal-title":"Contact Dermat."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"285","DOI":"10.4168\/aair.2022.14.3.285","article-title":"The Detrimental Effects of Phthalates on Allergic Diseases","volume":"14","author":"Ahn","year":"2022","journal-title":"Allergy Asthma Immunol. Res."},{"key":"ref_76","first-page":"24","article-title":"Exposure to Phthalates and Bisphenol A Are Associated with Atopic Dermatitis Symptoms in Children: A Time-Series Analysis","volume":"16","author":"Kim","year":"2017","journal-title":"Environ. Health A Glob. Access Sci. Source"},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"230123","DOI":"10.4491\/eer.2023.123","article-title":"Suspect and Non-Target Screening of Chemicals in Household Cleaning Products, and Their Toxicity Assessment","volume":"29","author":"Park","year":"2024","journal-title":"Environ. Eng. Res."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1111\/j.1600-0536.1980.tb05564.x","article-title":"Contact Urticaria from Nickel and Plastic Additives (Butylhydroxytoluene, Oleylamide)","volume":"6","author":"Osmundsen","year":"1980","journal-title":"Contact Dermat."},{"key":"ref_79","doi-asserted-by":"crossref","unstructured":"Naumoska, K., Jug, U., Metli\u010dar, V., and Vovk, I. (2020). Oleamide, a Bioactive Compound, Unwittingly Introduced into the Human Body through Some Plastic Food\/Beverages and Medicine Containers. Foods, 9.","DOI":"10.3390\/foods9050549"},{"key":"ref_80","unstructured":"(2024, April 16). European Chemicals Agency ECHA Database. Available online: https:\/\/echa.europa.eu\/information-on-chemicals."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1111\/1471-0528.17668","article-title":"Chemicals in Menstrual Products: A Systematic Review","volume":"131","author":"Marroquin","year":"2023","journal-title":"BJOG An Int. J. Obstet. Gynaecol."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/10915810290096504","article-title":"Final Report on the Safety Assessment of Acetyl Triethyl Citrate, Acetyl Tributyl Citrate, Acetyl Trihexyl Citrate, and Acetyl Trioctyl Citrate","volume":"21","author":"Johnson","year":"2002","journal-title":"Int. J. Toxicol."},{"key":"ref_83","doi-asserted-by":"crossref","unstructured":"D\u0105browski, \u0141. (2020). Evaluation of Solvents Used as Keepers in the Determination of Organic Pollutants by GC\/MS. Molecules, 25.","DOI":"10.3390\/molecules25194419"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/15\/3584\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T15:26:10Z","timestamp":1760109970000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/29\/15\/3584"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,30]]},"references-count":83,"journal-issue":{"issue":"15","published-online":{"date-parts":[[2024,8]]}},"alternative-id":["molecules29153584"],"URL":"https:\/\/doi.org\/10.3390\/molecules29153584","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,7,30]]}}}